Issue

Vol. 34 No. 4 (2022): Vol 34 Issue 4, 2022

Copyright (c) 2022 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

One-Pot Super Critical Fluid Synthesis of Spinel MnFe2O4 Nanoparticles and its Application as Anode Material for Mg-ion Battery

https://doi.org/10.14233/ajchem.2022.23642%20
Vinay Gangaraju
Department of Applied Sciences (Nanotechnology), Centre for Post-Graduation Studies, Visvesvaraya Technological University, Muddenahalli Campus, Chikkaballapura-562101, India
Tathagata Sardar
Department of Applied Sciences (Nanotechnology), Centre for Post-Graduation Studies, Visvesvaraya Technological University, Muddenahalli Campus, Chikkaballapura-562101, India
Kunal Roy
Department of Applied Sciences (Nanotechnology), Centre for Post-Graduation Studies, Visvesvaraya Technological University, Muddenahalli Campus, Chikkaballapura-562101, India
Mahesh Shastri
Department of Applied Sciences (Nanotechnology), Centre for Post-Graduation Studies, Visvesvaraya Technological University, Muddenahalli Campus, Chikkaballapura-562101, India ; Department of Electronics & Communication, Nagarjuna College of Engineering & Technology, Devanahalli, Bengaluru-562164, India
Manjunath Shetty
Department of Applied Sciences (Nanotechnology), Centre for Post-Graduation Studies, Visvesvaraya Technological University, Muddenahalli Campus, Chikkaballapura-562101, India ; Department of Aeronautical and Automobile Engineering, Manipal Institute of Technology, Manipal Academy of Higher Education (MAHE), Manipal-576104, India
Murthy Muniyappa
Department of Applied Sciences (Nanotechnology), Centre for Post-Graduation Studies, Visvesvaraya Technological University, Muddenahalli Campus, Chikkaballapura-562101, India ; Department of Electronics & Communication, Nagarjuna College of Engineering & Technology, Devanahalli, Bengaluru-562164, India
Hiroaki Kobayashi
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980- 8577, Japan
Takaaki Tomai
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980- 8577, Japan
Ananda Kumar C S
Department of Applied Sciences (Nanotechnology), Centre for Post-Graduation Studies, Visvesvaraya Technological University, Muddenahalli Campus, Chikkaballapura-562101, India
Prasanna D. Shivaramu
Department of Applied Sciences (Nanotechnology), Centre for Post-Graduation Studies, Visvesvaraya Technological University, Muddenahalli Campus, Chikkaballapura-562101, India
Dinesh Rangappa
Department of Applied Sciences (Nanotechnology), Centre for Post-Graduation Studies, Visvesvaraya Technological University, Muddenahalli Campus, Chikkaballapura-562101, India

Corresponding Author(s) : Prasanna D. Shivaramu

prasuds@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 4 (2022): Vol 34 Issue 4, 2022

Abstract

In present study, the synthesis of spinel MnFe2O4 nanoparticles using a facile one-pot super critical fluid method and their application for Mg-ion battery application as anode materials is reported. The synthesized MnFe2O4 nanoparticles were well characterized for their structure and morphology using XRD, SEM, TEM and EDS analysis. The average particle size of materials was less than 50 nm with spinel structure. The main feature of magnesium ion battery is its high specific capacity and large volumetric energy density, which makes it a promising alternative to Li-ion batteries. The spinel MnFe2O4 material has been used as an anode material for Mg-ion batteries. At different C-rates (0.05C to 2C), electrochemical charge-discharge behaviour has been observed. In first cycle of the phase-pure spinel structured anode, an initial specific capacity of 195.82 mAh/g, 139.70 mAh/g, 25.04 mAh/g and 14.16 mAh/g were obtained at C rate of 0.05C, 0.1C, 1C and 2C, respectively. A possible phase conversion reaction of the anode resulted in a decrease in specific capacity with increasing C-rate.

