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Vol. 34 No. 5 (2022): Vol 34 Issue 5, 2022

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Synthesis of Dibenzo[b,i]xanthene-5,7,12,14(13H)-tetraone using p-Toluenesulfonic Acid as Catalyst

https://doi.org/10.14233/ajchem.2022.23675
Kittappa Gunasundari
PG and Research Department of Chemistry, A.V.V.M. Sri Pushpam College, Poondi-613503, India
Manickam Pramesh
PG and Research Department of Chemistry, A.V.V.M. Sri Pushpam College, Poondi-613503, India
Selvaraj Jayanthi
PG and Research Department of Chemistry, A.V.V.M. Sri Pushpam College, Poondi-613503, India
Moorthy Vetriselvan
PG and Research Department of Chemistry, A.V.V.M. Sri Pushpam College, Poondi-613503, India
Sreedharan Helen Perci
PG and Research Department of Chemistry, A.V.V.M. Sri Pushpam College, Poondi-613503, India

Corresponding Author(s) : Manickam Pramesh

mprameshchemistry@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 5 (2022): Vol 34 Issue 5, 2022

Abstract

This methodology involves synthesis of dibenzo xanthene tetraone by one pot multicomponent reaction of 2-hydroxy-1,4-naphthoquinone and pyrazole aldehyde in presence of p-toluenesulfonic acid (PTSA) as catalyst in ethylene glycol at 75-95 ºC. This protocol provides excellent yields (80-90%) involving simple workup procedures and purification techniques. By using several spectroscopic techniques the compounds were characterized.

Keywords

Xanthene Pyrazole aldehydes 2-Hydroxy-1 4-naphthoquinone p-Toluenesulfonic acid
Gunasundari, K., Pramesh, M., Jayanthi, S., Vetriselvan, M., & Helen Perci, S. (2022). Synthesis of Dibenzo[b,i]xanthene-5,7,12,14(13H)-tetraone using p-Toluenesulfonic Acid as Catalyst. Asian Journal of Chemistry, 34(5), 1134–1138. https://doi.org/10.14233/ajchem.2022.23675
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