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Vol. 31 No. 8 (2019): Vol 31 Issue 8

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Enhanced Adsorption of Methylene Blue and Congo Red from Aqueous Solutions by MCM-41/HKUST-1 Composites

https://doi.org/10.14233/ajchem.2019.21935
D.O. Sulistiono
Department of Chemistry, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia
E. Santoso
Department of Chemistry, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia
R. Ediati
Department of Chemistry, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia

Corresponding Author(s) : R. Ediati

ratna.ediati@gmail.com

Asian Journal of Chemistry, Vol. 31 No. 8 (2019): Vol 31 Issue 8

Abstract

Impregnation of mesoporous silica MCM-41 on metal organic framework type HKUST-1 or often called CuBTC (BTC = 1,3,5-benzenetricarboxylate) has been successfully carried out by solvothermal methods in a solvent mixture of water, ethanol and N,N-dimethylformamide (DMF). The XRD patterns of the obtained solids showed that MCM-41/HKUST-1 composites had the same crystalline phase as pure as HKUST-1. SEM images revealed that the impregnation of the mesoporous silica to HKUST-1 did not alter the surface morphology of the original HKUST-1, which had octahedral shapes. In addition, the thermal stability of the MCM-41/HKUST-1 composites reached 302 °C, increased by 292 °C in comparison to the HKUST-1, even though the impregnation process resulted in a decreased in the specific surface area of the composites. Furthermore, MCM-41/HKUST-1 composites showed outstanding performance as adsorbent of methylene blue and Congo red in aqueous solutions. Results of adsorption studies showed that a pseudo-second order kinetics and Langmuir isotherm were observed for both types of dyes.

Keywords

Methylene blue Congo red HKUST-1 MCM-41 Composite Adsorbent Adsorption capacity
Sulistiono, D., Santoso, E., & Ediati, R. (2019). Enhanced Adsorption of Methylene Blue and Congo Red from Aqueous Solutions by MCM-41/HKUST-1 Composites. Asian Journal of Chemistry, 31(8), 1675–1682. https://doi.org/10.14233/ajchem.2019.21935
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