Keywords

Mg-ion battery Spinel MnFe2O4 Anode Conversion reaction Charge-discharge performance
Gangaraju, V., Sardar, T., Roy, K., Shastri, M., Shetty, M., Muniyappa, M., … Rangappa, D. (2022). One-Pot Super Critical Fluid Synthesis of Spinel MnFe2O4 Nanoparticles and its Application as Anode Material for Mg-ion Battery. Asian Journal of Chemistry, 34(4), 989–994. https://doi.org/10.14233/ajchem.2022.23642
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. Y. Liu, N. Zhang, C. Yu, L. Jiao and J. Chen, Nano Lett., 16, 3321 (2016); https://doi.org/10.1021/acs.nanolett.6b00942
  2. Q.D. Truong, M. Kempaiah Devaraju, P.D. Tran, Y. Gambe, K. Nayuki, Y. Sasaki and I. Honma, Chem. Mater., 29, 6245 (2017); https://doi.org/10.1021/acs.chemmater.7b01252
  3. M.-C. Lin, M. Gong, B. Lu, Y. Wu, D.-Y. Wang, M. Guan, M. Angell, C. Chen, J. Yang, B.-J. Hwang and H. Dai, Nature, 520, 324 (2015); https://doi.org/10.1038/nature14340
  4. A. Ponrouch, C. Frontera, F. Bardé and M.R. Palacín, Nat. Mater., 15, 169 (2016); https://doi.org/10.1038/nmat4462
  5. J. Muldoon, C.B. Bucur and T. Gregory, Chem. Rev., 114, 11683 (2014); https://doi.org/10.1021/cr500049y
  6. S. Tepavcevic, Y. Liu, D. Zhou, B. Lai, J. Maser, X. Zuo, H. Chan, P. Král, C.S. Johnson, V. Stamenkovic, N.M. Markovic and T. Rajh, ACS Nano, 9, 8194 (2015); https://doi.org/10.1021/acsnano.5b02450
  7. D. Aurbach, Z. Lu, A. Schechter, Y. Gofer, H. Gizbar, R. Turgeman, Y. Cohen, M. Moshkovich and E. Levi, Nature, 407, 724 (2000); https://doi.org/10.1038/35037553
  8. L.F. Wan and D. Prendergast, J. Am. Chem. Soc., 136, 14456 (2014); https://doi.org/10.1021/ja505967u
  9. T.J. Carter, R. Mohtadi, T.S. Arthur, F. Mizuno, R. Zhang, S. Shirai and J.W. Kampf, Angew. Chem. Int. Ed., 53, 3173 (2014); https://doi.org/10.1002/anie.201310317
  10. P. Novák, R. Imhof and O. Haas, Electrochim. Acta, 45, 351 (1999); https://doi.org/10.1016/S0013 4686(99)00216-9
  11. J. Muldoon, C.B. Bucur, A.G. Oliver, T. Sugimoto, M. Matsui, H.S. Kim, G.D. Allred, J. Zajicek and Y. Kotani, Energy Environ. Sci., 5, 5941 (2012); https://doi.org/10.1039/c2ee03029b
  12. E. Levi, Y. Gofer and D. Aurbach, Chem. Mater., 22, 860 (2010); https://doi.org/10.1021/cm9016497
  13. Z. Lu, A. Schechter, M. Moshkovich and D. Aurbach, J. Electroanal. Chem., 466, 203 (1999); https://doi.org/10.1016/S0022-0728(99)00146-1
  14. P. Poizot, S. Laruelle, S. Grugeon, L. Dupont and J.-M. Tarascon, Nature, 407, 496 (2000); https://doi.org/10.1038/35035045
  15. Y. Pan, Y. Zhang, X. Wei, C. Yuan, J. Yin, D. Cao and G. Wang, Electrochim. Acta, 109, 89 (2013); https://doi.org/10.1016/j.electacta.2013.07.026
  16. N. Sivakumar, S.R.P. Gnanakan, K. Karthikeyan, S. Amaresh, W.S. Yoon, G.J. Park and Y.S. Lee, J. Alloys Compd., 509, 7038 (2011); https://doi.org/10.1016/j.jallcom.2011.03.123
  17. D.C. Bock, K.R. Tallman, H. Guo, C. Quilty, S. Yan, P.F. Smith, B. Zhang, D.M. Lutz, A.H. McCarthy, M.M. Huie, V. Burnett, A.M. Bruck, A.C. Marschilok, E.S. Takeuchi, P. Liu and K.J. Takeuchi, Phys. Chem.
  18. Chem. Phys., 22, 26200 (2020); https://doi.org/10.1039/D0CP02322A
  19. C. Kim, P.J. Phillips, B. Key, T. Yi, D. Nordlund, Y.-S. Yu, R.D. Bayliss, S.-D. Han, M. He, Z. Zhang, A.K. Burrell, R.F. Klie and J. Cabana, Adv. Mater., 27, 3377 (2015); https://doi.org/10.1002/adma.201500083
  20. M. Liu, Z. Rong, R. Malik, P. Canepa, A. Jain, G. Ceder and K.A. Persson, Energy Environ. Sci., 8, 964 (2015); https://doi.org/10.1039/C4EE03389B
  21. Z. Feng, X. Chen, L. Qiao, A.L. Lipson, T.T. Fister, L. Zeng, C. Kim, T. Yi, N. Sa, D.L. Proffit, A.K. Burrell, J. Cabana, B.J. Ingram, M.D. Biegalski, M.J. Bedzyk and P. Fenter, ACS Appl. Mater. Interfaces, 7, 28438 (2015); https://doi.org/10.1021/acsami.5b09346
