Issue

Vol. 34 No. 4 (2022): Vol 34 Issue 4, 2022

Copyright (c) 2022 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Electrochemical, Quantum Chemical and Surface Analysis Studies using Novel Schiff Bases for the Inhibition Mild Steel Corrosion in Sulphuric Acid Medium

https://doi.org/10.14233/ajchem.2022.23588
M. Ragu
PG and Research Department of Chemistry, Vivekananda College, Tiruvedakam West, Madurai-625234, India
P. Karuppasamy
Department of Chemistry, Dayananda Sagar College of Engineering, Bangalore-560078, India
J. Thirupathi
Department of Chemistry, Thiagarajar College, Madurai-625309, India
M. Ganesan
Department of Chemistry, Sri Vidhya College of Arts and Science, Virudhunagar-626005, India
T. Rajendran
Department of Chemistry, K.L.N. Arts and Sciences College, Pottapalayam, Sivagangai-630612, India
V.K. Sivasubramanian
PG and Research Department of Chemistry, Vivekananda College, Tiruvedakam West, Madurai-625234, India

Corresponding Author(s) : V.K. Sivasubramanian

sivavk1957@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 4 (2022): Vol 34 Issue 4, 2022

Abstract

The influence of two newly synthesized salophen Schiff bases, namely N,N′-bis(5-nitrosalicylidene)-1,2-phenylenediamine (BNSPD) and N,N′-bis(5-chlorosalicylidene)-o-phenylenediamine (BCSPD), for inhibiting mild steel corrosion was investigated using potentiodynamic polarization, weight loss and electrochemical impedance spectroscopy in 0.5 M H2SO4 media. The results indicated that the inhibition efficiency of the inhibitors increased and decreased with the increase in the inhibitor concentration and temperature, respectively. Potentiodynamic polarization measurements revealed that the two inhibitors exhibited mixed type. The standard free energy (ΔGºads) and equilibrium constant of adsorption (Kads) were calculated. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques were used to investigate the surface morphology of the mild steel in the absence and presence of inhibitors. DFT calculations were performed to correlate the molecular structure and quantum chemical parameters with inhibition performance.

