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Vol. 35 No. 4 (2023): Vol 35 Issue 4, 2023

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Enhancing Corrosion Resistance Property of Mild Steel by Benzoxazine Synthesized from Vanillin and Copolymerize with Urethane

https://doi.org/10.14233/ajchem.2023.27290
K. Jayanthi
P.G. and Research Department of Chemistry, Queen Mary’s College (A), Chennai-600004, India
https://orcid.org/0000-0002-1646-1798
M. Sivaraju
P.G. and Research Department of Chemistry, Thiruvalluvar Government Arts College, Rasipuram-637401, India
https://orcid.org/0000-0001-8502-5458
P. Shanmugasundaram
P.G. and Research Department of Chemistry, Thiruvalluvar Government Arts College, Rasipuram-637401, India
https://orcid.org/0000-0002-1417-1818

Corresponding Author(s) : K. Jayanthi

kjayanthi_che@queenmaryscollege.edu.in

Asian Journal of Chemistry, Vol. 35 No. 4 (2023): Vol 35 Issue 4, 2023

Abstract

Benzoxazine monomer prepared from vanillin and n-butylamine was characterized by 1H NMR, 13C NMR, FT-IR and UV visible spectroscopic techniques. The synthesized monomer was coated on the mild steel with isocyanate hardener in varying concentrations of isocyanate of the poly(VaBz-PU) and cured. The thermal properties of the monomer with and without isocyanate hardener were studied by TGA and DSC methods. The effect of various concentrations of isocyanate (PU) hardener with benzoxazine monomer on hardness, water absorption and gel absorption was investigated. Various concentrations of PU hardener with benzoxazine coating (VaBz-PU) on the mild steel were investigated by the electrochemical impedance and polarization studies. The study revealed that an increasing concentration of isocyante in the coating with benzoxazine increased their thermal, chemical and anticorrosive properties. The DFT calculations were also performed to support the anti-corrosive ability of the material.

