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Vol. 35 No. 4 (2023): Vol 35 Issue 4, 2023

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Thermal, Mechanical and Swelling Studies of Semi-Interpenetrating Polymer Network Composed of Natural Rubber and Polyacrylamide

https://doi.org/10.14233/ajchem.2023.27592
Manju R Nath
Department of Chemistry, Payyanur College (Affiliated to Kannur University), Payyanur-670327, India Postgraduate Department of Chemistry, Government College Kasaragod (Affiliated to Kannur University), Kasaragod-673123, India
https://orcid.org/0009-0000-5187-3432
A. Mohanan
Postgraduate Department of Chemistry, Government College Kasaragod (Affiliated to Kannur University), Kasaragod-673123, India Department of Chemistry, Nehru Arts and Science College (Affiliated to Kannur University), Kanhangad-671314, India
https://orcid.org/0000-0001-9935-384X

Corresponding Author(s) : A. Mohanan

drmohanan75@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 4 (2023): Vol 35 Issue 4, 2023

Abstract

Semi-interpenetrating polymer network (IPN) composed of two polymers, namely natural rubber (NR) and polyacrylamide (PAAm) were prepared by crosslinking with glutaraldehyde. The NR/PAAm semi-IPN films were developed by varying the concentration of crosslinking agents and the polymer blend ratios. The impact of preparation parameters on the mechanical properties was studied. The semi-IPN was characterized by FTIR, DTG, TG and SEM. Swelling studies were done by using toluene as solvent. The kinetics and mechanism of swelling were investigated and the initial rate of swelling, swelling constant, swelling exponent, equilibrium swelling and diffusion coefficient were also determined.

Keywords

Semi-IPN systems Mechanical properties Swelling studies Diffusion coefficient
Nath, M. R., & Mohanan, A. (2023). Thermal, Mechanical and Swelling Studies of Semi-Interpenetrating Polymer Network Composed of Natural Rubber and Polyacrylamide. Asian Journal of Chemistry, 35(4), 977–985. https://doi.org/10.14233/ajchem.2023.27592
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