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Vol. 35 No. 10 (2023): Vol 35 Issue 10, 2023

Copyright (c) 2023 ANBARASU MURUGAN, VINITHA VISWANATHAN, DHANALAKSHMI RAVIKUMAR, SIVAMURUGAN VAJIRAVELU

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Zinc Catalysts: Unlocking the Sustainable Transformation of Post-Consumer PET Waste through Chemical Recycling

https://doi.org/10.14233/ajchem.2023.28206
ANBARASU MURUGAN
P.G. & Research Department of Chemistry, Pachaiyappa’s College, Chennai-600030, India
VINITHA VISWANATHAN
P.G. & Research Department of Chemistry, Pachaiyappa’s College, Chennai-600030, India
DHANALAKSHMI RAVIKUMAR
P.G. & Research Department of Chemistry, Pachaiyappa’s College, Chennai-600030, India
SIVAMURUGAN VAJIRAVELU
P.G. & Research Department of Chemistry, Pachaiyappa’s College, Chennai-600030, India
https://orcid.org/0000-0002-9295-2118

Corresponding Author(s) : SIVAMURUGAN VAJIRAVELU

sivaatnus@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 10 (2023): Vol 35 Issue 10, 2023

Abstract

This review article focuses on the reclamation of polyethylene terephthalate (PET) waste accomplished through zinc catalyzed depolymerization. Polyethylene terephthalate (PET) is a polyester that can be depolymerized in a variety of ways, including hydrolysis, alcoholysis, ammonolysis and aminolysis. Among these methods, widely employed methods are glycolysis and aminolysis due to their simplicity and adaptability in synthetic processes. The review explores the role of zinc catalysts in the PET depolymerization, with an emphasis on the latest advancements in this field. Zinc catalysts, known for their Lewis acidic nature, are capable of activating ester bonds using ionic liquids, nanoparticles, complexes, salts, porous materials and nanocomposites. Both homogeneous and heterogeneous zinc catalysts are discussed briefly in this comprehensive review.

Keywords

Polyethylene terephthalate Chemical recycling Zinc catalyst Glycolysis Aminolysis Depolymerization
MURUGAN, A., VISWANATHAN, V., RAVIKUMAR, D., & VAJIRAVELU, S. (2023). Zinc Catalysts: Unlocking the Sustainable Transformation of Post-Consumer PET Waste through Chemical Recycling. Asian Journal of Chemistry, 35(10), 2301–2311. https://doi.org/10.14233/ajchem.2023.28206
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