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Vol. 35 No. 11 (2023): Vol 35 Issue 11, 2023

Copyright (c) 2023 Reshma, HUSSAIN SHAIK, KONDA MANOHAR, B. MUKESH, RAMANA REDDY BODDU, SRAVANTHI ITTIKYALA, PUPPALA VEERA SOMAIAH

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Synthesis, Characterization, Biological Activity of PEG Capped Silver Nanoparticles and Photocatalytic Degradation of Methylene Blue Dye using LC-MS Method

https://doi.org/10.14233/ajchem.2023.27005
Reshma
Department of Chemistry, University College of Science, Osmania University, Tarnaka, Hyderabad-500007, India Chemistry Division, Department of Humanities & Sciences, CVR College of Engineering, Hyderabad-501510, India
https://orcid.org/0009-0002-5432-3430
HUSSAIN SHAIK
Analytical and Structural Chemistry Department, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500007, India
https://orcid.org/0000-0003-4902-2406
KONDA MANOHAR
Vignan Institute of Technology & Science, Deshmukhi (V), Pochampally (M), Yadadri-Bhuvanagiri District-508284, India
https://orcid.org/0000-0002-6585-2322
B. MUKESH
Vignan Institute of Technology & Science, Deshmukhi (V), Pochampally (M), Yadadri-Bhuvanagiri District-508284, India
RAMANA REDDY BODDU
Vignan Institute of Technology & Science, Deshmukhi (V), Pochampally (M), Yadadri-Bhuvanagiri District-508284, India
https://orcid.org/0009-0007-3041-7818
SRAVANTHI ITTIKYALA
Vignan Institute of Technology & Science, Deshmukhi (V), Pochampally (M), Yadadri-Bhuvanagiri District-508284, India
https://orcid.org/0009-0009-2724-4033
PUPPALA VEERA SOMAIAH
Department of Chemistry, University College of Science, Osmania University, Tarnaka, Hyderabad-500007, India
https://orcid.org/0009-0008-7965-3261

Corresponding Author(s) : Reshma

reshma1947aug15@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 11 (2023): Vol 35 Issue 11, 2023

Abstract

Silver nanoparticles (AgNPs) were prepared by co-precipitation method using a capping agent, PEG-4000 (polyethylene glycol). The synthesized AgNPs were characterized using UV-visible, FTIR, SEM, EDX and TEM techniques. The bandgap energy of snythesized nanoparticles was determined using UV-visible spectra and found to be 3.07 eV. The particle size of nanoparticles calculated from the TEM and XRD pattern was in the range of 10-23 nm. The degradation efficiency of PEG capped AgNPs towards methylene blue (MB) dye under solar radiation was 63.78%. The photocatalytic degradation of MB dye follows the pseudo-first-order kinetics with an apparent rate constant of 1.1 × 10-2 min-1. The degradation products of MB dye during the photocatalytic process were identified using liquid chromatography-mass spectrometry (LC-ESI-TOF-MS). The antibacterial activity of synthesized PEG capped AgNPs using a disc diffusion method against four different Gram-positive and Gram-negative bacterial strains. The results showed that the synthesized nanoparticles could exhibit antibacterial activity. The anticancer activity of synthesized PEG capped AgNPs was tested against cancer cell lines such as A549 and HepG2. The results revealed that the synthesized PEG capped AgNPs have also shown an excellent anticancer activity with increasing their concentration. The antidiabetic activity of PEG capped AgNPs was studied against the a- lucosidase enzyme. The results confirmed that the synthesized AgNPs were shown a-glucosidase inhibition to 45.08%. The ABTS and DPPH radical scavenging activities were used to assay the antioxidant activity of synthesized PEG capped AgNPs.

Keywords

Silver nanoparticles PEG-4000 Co-precipitation method, Biological activities, Photodegradation Methylene blue dye
Reshma, SHAIK, H., MANOHAR, K., MUKESH, B., BODDU, R. R., ITTIKYALA, S., & SOMAIAH, P. V. (2023). Synthesis, Characterization, Biological Activity of PEG Capped Silver Nanoparticles and Photocatalytic Degradation of Methylene Blue Dye using LC-MS Method. Asian Journal of Chemistry, 35(11), 2715–2725. https://doi.org/10.14233/ajchem.2023.27005
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