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Vol. 34 No. 5 (2022): Vol 34 Issue 5, 2022

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Synthesis and Characterization of Molybdenum Incorporated Cubic Mesoporous Materials and the Study of Catalytic Activity of SBA-1 and MCM-48

https://doi.org/10.14233/ajchem.2022.23658
Dhanju Mani Pathak
Department of Chemistry, Nalbari College, Nalbari-781335, India
Kishor Kr Shah
Department of Chemistry, A.D.P. College, Nagaon-782002, India
Pankaj Kumar Ghosh
Department of Chemistry, Mangaldai College, Darrang-784125, India
Anup Kumar Talukdar
Department of Chemistry, Gauhati University, Guwahati-781014, India

Corresponding Author(s) : Dhanju Mani Pathak

dhanjumani@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 5 (2022): Vol 34 Issue 5, 2022

Abstract

In present work, a two step synthetic procedure for the synthesis of MCM-48 materials is proposed. A sample of Mo-MCM-48 with Si/Mo ratio 100 was synthesized applying the same procedure as applied for the synthesis of Si-MCM-48 materials, only difference was that ammonium hepta-molybdate was added as a source of molybdenum in the second step. Two samples of SBA-1 and Mo-SBA-1 were also synthesized. The XRD patterns of synthesized Si-MCM-48 and Mo-MCM-48 and that of SBA-1 and Mo-SBA-1 were in good agreement with those of reported data for the cubic MCM-48 and SBA-1 materials. The synthesized samples were further characterized by FT-IR (for phase formation), TGA (for thermal stability), N2 adsorption-desorption isotherm (for surface are, pore size and pore volume), UV-DRS (for insertion of Mo in the framework) and SEM (for morphology). The catalytic activity of synthesized MCM-48 was found to be better than SBA-1 for the esterification reaction of benzyl alcohol and acetic acid.

Keywords

Mesoporous materials MCM-48 SBA-1 Esterification reaction
Mani Pathak, D., Kr Shah, K., Kumar Ghosh, P., & Kumar Talukdar, A. (2022). Synthesis and Characterization of Molybdenum Incorporated Cubic Mesoporous Materials and the Study of Catalytic Activity of SBA-1 and MCM-48. Asian Journal of Chemistry, 34(5), 1189–1196. https://doi.org/10.14233/ajchem.2022.23658
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