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Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023

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Adsorption of Rhodamine-B Dye by Raw and Activated Bael Leaves: Isotherms, Kinetics and Thermodynamics Perspectives

https://doi.org/10.14233/ajchem.2023.26880
Renu Yadav
Department of Chemistry, Ahir College, Rewari-123401, India ; Department of Chemistry, Raj Rishi Bhartrihari Matsya University, Alwar-301001, India
Anoop Kumar Sharma
Department of Chemistry, Government P.G. College Rajgarh, Alwar-301001, India
Anil Yadav
Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131001, India

Corresponding Author(s) : Anil Yadav

anilyadav.che@dcrustm.org

Asian Journal of Chemistry, Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023

Abstract

The agricultural waste and their derived products to remove dyes from wastewater have attracted ample attention due to its availability and economic advantages with high removal efficiency. In this study, raw bael leaves and their prepared carbon were used to remove Rhodamine-B (RhB) dye present in wastewater. The effects of different factors, including concentration (50-100 mg/L), contact time (20-140 min), adsorbent dosage (5-50 mg), pH range (1-10) and temperature (20-60 ºC) were investigated. The maximum percentage removal of RhB dye were found to be 77.4 and 89.9, respectively using raw bael leaves (RBL) and activated carbon of bael leaves (ACBL) with optimum conditions. Different characterization techniques used to characterize the adsorbents (RBL and ACBL) via SEM, FTIR, XRD and BET. Adsorption process obeyed Langmuir isotherm model for both cases viz. adsorption of RhB on RBL and adsorption of RhB on ACBL. The maximum adsorption capacities 86.89 mg/g and 113.82 mg/g were found for RBL and ACBL, respectively. The kinetics adsorption study for adsorption of RhB on RBL and ACBL had a great correlation with pseudo-second order model and confirmed the processes are chemisorption. Therefore, the RBL and ACBL adsorbents could be encouraging adsorbents for the removal of dyes.

Keywords

Raw bael leaves Bael leaves Activated carbon Rhodamine-B dye Adsorption
Yadav, R., Kumar Sharma, A., & Yadav, A. (2023). Adsorption of Rhodamine-B Dye by Raw and Activated Bael Leaves: Isotherms, Kinetics and Thermodynamics Perspectives. Asian Journal of Chemistry, 35(2), 337–344. https://doi.org/10.14233/ajchem.2023.26880
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