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Green and Low-Cost Synthesis of TiO2 Nanoparticles for Methanol Detection
Corresponding Author(s) : Narayana Ashwath
Asian Journal of Chemistry,
Vol. 34 No. 8 (2022): Vol 34 Issue 8, 2022
Abstract
TiO2 nanoparticles synthesis using Ficus benghalensis leaf extract via green synthesis approach, were characterized using XRD, FTIR, EDAX analysis and SEM. The present study explores the use of as-synthesized TiO2 nanoparticles for the detection of methanol by spin-coating as-synthesized TiO2 nanoparticles (~ 100 nm thickness) over n-type Si substrate as an active material with Au sputtered electrodes (~ 60 nm). The change in resistivity and electrical conductivity when exposed to the analyte clearly evidenced the detection at low operating temperature is recorded. The response curve of transient resistance vs. time was recorded at different working temperatures (50-200 ºC) and the device tested multiple times exhibited the same behaviour affirming the reproducibility with stability of thin film sensor is reported.
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- R. Abdel-Karim, Y. Reda and A. Abdel-Fattah, J. Electrochem. Soc., 167, 037554 (2020); https://doi.org/10.1149/1945-7111/ab67aa
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- A. Ruiz Puigdollers, P. Schlexer, S. Tosoni and G. Pacchioni, ACS Catal., 7, 6493 (2017); https://doi.org/10.1021/acscatal.7b01913
References
R. Abdel-Karim, Y. Reda and A. Abdel-Fattah, J. Electrochem. Soc., 167, 037554 (2020); https://doi.org/10.1149/1945-7111/ab67aa
J. Jeevanandam, A. Barhoum, Y.S. Chan, A. Dufresne and M.K. Danquah, Beilstein J. Nanotechnol., 9, 1050 (2018); https://doi.org/10.3762/bjnano.9.98
S.G. Surya, B.S.N. Ashwath, S. Mishra, K. A.R.B, A.B. Sastry, P. B.L.v, D. Rangappa and V.R. Rao, Sens. Actuators B Chem., 235, 378 (2016); https://doi.org/10.1016/j.snb.2016.05.096
A. Narayana, S.A. Bhat, A. Fathima, S.V. Lokesh, S.G. Surya and C.V. Yelamaggad, RSC Adv., 10, 13532 (2020); https://doi.org/10.1039/D0RA00478B
M. Chung, G. Fortunato and N. Radacsi, J.R. Soc. Interface, 16, 20190217 (2019); https://doi.org/10.1098/rsif.2019.0217
Z. Liu, S. Li, G. Ge, Y. Li, C. Zhao, H. Zhang and Z. Yang, RSC Adv., 9, 5377 (2019); https://doi.org/10.1039/C8RA10036E
N. Ashwath, S.U. Kumar, N. Tarannum and S.V. Lokesh, Sensors Lett., 17, 581 (2019); https://doi.org/10.1166/sl.2019.4113
H. Lu, L. Xiong, H. Liu, M. Yu, Z. Shen, F. Li and X. You, Org. Biomol. Chem., 7, 2554 (2009); https://doi.org/10.1039/b902912e
K.P. Gattu, K. Ghule, A.A. Kashale, V.B. Patil, D.M. Phase, R.S. Mane, S.H. Han, R. Sharma and A.V. Ghule, RSC Adv., 5, 72849 (2015); https://doi.org/10.1039/C5RA13513C
A. Narayana, N. Tarannum, M.S. Shaik, B.N. Shobha, R.M. Sundar and S.V. Lokesh, Adv. Mater. Res., 1159, 67 (2020); https://doi.org/10.4028/www.scientific.net/AMR.1159.67
S. Kim, H. Park, S. Choo, S. Baek, Y. Kwon, N. Liu, J.Y. Yang, C.-W. Yang, G. Yoo and S. Kim, Commun Mater., 1, 86 (2020); https://doi.org/10.1038/s43246-020-00086-y
V.N. Kalpana and R.V. Devi, Bioinorg. Chem. Appl., 2018, 3569758 (2018); https://doi.org/10.1155/2018/3569758
S. Iravani, Green Chem., 13, 2638 (2011); https://doi.org/10.1039/c1gc15386b
N.M. Noah, J. Nanomater., 2020, 8855321 (2020); https://doi.org/10.1155/2020/8855321
G. Balanagireddy, A. Narayana and M. Roopa, Asian J. Chem., 33, 31 (2020); https://doi.org/10.14233/ajchem.2021.22908
S. Sungur, Handbook of Nanomaterials and Nanocomposites for Energy and Environmental Applications, pp. 1–18 (2020).
N. Chen, D. Deng, Y. Li, X. Liu, X. Xing, X. Xiao and Y. Wang, Sci. Rep., 7692, 1 (2017); https://doi.org/10.1038/s41598-017-08074-y
L. Xie, Z. Li, L. Sun, B. Dong, Q. Fatima, Z. Wang and A.A. Haidry, Front. Mater., 6, 184 (2019); https://doi.org/10.3389/fmats.2019.00184
K. Indira, U.K. Mudali, T. Nishimura and N. Rajendran, J. Bio Tribocorros., 1, 28 (2015); https://doi.org/10.1007/s40735-015-0024-x
N. Asim, S. Ahmadi, M.A. Alghoul, F.Y. Hammadi, K. Saeedfar and K. Sopian, Int. J. Photoenergy, 2014, 518156 (2014); https://doi.org/10.1155/2014/518156
F. Mironyuk, L.M. Soltys, T.R. Tatarchuk and K.O. Savka, Phys. Chem. Solid State, 21, 462 (2020); https://doi.org/10.15330/pcss.21.3.462-477
H. Zhang, X. Wang, N. Li, J. Xia, Q. Meng, J. Ding and J. Lu, RSC Adv., 8, 34241 (2018); https://doi.org/10.1039/C8RA06681G
S. Bagheri, K. Shameli and S.B. Abd Hamid, J. Chem., 2013, 848205 (2013); https://doi.org/10.1155/2013/848205
F. Faghihzadeh, N.M. Anaya, L.A. Schifman and V. Oyanedel-Craver, Nanotechnol. Environ. Eng., 1, 1 (2016); https://doi.org/10.1007/s41204-016-0001-8
J. Singh, T. Dutta, K.-H. Kim, M. Rawat, P. Samddar and P. Kumar, J. Nanobiotechnology, 16, 84 (2018); https://doi.org/10.1186/s12951-018-0408-4
T. Dey and D. Naughton, J. Sol-Gel Sci. Technol., 77, 1 (2016); https://doi.org/10.1007/s10971-015-3879-x
M. Letiche, M. Hallot, M. Huvé, T. Brousse, P. Roussel and C. Lethien, Chem. Mater., 29, 6044 (2017); https://doi.org/10.1021/acs.chemmater.7b01921
M.T. Greiner and Z.-H. Lu, NPG Asia Mater., 5, e55 (2013); https://doi.org/10.1038/am.2013.29
S.W. Lee, J.M. Kim, W. Park, H. Lee, G.R. Lee, Y. Jung, Y.S. Jung and J.Y. Park, Nat. Commun., 12, 40 (2021); https://doi.org/10.1038/s41467-020-20293-y
A. Ruiz Puigdollers, P. Schlexer, S. Tosoni and G. Pacchioni, ACS Catal., 7, 6493 (2017); https://doi.org/10.1021/acscatal.7b01913