Keywords

Corrosion inhibitors Mild steel Salophen Schiff bases Thermodynamics Adsorption isotherms
Ragu, M., Karuppasamy, P., Thirupathi, J., Ganesan, M., Rajendran, T., & Sivasubramanian, V. (2022). Electrochemical, Quantum Chemical and Surface Analysis Studies using Novel Schiff Bases for the Inhibition Mild Steel Corrosion in Sulphuric Acid Medium. Asian Journal of Chemistry, 34(4), 823–833. https://doi.org/10.14233/ajchem.2022.23588
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. A. Dehghani, G. Bahlakeh, B. Ramezanzadeh and M. Ramezanzadeh, Constr. Build. Mater., 245, 118464 (2020); https://doi.org/10.1016/j.conbuildmat.2020.118464
  2. P.S. Neriyana and V.D.P. Alva, Chem. Africa, 3, 1087 (2020); https://doi.org/10.1007/s42250-020-00190 z
  3. K. Muthukumarasamy, S. Pitchai, K. Devarayan and L. Nallathambi, Mater. Today Proc., 33, 2214 (2020); https://doi.org/10.1016/j.matpr.2020.06.533
  4. H. Lgaz, S.K. Saha, A. Chaouiki, K.S. Bhat, R. Salghi, Shubhalaxmi, P. Banerjee, I.H. Ali, M.I. Khan and I. M. Chung, Constr. Build. Mater., 233, 117320 (2020); https://doi.org/10.1016/j.conbuildmat.2019.117320
  5. D.K. Verma, A. Al Fantazi, C. Verma, F. Khan, A. Asatkar, C.M. Hussain and E.E. Ebenso, J. Mol. Liq., 314, 113651 (2020); https://doi.org/10.1016/j.molliq.2020.113651
  6. E.K. Ardakani, E. Kowsari and A. Ehsani, J. Colloids Surf., 586, 124195 (2020); https://doi.org/10.1016/j.colsurfa.2019.124195
  7. A. Thomas, M. Prajila, K.M. Shainy and A. Joseph, J. Mol. Liq., 312, 113369 (2020); https://doi.org/10.1016/j.molliq.2020.113369
  8. J. Narenkumar, P. Parthipan, U.R.N. Ayyakkannu, B.K.M. Giovanni and A. Rajasekar, J. Biotechnol., 7, 133 (2020); https://doi.org10.1007/s13205-017-0783-9
  9. M. Ouakki, M. Galai, S. Rbaa, A.S. Abousalem, B. Lakhrissi, M.E. Touhami and M. Cherkaoui, J. Mol. Liq., 319, 114063 (2020); https://doi.org/10.1016/j.molliq.2020.114063
  10. A. Dehghani, G. Bahlakeh, B. Ramezanzadeh and M. Ramezanzadeh, J. Mol. Liq., 279, 603 (2019); https://doi.org/10.1016/j.molliq.2019.02.010
  11. J. Vicente, F. Calderón, A. Santos, D. Marquina and S. Benito, Int. J. Mol. Sci., 22, 1196 (2021); https://doi.org/10.3390/ijms22031196
  12. C. Verma, E.E. Ebenso, M.A. Quraishi and C.M. Hussain, J. Mater. Adv., 2, 3806 (2021); https://doi.org/10.1039/D0MA00681E
  13. P. Parthipan, P. Elumalai, J. Narenkumar, L.L. Machuca, K. Murugan, O.P. Karthikeyan and A. Rajasekar, Int. Biodeterior. Biodegrad., 132, 66 (2018); https://doi.org/10.1016/j.ibiod.2018.05.005
  14. T. Sathiyapriya, G. Rathika and M. Dhandapani, J. Adhes. Sci. Technol., 33, 2443 (2019); https://doi.org/10.1080/01694243.2019.1645261
  15. A.K. Singh and M.A. Quraishi, Int. J. Electrochem. Sci., 7, 3222 (2012).
  16. M. Solomon and S.A. Umoren, J. Environ. Chem. Eng., 3, 1812 (2015); https://doi.org/10.1016/j.jece.2015.05.018
  17. K.R. Ansari, D.S. Chauhan, M.A. Quraishi, M.A.J. Mazumder and A. Singh, Int. J. Biol. Macromol., 144, 305 (2020); https://doi.org/10.1016/j.ijbiomac.2019.12.106
  18. M. Kashmitha Muthamma, Preethi KumariM.M.Lavanya,M.,Suma and A.Rao, J. Bio- and Tribo., 7, 10 (2021); https://doi.org/10.1007/s40735-020-00439-7
  19. A. Al-Amiery, T.A. Salman, K.F. Alazawi, L.M. Shaker, A.A.H. Kadhum and M.S. Takriff, Int. J. Low-Carbon Technol., 15, 202 (2020); https://doi.org/10.1093/ijlct/ctz074
  20. M. Hanoon, A. Resen, L. Shaker, A. Kadhum and A. Al-Amiery, Biointerface Res. Appl. Chem., 11, 9735 (2021); https://doi.org/10.33263/BRIAC112.97359743
  21. M.V. Fiori-Bimbi, P.E. Alvarez, H. Vaca and C.A. Gervasi, Corros. Sci., 92, 192 (2015); https://doi.org/10.1016/j.corsci.2014.12.002
  22. G. Sigircik, T. Tüken and M. Erbil, Corros. Sci., 102, 437 (2016); https://doi.org/10.1016/j.corsci.2015.10.036
  23. P.R. Ammal, M. Prajila and A. Joseph, Egypt. J. Pet., 27, 823 (2018); https://doi.org/10.1016/j.ejpe.2017.12.004
  24. Z. Tao, S. Zhang, W. Li and B. Hou, Corros. Sci., 51, 2588 (2009); https://doi.org/10.1016/j.corsci.2009.06.042
  25. M. Yadav, L. Gope, N. Kumari and P. Yadav, J. Mol. Liq., 216, 78 (2016); https://doi.org/10.1016/j.molliq.2015.12.106
  26. A. Dutta, S.K. Saha, P. Banerjee and D. Sukul, Corros. Sci., 98, 541 (2015); https://doi.org/10.1016/j.corsci.2015.05.065
  27. A. Popova, M. Christov and A. Vasilev, Corros. Sci., 94, 70 (2015); https://doi.org/10.1016/j.corsci.2015.01.039
