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Vol. 35 No. 10 (2023): Vol 35 Issue 10, 2023

Copyright (c) 2023 Mrinal Sarkar

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An Ammonium Cation Included Dinuclear Cd(II) Complex and A Face-Shared Octahedral Dinuclear Cd(II) Complex with N2O Donor Tridentate Schiff base Ligand

https://doi.org/10.14233/ajchem.2023.28221
Mrinal Sarkar
Department of Chemistry, Derozio Memorial College, Rajarhat Road, P.O. R. Gopalpur, Kolkata-700136, India
https://orcid.org/0000-0002-4263-5181

Corresponding Author(s) : Mrinal Sarkar

msarkar81@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 10 (2023): Vol 35 Issue 10, 2023

Abstract

One face-shared octahedral Cd(II) complex and one ammonium cation included Cd(II) complex have been examined with the N2O donor monoanionic Schiff-base ligand 4-methyl-2,6-bis(((phenylmethyl)imino)methyl)phenol (HL) having a central phenoxide unit. The configuration of the cadmium coordination geometries is responsible for varying modes of ligand binding and structures. The gas phase geometry of complex 1 has been optimized by density functional theory. In CH3OH, the reaction between HL and Cd(NO3)2·4H2O in the presence of triethylamine produces a tris-L clipped face-shared octahedral dinuclear complex [Cd2(μ-L)3]·(OH) (1). Use of Cd(NO3)2·4H2O and NH4SCN in CH3OH in the absence of triethylamine leads to the synthesis of [Cd2(μ-L)2(μ1,1-NCS)(μ-NH4 +)(NCS)2] (2), which contains a NH4 + cation at its center. Changes in co-ligands have an ability to regulate the synthesis of these two Cd(II) complexes, effectively allowing selfassembly to be directed. Three types of bridges of Cd(OPh)3Cd and Cd(OPh)2(μ1,1-NCS)(μ- H4
+)Cd in 1 and 2 are responsible for the Cd···Cd separations of 3.324 and 3.432 Å, respectively.

Keywords

Tris(μ-phenoxido) bridging Thiocyanato bridging Ammonium cation Cd(II) complex Crystal structure DFT
Sarkar, M. (2023). An Ammonium Cation Included Dinuclear Cd(II) Complex and A Face-Shared Octahedral Dinuclear Cd(II) Complex with N2O Donor Tridentate Schiff base Ligand. Asian Journal of Chemistry, 35(10), 2430–2438. https://doi.org/10.14233/ajchem.2023.28221
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