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Vol. 35 No. 11 (2023): Vol 35 Issue 11, 2023

Copyright (c) 2023 Sheetal Maan, Anushree Jatrana, Vinay Kumar, Meena Sindhu, Sanchit Mondal

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Chlorpyrifos Release Kinetics from Citric Acid Crosslinked Biopolymeric Nanoparticles: A Sustainable Approach

https://doi.org/10.14233/ajchem.2023.30755
SHEETAL MAAN
Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125004, India
https://orcid.org/0009-0000-6004-9226
ANUSHREE JATRANA
Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125004, India
https://orcid.org/0000-0003-4927-0768
VINAY KUMAR
2Department of Physics, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125004, India
https://orcid.org/0000-0002-1655-6316
MEENA SINDHU
Department of Microbiology, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125004, India
https://orcid.org/0000-0002-8755-4705
SANCHIT MONDAL
Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125004, India
https://orcid.org/0000-0001-5311-6187

Corresponding Author(s) : SHEETAL MAAN

sheetalmaan007@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 11 (2023): Vol 35 Issue 11, 2023

Abstract

Biopolymer based nanoformulation was synthesized by using microwave assisted nano-precipitaion method. The biopolymers consist of chitosan and guar gum were crosslinked using citric acid in order to encapsulate chlorpyrifos pesticide. The successful synthesis of chlorpyrifos containing nano-formulations was thoroughly examined, where the surface morphology examined by using field emission scanning electron microscopy (FE-SEM) has established the loading of chlorpyrifos in the biopolymeric matrix, transmission electron microscopy (TEM) examination revealed the spherical shaped particles of about 234 nm and Fourier-transform infrared spectroscopy (FTIR) analysis has confirmed the crosslinking between two biopolymers through citric acid due to the presence of peaks corresponding to ester linkages at 1730 cm-1. The encapsulation efficiency of chlorpyrifos at pH 7 and 30 ºC was around 50%. The successfully synthesized chlorpyrifos loaded biopolymeric nano-formulation were further utilized to study the release behaviour of chlorpyrifos in water and biocompatibility towards soil microbiota. The release of chlorpyrifos was almost 15% slower than conventional chlorpyrifos and the formulation was found biocompatible towards microbiota.

Keywords

Chitosan Guar gum, Biopolymers Biocompatibility, Encapsulation efficiency Nano-formulation Slow release behaviouru
MAAN, S., JATRANA, A., KUMAR, V., SINDHU, M., & MONDAL, S. (2023). Chlorpyrifos Release Kinetics from Citric Acid Crosslinked Biopolymeric Nanoparticles: A Sustainable Approach. Asian Journal of Chemistry, 35(11), 2822–2828. https://doi.org/10.14233/ajchem.2023.30755
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