  28. M. Yadav, R. Sinha, S. Kumar, I. Bahadur and E.E. Ebenso, J. Mol. Liq., 208, 322 (2015); https://doi.org/10.1016/j.molliq.2015.05.005
  29. E.S. Meresht, T.S. Farahani and J. Neshati, Eng. Fail. Anal., 18, 963 (2011); https://doi.org/10.1016/j.engfailanal.2010.11.014
  30. E.S. Meresht, T.S. Farahani and J. Neshati, Corros. Sci., 54, 36 (2012); https://doi.org/10.1016/j.corsci.2011.08.052
  31. A. Madhankumar and N. Rajendran, Synth. Met., 162, 176 (2012); https://doi.org/10.1016/j.synthmet.2011.11.028
  32. J. Saranya, P. Sounthari, K. Parameswari and S. Chitra, Measurement, 77, 175 (2016); https://doi.org/10.1016/j.measurement.2015.09.008
  33. B. Xu, Y. Ji, X. Zhang, X. Jin, W. Yang and Y. Chen, J. Taiwan Inst. Chem. Eng., 59, 526 (2016); https://doi.org/10.1016/j.jtice.2015.08.020
  34. S.J. Alaneme, O. Olusegun and O.T. Adelowo, Alex. Eng. J., 55, 673 (2016); https://doi.org/10.1016/j.aej.2015.10.009
  35. A. Stoyanova, G. Petkova and S.D. Peyerimhoff, Chem. Phys., 279, 1 (2002); https://doi.org/10.1016/S0301-0104(02)00408-1
  36. N.O. Obi-Egbedi, I.B. Obot and M.I. El-Khaiary, J. Mol. Struct., 1002, 86 (2011); https://doi.org/10.1016/j.molstruc.2011.07.003
  37. H.M. Abd El-Lateef, V.M. Abbasov, L.I. Aliyeva, E.E. Qasimov and I.T. Ismayilov, Mater. Chem. Phys., 142, 502 (2013); https://doi.org/10.1016/j.matchemphys.2013.07.044
  38. P. Mourya, P. Singh, R.B. Rastogi and M.M. Singh, Appl. Surf. Sci., 380, 141 (2016); https://doi.org/10.1016/j.apsusc.2016.01.263
  39. D. Zhang, Y. Tang, S. Qi, D. Dong, H. Cang and G. Lu, Corros. Sci., 102, 517 (2016); https://doi.org/10.1016/j.corsci.2015.10.002
  40. K. Krishnaveni and J. Ravichandran, J. Electroanal. Chem., 10, 1016 (2014); https://doi.org/10.1016/j.jelechem.2014.09.032
  41. D.K. Singh, S. Kumar, G. Udayabhanu and R.P. John, J. Mol. Liq., 216, 738 (2016); https://doi.org/10.1016/j.molliq.2016.02.012
  42. J.E. Del Bene, W.B. Person and K. Szczepaniak, J. Phys. Chem., 99, 10705 (1995); https://doi.org/10.1021/j100027a005
  43. F. El-Taib Heakal, A.S. Fouda and M.S. Radwan, Mater. Chem. Phys., 125, 26 (2011); https://doi.org/10.1016/j.matchemphys.2010.08.067
  44. S.E. Nataraja, T.V. Venkatesha, K. Manjunatha, B. Poojary, M.K. Pavithra and H.C. Tandon, Corros. Sci., 53, 2651 (2011); https://doi.org/10.1016/j.corsci.2011.05.004
  45. I. Danaee, O. Ghasemi, G.R. Rashed, M.R. Avei and M.H. Maddahy, J. Mol. Struct., 1035, 247 (2013); https://doi.org/10.1016/j.molstruc.2012.11.013
  46. S.-H. Yoo, Y.-W. Kim, K. Chung, N.-K. Kim and J.-S. Kim, Ind. Eng. Chem. Res., 52, 10880 (2013); https://doi.org/10.1021/ie303092j
  47. F.K. Ekuma Ul-Ekanem and H.O. Chukwuemeka-Okorie, Int. J. Chem. Stud., 6, 2599 (2018).
  48. H.N. Deepakumari, H.D. Revanasiddappa and K.N.N. Prasad, Vietnam J. Chem., 57, 641 (2019); https://doi.org/10.1002/vjch.201900120
  49. M.A. Bedair, M.M.B. El-Sabbah, A.S. Fouda and H.M. Elaryian, Corros. Sci., 128, 54 (2017); https://doi.org/10.1016/j.corsci.2017.09.016
  50. A. Dennis Raj, M. Jeeva, M. Shankar, G. Venkatesa Prabhu, M. Vimalan and I. Vetha Potheher, J. Mol. Struct., 1147, 763 (2017); https://doi.org/10.1016/j.molstruc.2017.06.133
  51. T. Zhang, R. Zhou, P. Wang, A. Mai-Prochnow, R. McConchie, W. Li, R. Zhou, E.W. Thompson, K. Ostrikov and P.J. Cullen, Chem. Eng. J., 421, 127730 (2016); https://doi.org/10.1016/j.cej.2020.127730
  52. A.D. Becke, J. Chem. Phys., 98, 5648 (1993); https://doi.org/10.1063/1.464913
  53. C. Lee, W. Yang and R.G. Parr, Phys. Rev. B, 37, 785 (1988); https://doi.org/10.1103/PhysRevB.37.785
  54. R. Ditchfield, W.J. Hehre and J.A. Pople, J. Chem. Phys., 54, 724 (1971); https://doi.org/10.1063/1.1674902
  55. I.B. Obot and Z.M. Gasem, Corros. Sci., 83, 359 (2014); https://doi.org/10.1016/j.corsci.2014.03.008
  56. U. Nazir, Z. Akhter, N.K. Janjua, M.A. Asghar, S. Kanwal, T.M. Butt, A. Sani, F. Liaqat, R. Hussain and F.U. Shah, RSC Adv., 10, 7585 (2020); https://doi.org/10.1039/C9RA10692H
  57. N.M. EL Basiony, A. Elgendy, H. Nady, M.A. Migahed and E.G. Zaki, RSC Adv., 9, 10473 (2019); https://doi.org/10.1039/C9RA00397E
  58. A. Al-Amiery, T.A. Salman, K.F. Alazawi, L.M. Shaker, A.A.H. Kadhum and M.S. Takriff, Int. J. Low Carbon Technol., 15, 202 (2020); https://doi.org/10.1093/ijlct/ctz074
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 1 Download : 1