  22. H.D. Yoo, I. Shterenberg, Y. Gofer, G. Gershinsky, N. Pour and D. Aurbach, Energy Environ. Sci., 6, 2265 (2013); https://doi.org/10.1039/c3ee40871j
  23. M. Mao, T. Gao, S. Hou and C. Wang, Chem. Soc. Rev., 47, 8804 (2018); https://doi.org/10.1039/C8CS00319J
  24. S. Okamoto, T. Ichitsubo, T. Kawaguchi, Y. Kumagai, F. Oba, S. Yagi, K. Shimokawa, N. Goto, T. Doi and E. Matsubara, Adv. Sci., 8, 1500072 (2015); https://doi.org/10.1002/advs.201500072
  25. R. Yokozaki, H. Kobayashi and I. Honma, Ceram. Int., 47, 10236 (2021); https://doi.org/10.1016/j.ceramint.2020.10.184
  26. M.M. Thackeray, W.I.F. David, P.G. Bruce and J.B. Goodenough, Mater. Res. Bull., 18, 461 (1983); https://doi.org/10.1016/0025-5408(83)90138-1
  27. M.M. Thackeray, Prog. Solid State Chem., 25, 1 (1997); https://doi.org/10.1016/S0079-6786(97)81003 5
  28. K. Amine, H. Tukamoto, H. Yasuda and Y. Fujita, J. Electrochem. Soc., 143, 1607 (1996); https://doi.org/10.1149/1.1836686
  29. Y. Terada, K. Yasaka, F. Nishikawa, T. Konishi, M. Yoshio and I. Nakai, J. Solid State Chem., 156, 286 (2001); https://doi.org/10.1006/jssc.2000.8990
  30. D. Liu, Y. Lu and J.B. Goodenough, J. Electrochem. Soc., 157, A1269 (2010); https://doi.org/10.1149/1.3491365
  31. H. Kawai, M. Nagata, H. Kageyama, H. Tukamoto and A.R. West, Electrochim. Acta, 45, 315 (1999); https://doi.org/10.1016/S0013-4686(99)00213-3
  32. Q.D. Truong, H. Kobayashi, K. Nayuki, Y. Sasaki and I. Honma, Solid State Ion., 344, 115136 (2020); https://doi.org/10.1016/j.ssi.2019.115136
  33. Q.D. Truong, H. Kobayashi and I. Honma, RSC Adv., 9, 36717 (2019); https://doi.org/10.1039/C9RA04936C
  34. T.S. Arthur, R. Zhang, C. Ling, P.-A. Glans, X. Fan, J. Guo and F. Mizuno, ACS Appl. Mater. Interfaces, 6, 7004 (2014); https://doi.org/10.1021/am5015327
  35. M. Okubo, E. Hosono, J. Kim, M. Enomoto, N. Kojima, T. Kudo, H. Zhou and I. Honma, J. Am. Chem. Soc., 129, 7444 (2007); https://doi.org/10.1021/ja0681927
  36. M. Okubo, Y. Mizuno, H. Yamada, J. Kim, E. Hosono, H. Zhou, T. Kudo and I. Honma, ACS Nano, 4, 741 (2010); https://doi.org/10.1021/nn9012065
  37. M. Fracchia, M. Manzoli, U. Anselmi-Tamburini and P. Ghigna, Scr. Mater., 188, 26 (2020); https://doi.org/10.1016/j.scriptamat.2020.07.002
  38. V.S. Zhandun and A.V. Nemtsev, Mater. Chem. Phys., 259, 124065 (2021); https://doi.org/10.1016/j.matchemphys.2020.124065
  39. A. Sankaramahalingam and J.B. Lawrence, Nano-Metal Chem., 42, 121 (2012); https://doi.org/10.1080/15533174.2011.609500
  40. W.B. Cross, L. Affleck, M.V. Kuznetsov, I.P. Parkin and Q.A. Pankhurst, J. Mater. Chem., 9, 2545 (1999); https://doi.org/10.1039/a904431k
  41. M.A. Ahmed, E. Ateia and F.M. Salem, J. Mater. Sci., 42, 3651 (2007); https://doi.org/10.1007/s10853 006-1349-0
  42. F.A. Radwan, M.A. Ahmed and G. Abdelatif, J. Phys. Chem. Solids, 64, 2465 (2003); https://doi.org/10.1016/j.jpcs.2003.08.003
  43. K. Shimokawa and T. Ichitsubo, Curr. Opin. Electrochem., 21, 93 (2020); https://doi.org/10.1016/j.coelec.2020.01.017
  44. N. Kitamura, Y. Tanabe, N. Ishida and Y. Idemoto, Chem. Commun., 55, 2517 (2019); https://doi.org/10.1039/C8CC09713E
  45. K. Shimokawa, H. Matsumoto and T. Ichitsubo, J. Phys. Chem. Lett., 9, 4732 (2018); https://doi.org/10.1021/acs.jpclett.8b02209
  46. Y. Kotani, R. Ise, K. Ishii, T. Mandai, Y. Oaki, S. Yagi and H. Imai, J. Alloys Compd., 739, 793 (2018); https://doi.org/10.1016/j.jallcom.2017.12.315
  47. T. Ichitsubo, S. Okamoto, T. Kawaguchi, Y. Kumagai, F. Oba, S. Yagi, N. Goto, T. Doi and E. Matsubara, J. Mater. Chem. A Mater. Energy Sustain., 3, 10188 (2015); https://doi.org/10.1039/C5TA01365H
  48. T. Ichitsubo, T. Adachi, S. Yagi and T. Doi, J. Mater. Chem., 21, 11764 (2011); https://doi.org/10.1039/c1jm11793a
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0