Keywords

Benzoxazine Vanillin Polyurethane copolymer Electrochemical impedance Corrosion Polarization
Jayanthi, K., Sivaraju, M., & Shanmugasundaram, P. (2023). Enhancing Corrosion Resistance Property of Mild Steel by Benzoxazine Synthesized from Vanillin and Copolymerize with Urethane. Asian Journal of Chemistry, 35(4), 851–860. https://doi.org/10.14233/ajchem.2023.27290
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References
  1. N. Haghdadi, M. Laleh, M. Moyle and S. Primig, J. Mater. Sci., 56, 64 (2021); https://doi.org/10.1007/s10853-020-05109-0
  2. M. El-Sayed Sherif and H.A. Ayman, Crystals, 11, 1516 (2021); https://doi.org/10.3390/cryst11121516
  3. I.A. Kartsonakis, S.G. Stanciu, A.A. Matei, R. Hristu, A. Karantonis and C.A. Charitidis, Corros. Sci., 112, 289 (2016); https://doi.org/10.1016/j.corsci.2016.07.030
  4. A. Dastgheib, M.M. Attar and A. Zarebidaki, Met. Mater. Int., 26, 1634 (2020); https://doi.org/10.1007/s12540-019-00432-x
  5. M.A.A. Khan, O.M. Irfan, F. Djavanroodi and M. Asad, Sustainability, 14, 9502 (2022); https://doi.org/10.3390/su14159502
  6. G. Veselinka, B. Ivana, M. Sanja and K. Bojana, Maced. J. Chem. Chem. Eng., 37, 203 (2018).
  7. L. Suman and R.S. Chaudhary, Indian J. Chem. Technol., 15, 364 (2008).
  8. A.-R. El-Sayed, U. Harm, K.-M. Mangold and W. Fürbeth, Corros. Sci., 55, 339 (2012); https://doi.org/10.1016/j.corsci.2011.10.036
  9. M.M. Muzakir, F.O. Nwosu and S.O. Amusat, Port. Electrochem. Acta, 37, 359 (2019); https://doi.org/10.4152/pea.201906359
  10. X. Li, S. Deng, X. Xie and H. Fu, Corros. Sci., 87, 15 (2014); https://doi.org/10.1016/j.corsci.2014.05.013
  11. H. Ishida and D. Allen, J. Polym. Sci., B, Polym. Phys., 34, 1019 (1996); https://doi.org/10.1002/(SICI)1099-0488(19960430)34:6<1019::AID-POLB1>3.0.CO;2-T
  12. H.C. Liu, W.C. Su and Y.L. Liu, J. Mater. Chem., 21, 7182 (2011); https://doi.org/10.1039/c1jm10815h
  13. Y.J. Lee, S.W. Kuo, Y.C. Su, J.K. Chen, C.W. Tu and F.C. Chang, Polymer, 45, 6321 (2004); https://doi.org/10.1016/j.polymer.2004.04.055
  14. C. Zhou, M. Fu, H. Xie, Y. Gong, J. Chen, J. Liu and Z. Xin, Ind. Eng. Chem. Res., 60, 1675 (2021); https://doi.org/10.1021/acs.iecr.0c05903
  15. T. Periyasamy, S.P. Asrafali, S. Muthusamy and S.-C. Kim, New J. Chem., 40, 9313 (2016); https://doi.org/10.1039/C6NJ02242A
  16. G.A. Phalak, D.M. Patil and S.T. Mhaske, Eur. Polym. J., 88, 93 (2017); https://doi.org/10.1016/j.eurpolymj.2016.12.030
  17. D.M. Patil, G.A. Phalak and S.T. Mhaske, Prog. Org. Coat., 105, 18 (2017); https://doi.org/10.1016/j.porgcoat.2016.10.027
  18. M. Fache, B. Boutevin and S. Caillol, Eur. Polym. J., 68, 488 (2015); https://doi.org/10.1016/j.eurpolymj.2015.03.050
  19. A. Van, K. Chiou and H. Ishida, Polymer, 55, 1443 (2014); https://doi.org/10.1016/j.polymer.2014.01.041
  20. N.K. Sini, J. Bijwe and I.K. Varma, Polym. Degrad. Stab., 109, 270 (2014); https://doi.org/10.1016/j.polymdegradstab.2014.07.015
  21. N.K. Sini, J. Bijwe and I.K. Varma, J. Polym. Sci. A Polym. Chem., 52, 7 (2014); https://doi.org/10.1002/pola.26981
  22. C. Chen, Y. Cao, X. Lu, X. Li, H. Yao and Z. Xin, Colloids Surf. A Physicochem. Eng. Asp., 609, 125605 (2021); https://doi.org/10.1016/j.colsurfa.2020.125605
  23. M.S. Mahajan, P.P. Mahulikar and V.V. Gite, Prog. Org. Coat., 148, 105826 (2020); https://doi.org/10.1016/j.porgcoat.2020.105826
  24. R.L. Quirino, T.F. Garrison and M.R. Kessler, Green Chem., 16, 1700 (2014); https://doi.org/10.1039/C3GC41811A
