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Vol. 34 No. 9 (2022): Vol 34 Issue 9

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Speed of Sound, Density, Viscosity and Related Thermodynamic Excess Properties of Binary Liquid Mixtures Containing Butyl Carbitol with 1-Butanol, Toluene and Diethylmalonate at 308.15 and 318.15 K

https://doi.org/10.14233/ajchem.2022.23785
U. Revathi
Department of Chemistry, St. Joseph’s College (Autonomous) (Affiliated to Bharathidasan University, Tiruchirappalli), Tiruchirappalli-620002, India
A. Rose Venis
Department of Chemistry, St. Joseph’s College (Autonomous) (Affiliated to Bharathidasan University, Tiruchirappalli), Tiruchirappalli-620002, India

Corresponding Author(s) : A. Rose Venis

rosevenis@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 9 (2022): Vol 34 Issue 9

Abstract

In present communication, measurements of experimental density, viscosity and ultrasonic velocity of binary liquid mixtures of butyl carbitol with 1-butanol, toluene and diethylmalonate have been carried out at 308.15 and 318.15 K at atmospheric pressure over the entire composition range of mole fractions. To study the intermolecular interactions present in these liquid mixtures, thermodynamic parameters like VE, ΔKS, Δη, ΔLf, ΔVf and ΔZ have been calculated. The excess functions and their deviations from ideality have also been correlated using Redlich-Kister type polynomial equation by the method of least-squares. The variations of thermodynamic parameters with composition and temperature have been discussed in terms of molecular interaction in these liquid mixtures. Further, IR spectra of these liquid mixtures have also been recorded and the obtained results have been used to analyze the mixing behaviour of the components.

Keywords

Butyl carbitol Molecular interaction Ultrasonic sound Thermodynamic parameters
Revathi, U., & Rose Venis, A. (2022). Speed of Sound, Density, Viscosity and Related Thermodynamic Excess Properties of Binary Liquid Mixtures Containing Butyl Carbitol with 1-Butanol, Toluene and Diethylmalonate at 308.15 and 318.15 K. Asian Journal of Chemistry, 34(9), 2274–2280. https://doi.org/10.14233/ajchem.2022.23785
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References
  1. B. Satheesh, D. Sreenu and T.S. Jyostna, Chem. Data. Coll., 28, 100448 (2020); https://doi.org/10.1016/j.cdc.2020.100448
  2. M.B. Jalali, A. Jouyban, H. Shekari and S.N. Mirheydari, Iran. J. Chem. Chem. Eng., 39, 231 (2020); https://doi.org/10.30492/IJCCE.2020.34833
  3. K.U. Sivakami, S. Vaideeswaran and A. Rosevenis, J. Environ. Nanotechnol., 7, 22 (2018); https://doi.org/10.13074/jent.2018.09.183319
  4. M. Zaoui-Djelloul-Daouadji, L. Bendiaf, I. Bahadur, D. Ramjugernath, A. Negadi, E.E. Ebenso and L. Negadi, Thermochim. Acta, 611, 47 (2015); https://doi.org/10.1016/j.tca.2015.04.032
  5. H.E. Hoga and R.B. Tôrres, J. Chem. Thermodyn., 43, 1104 (2011); https://doi.org/10.1016/j.jct.2011.02.018
  6. K. Umasivakami, S. Vaideeswaran and A. Rosevenis, J. Serb. Chem. Soc., 83, 1131 (2018); https://doi.org/10.2298/JSC170829056U
  7. P. Prabhu, U. Revathy and A.R. Venis, Asian J. Chem., 30, 1325 (2018); https://doi.org/10.14233/ajchem.2018.21233
  8. U. Revathi, K. Uma Sivakami and P. Prabhu, World J. Pharm. Pharm. Sci., 6, 857 (2017).
  9. S. Felixa, U. Sivakami and R. Venis, World J. Pharm. Pharm. Sci., 5, 1602 (2016).
  10. U. Revathi and A.R. Venis, J. Emerg. Technol. Innov. Res., 6, 254 (2019).
  11. D. Ubagaramary, K. Kesavaswamy and M. Enoch, Orient. J. Chem., 32, 321 (2016); https://doi.org/10.13005/ojc/320136
  12. A. Ali and M. Tariq, J. Mol. Liq., 128, 50 (2006); https://doi.org/10.1016/j.molliq.2005.09.002
  13. H. Kumar and Akanksha, J. Chem. Thermodyn., 149, 106166 (2020); https://doi.org/10.1016/j.jct.2020.106166.
  14. A.R. Venis and X.R. Rajkumar, Asian J. Chem., 26, 4711 (2014); https://doi.org/10.14233/ajchem.2014.16182
  15. S.S. Sastry, S. Babu, T. Vishwam and H.S. Tiong, J. Therm. Anal. Calorim., 116, 923 (2014); https://doi.org/10.1007/s10973-013-3570-9
  16. S. Bahadur Alisha, S. Nafeesabanu, K.S.V. Krishna Rao, M.C.S. Subha and K. Chowdoji Rao, Indian J. Adv. Chem. Sci., 5, 142 (2017).
  17. G. Prakash Dubey and L. Dhingra, J. Chem. Thermodyn., 149, 106161(2020); https://doi.org/10.1016/j.jct.2020.106161
  18. M. Lifi, J. Lorenzo, F. Aguilar, N. Muñoz-Rujas, E.A. Montero, Y. Chhiti and F.E.M. Alaoui, J. Chem. Thermodyn., 153, 106306 (2021); https://doi.org/10.1016/j.jct.2020.106306
  19. L. Bendiaf, I. Bahadur, A. Negadi, P. Naidoo, D. Ramjugernath and L. Negadi, Thermochim. Acta, 599, 13 (2015); https://doi.org/10.1016/j.tca.2014.11.009
  20. C. Ramana, A.B.V.K. Kumar, A.S. Kumar, M.A. Kumar and M.K. Moodley, Thermochim. Acta, 566, 130 (2013); https://doi.org/10.1016/j.tca.2013.05.022
  21. R. Martinez, J.A. Gonzalez, I.G. de la Fuente and J.C. Cobos, J. Chem. Eng. Data, 45, 1036 (2000); https://doi.org/10.1021/je000144t
  22. S.B. Alisha, S.N. Banu, K.S.V. Krishna Rao, M.C.S. Subha and K.C. Rao, Indian J. Adv. Chem. Sci., 5, 148 (2017).
  23. R. Rajalakshmi, S. Ravikumar, K. Sivakumar and V. Pandiyan, Chem. Data Coll., 24, 100299 (2019); https://doi.org/10.1016/j.cdc.2019.100299
  24. A. Pal and A. Kumar, Fluid Phase Equilib., 143, 241 (1998); https://doi.org/10.1016/S0378-3812(97)00221-5
  25. I. Mozo, I.G. de la Fuente, J.A. González and J.C. Cobos, J. Chem. Eng. Data, 52, 2086 (2007); https://doi.org/10.1021/je700281z
  26. S. Kumar and P. Jeevanandham, J. Mol. Liq., 174, 34 (2012); https://doi.org/10.1016/j.molliq.2012.07.025
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