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Vol. 34 No. 6 (2022): Vol 34 Issue 6

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Synthesis and Characterization of Disodium Aquabis(malonato)oxovanadate(IV)

https://doi.org/10.14233/ajchem.2022.23746
Dipesh Ghosh
Department of Chemistry, Vivekananda Mission Mahavidyalaya, Chaitanyapur, Haldia-721645, India
Douglas R. Powell
Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Room 208, Norman, Oklahoma 73019-3051 USA
J. David Van Horn
Department of Chemistry, University of Missouri-Kansas City, 5110 Rockhill Rd., Kansas City, MO 64110-2446, USA

Corresponding Author(s) : Dipesh Ghosh

dipesh105@hotmail.com

Asian Journal of Chemistry, Vol. 34 No. 6 (2022): Vol 34 Issue 6

Abstract

The complex, disodium aquabis(malonato)oxovanadate(IV) monohydrate, has been synthesized and its structure determined by X-ray diffraction analysis. The geometry around the metal is octahedral and the two malonate ligands are coordinated in a trans-arrangement with respect to one another, forming an equatorial plane, with oxo and aqua ligands occupying the axial positions. The V=O bond length is 1.596(2) Å and the four equatorial V–O distances range between 1.995(2) and 2.012(2) Å. An intensive network of weak hydrogen bonds is observed between crystalline water molecules and between oxygen atoms of the anion and sodium cations.

Keywords

Vanadium(IV) Oxovanadate(IV) complexes Malonic acid X-ray structure Electron spin resonance
Ghosh, D., R. Powell, D., & David Van Horn, J. (2022). Synthesis and Characterization of Disodium Aquabis(malonato)oxovanadate(IV). Asian Journal of Chemistry, 34(6), 1570–1574. https://doi.org/10.14233/ajchem.2022.23746
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