  25. G. Wu, X. He, L. Xu, H. Zhang and Y. Yan, RSC Adv., 5, 27097 (2015); https://doi.org/10.1039/C5RA02912K
  26. A.S. More, B. Gadenne, C. Alfos and H. Cramail, Polym. Chem., 3, 1594 (2012); https://doi.org/10.1039/c2py20123b
  27. T.J. Nelson, B. Masaki, Z. Morseth and D.C. Webster, J. Coat. Technol. Res., 10, 757 (2013); https://doi.org/10.1007/s11998-013-9524-0
  28. C. Zhang, S.A. Madbouly and M.R. Kessler, ACS Appl. Mater. Interfaces, 7, 1226 (2015); https://doi.org/10.1021/am5071333
  29. P. Thirukumaran, P.A. Shakila, M. Sarojadevi and C.K. Seong, New J. Chem., 43, 8816 (2020); https://doi.org/10.1039/C9NJ90071C
  30. A. Trejo-Machin, A. Adjaoud, L. Puchot, R. Dieden and P. Verge, Eur. Polym. J., 124, 109468 (2020); https://doi.org/10.1016/j.eurpolymj.2019.109468
  31. X. Ning and H. Ishida, J. Polym. Sci. A Polym. Chem., 32, 1121 (1994); https://doi.org/10.1002/pola.1994.080320614
  32. J.A. Macko and H. Ishida, Polymer, 42, 6371 (2001); https://doi.org/10.1016/S0032-3861(01)00055-6
  33. R.-C. Lin and S.-W. Kuo, RSC Adv., 8, 13592 (2018); https://doi.org/10.1039/C8RA00506K
  34. C. Zhou, X. Lu, Z. Xin and Y. Zhang, J. Coat. Technol. Res., 13, 63 (2016); https://doi.org/10.1007/s11998-015-9722-z
  35. H. Wei, D. Ding, S. Wei and Z. Guo, J. Mater. Chem. A Mater. Energy Sustain., 1, 10805 (2013); https://doi.org/10.1039/c3ta11966a
  36. P. Selvakumar, K.B. Balanaga and C. Thangavelu, J. Adv. Chem., 6, 897 (2013).
  37. Z. Tao, S. Zhang, W. Li and B. Hou, Corros. Sci., 51, 2588 (2009); https://doi.org/10.1016/j.corsci.2009.06.042
  38. P.C. Okafor, X. Liu and Y.G. Zheng, Corros. Sci., 51, 761 (2009); https://doi.org/10.1016/j.corsci.2009.01.017
  39. M.G. Hosseini, M. Ehteshamzadeh and T. Shahrabi, Electrochim. Acta, 52, 3680 (2007); https://doi.org/10.1016/j.electacta.2006.10.041
  40. S. Muralidharan, K.L.N. Phani, S. Pitchumani, S. Ravichandran and S.V.K. Iyer, J. Electrochem. Soc., 142, 1478 (1995); https://doi.org/10.1149/1.2048599
  41. F. Bentiss, M. Traisnel and M. Lagrenee, Corros. Sci., 42, 127 (2000); https://doi.org/10.1016/S0010-938X(99)00049-9
  42. X. Yang, S. Fan, Y. Li, Y. Guo, Y. Li, K. Ruan, S. Zhang, J. Zhang, J. Kong and J. Gu, Composites Part A, 128, 105670 (2020); https://doi.org/10.1016/j.compositesa.2019.105670
  43. P. Song, H. Wang, L. Wang, X. Liu, Y. Zhang, J. Zhang, J. Kong and J. Gu, Sustain. Mater. Technol., 24 e00153 (2020); https://doi.org/10.1016/j.susmat.2020.e00153
  44. S. Sriharshitha, K. Krishnadevi, S. Devaraju, V. Srinivasadesikan and S.-L. Lee, ACS Omega, 5, 33178 (2020); https://doi.org/10.1021/acsomega.0c04840
  45. P. Sharma, P. Dutta and L. Nebhani, Polymer, 184, 121905 (2019); https://doi.org/10.1016/j.polymer.2019.121905
  46. P. Sharma and L. Nebhani, Polymer, 199, 122549 (2020); https://doi.org/10.1016/j.polymer.2020.122549
  47. A. Ouass, M. Galai, M. Ouakki, E. Ech-Chihbi, L. Kadiri, R. Hsissou, Y. Essaadaoui, A. Berisha, M. Cherkaoui, A. Lebkiri and E.H. Rifi, J. Appl. Electrochem., 51, 1009 (2021); https://doi.org/10.1007/s10800-021-01556-y
  48. J. Fang and J. Li, J. Mol. Struct. THEOCHEM, 593, 179 (2002); https://doi.org/10.1016/S0166-1280(02)00316-0
  49. D.K. Singh, E.E. Ebenso, M.K. Singh, D. Behera, G. Udayabhanu and R.P. John, J. Mol. Liq., 250, 88 (2018); https://doi.org/10.1016/j.molliq.2017.11.132
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