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Vol. 35 No. 5 (2023): Vol 35 Issue 5, 2023

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First-Order Derivative Spectrophotometry Method with Triapine as Chelating Agent for Simultaneous Determination of Barium(II) and Lead(II)

https://doi.org/10.14233/ajchem.2023.27793
S. Nazimunnisa
Department of Chemistry, AMC Engineering College, Bangalore-560083, India
V. Veeranna
Department of Chemistry, AMC Engineering College, Bangalore-560083, India
https://orcid.org/0000-0002-8192-6045
V. Venkata Laxmi
V. Venkata Laxmi
G. Pathalinga Prasad
Department of Mechanical Engineering, AMC Engineering College, Bangalore-560083, India
S. Yallappa
Department of Chemistry, AMC Engineering College, Bangalore-560083, India
https://orcid.org/0000-0002-5252-5541

Corresponding Author(s) : V. Veeranna

saidikshav@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 5 (2023): Vol 35 Issue 5, 2023

Abstract

A simple, selective and sensitive first-order spectrophotometric method was used for the simultaneous determination of Ba(II) and Pb(II) with triapine as chelating agent. When triapine reagent was mixed with Ba(II) and Pb(II) solutions, it produces a light green colour in a basic medium. Maximum peaks for both Ba(II) and Pb(II) were observed at pH 8.5 (basic buffer solution) between 350 and 395 nm. Ba(II)-triapine has a molar absorbance of 5.276 × 106 L mol-1 cm-1 and a Sandell’s sensitivity of 0.000189 g/cm2. Similarly, they are 9.421 × 105 L mol-1 cm-1 and 0.00106 g/cm2 for Pb(II)-triapine, respectively. The stability constants of Ba(II)-triapine and Pb(II)-trapine complexes are 3.207 × 104 and 5.118 × 104, respectively. The effects of Ba(II)-triapine and Pb(II)-triapine concentrations on amplitude were also studied. The detection and quantification limits for Ba(II)-triapine are 0.0882 g/mL and 0.746 g/mL, respectively. Similarly, detection and quantification values were 0.089 g/mL and 0.745 g/mL for Pb(II)-triapine, respectively. The developed or proposed method was used to examine biological samples of carrots, onions, beans, paints, milk powder and alloys. The sample results were close to the certified reference values for the ICP-AES, FDA and AAS methods.

Keywords

First-order spectrophotometric Triapine Ba(II)-triapine ICP-AES
Nazimunnisa, S., Veeranna, V., Laxmi, V. V., Prasad, G. P., & Yallappa, S. (2023). First-Order Derivative Spectrophotometry Method with Triapine as Chelating Agent for Simultaneous Determination of Barium(II) and Lead(II). Asian Journal of Chemistry, 35(5), 1231–1236. https://doi.org/10.14233/ajchem.2023.27793
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