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Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023

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Cd(II) Dithiocarbamate Complexes: Synthesis, Spectral Studies, Thermogravimetric Analysis and Semiconducting Behaviour

https://doi.org/10.14233/ajchem.2023.27486
V.K. Maurya
Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi-221005, India
L.B. Prasad
Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi-221005, India
A. Singh
Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi-221005, India
K. Shiv
Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi-221005, India
S. Kumar
Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi-221005, India
M.K. Bharty
Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi-221005, India

Corresponding Author(s) : L.B. Prasad

lbprasad@bhu.ac.in

Asian Journal of Chemistry, Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023

Abstract

Five new homoleptic Cd(II) dithiocarbamate complexes (1-5) have been synthesized and characterized by IR, NMR, UV-visible spectroscopic and thermogravimetric analysis. Single-crystal X-ray diffraction study of complex 1 revealed a triclinic system with space group P-1 and possesses a centrosymmetric dimeric structure. In this complex, both C–H···S and C–H···π intermolecular interactions are playing a crucial role in the stabilization of the dithiocarbamate complex. Complexes (1-5) show weak conductivity at ambient temperature (σrt = 10-9-10-10 S·cm-1) because of the absence of M···S/S···S intermolecular stacking. Plot of log σ versus T–1 in the 303-363 K range indicates their semiconducting behaviour. However, their electrical conductivities gradually increase with increasing temperature and ideally decrease with decreasing temperature range showing their semiconducting nature. TGA showed thermal decomposition of complexes into CdS as the final product with grain size of 1-10 nm.

Keywords

Cd(II) dithiocarbamate complexes Luminescent emission Conductivity Thermogravimetric studies
Maurya, V., Prasad, L., Singh, A., Shiv, K., Kumar, S., & Bharty, M. (2023). Cd(II) Dithiocarbamate Complexes: Synthesis, Spectral Studies, Thermogravimetric Analysis and Semiconducting Behaviour. Asian Journal of Chemistry, 35(2), 499–506. https://doi.org/10.14233/ajchem.2023.27486
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