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Vol. 35 No. 10 (2023): Vol 35 Issue 10, 2023

Copyright (c) 2023 RITA BHATTACHARJEE, VIRUPAIAH GAYATHRI

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Synthesis and Characterization of Ruthenium(II) Carbonyl Complexes of Substituted Quinazoline Derivatives and their Catalytic Activity

https://doi.org/10.14233/ajchem.2023.28048
RITA BHATTACHARJEE
Department of Chemistry, BMS College for Women, Bengaluru-560004, India
https://orcid.org/0009-0007-7348-4631
VIRUPAIAH GAYATHRI
Department of Post Graduate Studies in Chemistry, Bengaluru City University, Bengaluru-560001, India
https://orcid.org/0000-0001-6207-6463

Corresponding Author(s) : RITA BHATTACHARJEE

rita@bmscw.edu.in

Asian Journal of Chemistry, Vol. 35 No. 10 (2023): Vol 35 Issue 10, 2023

Abstract

A series of ruthenium(II) carbonyl complexes of the types [RuCl2(CO)2L]2·nH2O {n = 1, L = L1, L3}; [RuCl2(CO)2(L)(H2O)]·nH2O {n = 1, L = L2, L4, L6 and n = 2, L = L7}; [RuCl(CO)2(L-H)(H2O)]2 {L = L5}; [RuCl2(CO)2]3(L)2 {L = L8} were synthesized where L is 6R-5,6- dihydrobenzoimidazo[1,2-c]quinazoline (R-Diq; R = phenyl: L1/furyl: L2/thiophenyl: L3/o or p-hydroxyphenyl: L4, L5/o or p- hlorophenyl: L6, L7/dimethylaminophenyl: L8). The Ru(II) complexes were characterized by elemental analyses, conductivity measurements, TGA, infrared, electronic, NMR and mass spectral techniques. An octahedral geometry around the metal ion was proposed for all the complexes and monomeric, dimeric and trimeric stereochemistry was suggested. The catalytic activity for few ruthenium(II) complexes towards oxidation of benzyl alcohol, hydroquinone and cyclohexanol was also investigated. 

Keywords

Dihydrobenzoimidazoquinazoline derivatives Mass spectra Ru(II) carbonyl complexes
BHATTACHARJEE, R., & GAYATHRI, V. (2023). Synthesis and Characterization of Ruthenium(II) Carbonyl Complexes of Substituted Quinazoline Derivatives and their Catalytic Activity. Asian Journal of Chemistry, 35(10), 2359–2364. https://doi.org/10.14233/ajchem.2023.28048
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