Copyright (c) 2022 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis, Characterization and Structural Analysis of Cobaloximes Complexes
Corresponding Author(s) : M. Amutha Selvi
Asian Journal of Chemistry,
Vol. 34 No. 6 (2022): Vol 34 Issue 6
Abstract
A series of bioactive cobalt(III) complexes were synthesized with bidentate ligand have been investigated as vitamin B12 models. The experiment was two pot snythesis, in the first part was green microcrystalline dihalo(dimethylglyoximato)cobalt(III) and second part was brown microcrystalline halo(pyridine based ligand) cobaloximes. Final part of synthesized complexes was characterized by IR, electronic and NMR spectral studies. Infrared spectra of metal complexes indicated the formation of Co-N axial bond and Co-N equatorial bond. Thermal analysis revealed that the Co(III) complexes were stable up to 350 ºC. The experimental results of antimicrobial were showed good zone of inhibition towards selected microbes.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- Z. Biyiklioglu, G. Dilber and H. Kantekin, Transition Met. Chem., 31, 979 (2006); https://doi.org/10.1007/s11243-006-0092-3
- S. Mirra, M. Strianese, C. Pellecchia, V. Bertolasi, G. Monaco and S. Milione, Inorg. Chim. Acta, 444, 202 (2016); https://doi.org/10.1016/j.ica.2016.01.040
- A. Bhattacharjee, M. Chavarot-Kerlidou, J.L. Dempsey, H.B. Gray, E. Fujita, J.T. Muckerman, M. Fontecave, V. Artero, G.M. Arantes and M.J. Field, ChemPhysChem, 15, 2951 (2014); https://doi.org/10.1002/cphc.201402398
- A. Panagiotopoulos, K. Ladomenou, D. Sun, V. Artero and A.G. Coutsolelos, Dalton Trans., 45, 6732 (2016); https://doi.org/10.1039/C5DT04502A
- D. Dolui, S. Khandelwal, P. Majumder and A. Dutta, Chem. Commun., 56, 8166 (2020); https://doi.org/10.1039/D0CC03103H
- M. Erdem-Tunçmen, F. Karipcin, M. Atis and S. Perçin-Özkorucuklu, J. Organomet. Chem., 10, 756 (2014); https://doi.org/10.1016/j.jorganchem.2014.01.023
- Y. Jadegoud, O.B. Ijare, N.N. Mallikarjuna, S.D. Angadi and B.H.M. Mruthyunjayaswamy, J. Indian Chem. Soc., 79, 921 (2002).
- P. Jothi, C. Revathi, A. Dayalan, P. Ramesh and A. Subiapandia, Acta Crystallogr. Sect. E Struct. Rep. Online, 64, m300 (2008); https://doi.org/10.1107/S1600536807068407
- C. Lopez, S. Alvarez, X. Solans and M. Font-Altaba, Inorg. Chem., 25, 2962 (1986); https://doi.org/10.1021/ic00237a009
- N. Lu, W.H. Chang, W.H. Tu and C.K. Li, Chem. Commun., 47, 7227 (2011); https://doi.org/10.1039/C1CC11556A
- D.R. Lantero and M.E. Welker, J. Organomet. Chem., 656, 217 (2002); https://doi.org/10.1016/S0022-328X(02)01596-6
- S.C. Nayak, K.K. Sahoo and P.K. Das, J. Anal. Appl. Pyrol., 70, 699 (2003); https://doi.org/10.1016/S0165-2370(03)00041-X
- T.M. Brown, A.T. Dronsfield, J.H. Fowler and S.W. Hill, Inorg. Chim. Acta, 299, 277 (2000); https://doi.org/10.1016/S0020-1693(99)00494-6
- A. Dayalan and V.R. Vijayaraghavan, Indian J .Chem., 40A, 959 (2001).
- E.C. Kornfeld, J. Org. Chem., 16, 131 (1951); https://doi.org/10.1021/jo01141a020
- N. Navaneetha, P.A. Nagarjun and S. Satyanarayana, J. Chem. Sci., 119, 29 (2007); https://doi.org/10.1007/s12039-007-0005-9
- P.O. Kane, Nature, 195, 495 (1962); https://doi.org/10.1038/195495a0
References
Z. Biyiklioglu, G. Dilber and H. Kantekin, Transition Met. Chem., 31, 979 (2006); https://doi.org/10.1007/s11243-006-0092-3
S. Mirra, M. Strianese, C. Pellecchia, V. Bertolasi, G. Monaco and S. Milione, Inorg. Chim. Acta, 444, 202 (2016); https://doi.org/10.1016/j.ica.2016.01.040
A. Bhattacharjee, M. Chavarot-Kerlidou, J.L. Dempsey, H.B. Gray, E. Fujita, J.T. Muckerman, M. Fontecave, V. Artero, G.M. Arantes and M.J. Field, ChemPhysChem, 15, 2951 (2014); https://doi.org/10.1002/cphc.201402398
A. Panagiotopoulos, K. Ladomenou, D. Sun, V. Artero and A.G. Coutsolelos, Dalton Trans., 45, 6732 (2016); https://doi.org/10.1039/C5DT04502A
D. Dolui, S. Khandelwal, P. Majumder and A. Dutta, Chem. Commun., 56, 8166 (2020); https://doi.org/10.1039/D0CC03103H
M. Erdem-Tunçmen, F. Karipcin, M. Atis and S. Perçin-Özkorucuklu, J. Organomet. Chem., 10, 756 (2014); https://doi.org/10.1016/j.jorganchem.2014.01.023
Y. Jadegoud, O.B. Ijare, N.N. Mallikarjuna, S.D. Angadi and B.H.M. Mruthyunjayaswamy, J. Indian Chem. Soc., 79, 921 (2002).
P. Jothi, C. Revathi, A. Dayalan, P. Ramesh and A. Subiapandia, Acta Crystallogr. Sect. E Struct. Rep. Online, 64, m300 (2008); https://doi.org/10.1107/S1600536807068407
C. Lopez, S. Alvarez, X. Solans and M. Font-Altaba, Inorg. Chem., 25, 2962 (1986); https://doi.org/10.1021/ic00237a009
N. Lu, W.H. Chang, W.H. Tu and C.K. Li, Chem. Commun., 47, 7227 (2011); https://doi.org/10.1039/C1CC11556A
D.R. Lantero and M.E. Welker, J. Organomet. Chem., 656, 217 (2002); https://doi.org/10.1016/S0022-328X(02)01596-6
S.C. Nayak, K.K. Sahoo and P.K. Das, J. Anal. Appl. Pyrol., 70, 699 (2003); https://doi.org/10.1016/S0165-2370(03)00041-X
T.M. Brown, A.T. Dronsfield, J.H. Fowler and S.W. Hill, Inorg. Chim. Acta, 299, 277 (2000); https://doi.org/10.1016/S0020-1693(99)00494-6
A. Dayalan and V.R. Vijayaraghavan, Indian J .Chem., 40A, 959 (2001).
E.C. Kornfeld, J. Org. Chem., 16, 131 (1951); https://doi.org/10.1021/jo01141a020
N. Navaneetha, P.A. Nagarjun and S. Satyanarayana, J. Chem. Sci., 119, 29 (2007); https://doi.org/10.1007/s12039-007-0005-9
P.O. Kane, Nature, 195, 495 (1962); https://doi.org/10.1038/195495a0