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Vol. 34 No. 8 (2022): Vol 34 Issue 8, 2022

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Cellulose Nanofibrils Production from Sugarcane Bagasse: A Comparative Study between Low Energy Selective Oxidation Method and Stone Milling Fibrillation

https://doi.org/10.14233/ajchem.2022.23667
Nguyen Chau Giang
School of Chemical Engineering, Hanoi University of Science and Technology, Hanoi, Vietnam
Vu Minh Duc
School of Chemical Engineering, Hanoi University of Science and Technology, Hanoi, Vietnam

Corresponding Author(s) : Vu Minh Duc

duc.vuminh@hust.edu.vn

Asian Journal of Chemistry, Vol. 34 No. 8 (2022): Vol 34 Issue 8, 2022

Abstract

Sugarcane bagasse (SCB), an abundant agro-industrial residue in Vietnam, was used as a raw material to produce cellulose nanofibrils (CNF). First, SCB pulp was obtained from the raw material of bagasse using a two-fraction method, soda treatment followed by bleaching with Javel solution. Then, the SCB pulp was converted into nano-sized cellulose fibers by subjected to low energy, economical treatment of TEMPO-mediated oxidation. A traditional mechanical method of fibrillation SCB pulp, stone grinding was done for comparison, the produced nanocellulose is referred to as MeSCB. The nanocellulose fibers refer as TOSCB obtained from the TEMPO oxidation process were characterized in terms of carboxyl content, morphology, crystallinity and thermal stability. The degree of fibrillation and the dimension of the two obtained nanocelluloses was determined by applying FE-SEM observations combined with an image processing application, ImageJ. The results show that the MeSCB were much less nanofibrillated than the corresponding TOSCB material but less toxic.

Keywords

Nanocellulose Stone grinding Sugarcane bagasse TEMPO-oxidation
Chau Giang, N., & Minh Duc, V. (2022). Cellulose Nanofibrils Production from Sugarcane Bagasse: A Comparative Study between Low Energy Selective Oxidation Method and Stone Milling Fibrillation. Asian Journal of Chemistry, 34(8), 2017–2024. https://doi.org/10.14233/ajchem.2022.23667
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