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Vol. 34 No. 7 (2022): Vol 34 Issue 7, 2022

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Iron Capped Spent Tea Leaves as Nano-Adsorbent for Removal of Eriochrome Black T from Aqueous Phase

https://doi.org/10.14233/ajchem.2022.23776
Rehana Baiju Mampilly
Department of Chemistry, Hemchandracharya North Gujarat University, Patan-384265, India
Amanullakhan Pathan
Department of Chemistry, Shri Sarvajanik P.G. Science College, Mehsana-384001, India
Chetan G. Prajapati
Department of Humanities and Science, Government Engineering College, Palanpur-385001, India
C.P. Bhasin
Department of Chemistry, Hemchandracharya North Gujarat University, Patan-384265, India

Corresponding Author(s) : Amanullakhan Pathan

amankhan255@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 7 (2022): Vol 34 Issue 7, 2022

Abstract

In present study, the removal of Eriochrome black T dye by iron nanoparticles prepared through tea leaves extract has been investigated. Synthesized iron capped nanoparticles were characterized by FTIR spectroscopy, X-ray diffraction (XRD), high-resolution transmission electron microscopy (HR-TEM) and field emission gun scanning electron microscopy (FEG-SEM) with EDAX. The X-ray diffraction patterns revealed that iron nanoparticles exhibited an amorphous nature. Scanning electron microscopy exhibited clearly spherical shape of iron nanoparticles. The transmission electron microscopy (HR-TEM) of iron nanoparticles shows the particle size in the range of 30-40 nm. Further, the degradation of Eriochrome black T dye was studied. To obtain the optimal conditions for the dye degradation, the effect of various experimental parameters, like the proportion of adsorbent, pH, the concentration of dye and contact time on the rate of reaction was studied. Adsorptions of Eriochrome black T dye follow pseudo-first-order kinetics. It was found that the dye degradation showed best results in the presence of sunlight at a pH of 3, Eriochrome black T dye concentration 50 ppm with 0.60 g of adsorbent. At 29 ± 1 ºC, the maximum removal of dye was achieved within 90 min.

Keywords

Adsorption Iron nanoparticles Tea leaves extract Eriochrome black T dye
Baiju Mampilly, R., Pathan, A., G. Prajapati, C., & Bhasin, C. (2022). Iron Capped Spent Tea Leaves as Nano-Adsorbent for Removal of Eriochrome Black T from Aqueous Phase. Asian Journal of Chemistry, 34(7), 1814–1820. https://doi.org/10.14233/ajchem.2022.23776
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