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A Study on 4-(4-Aminobenzene-1-sulfonyl)piperazin-1-yl)(furan-2-yl)methanone for the Prevention of Corrosion on Mild Steel in Acidic Medium
Corresponding Author(s) : P. Singaravelu
Asian Journal of Chemistry,
Vol. 34 No. 4 (2022): Vol 34 Issue 4, 2022
Abstract
Synthesized [4-(4-aminobenzene-1-sulfonyl)piperazin-1-yl)(furan-2-yl)methanone (4-4-ABSPFM), a novel organic compound was used as inhibitor on prevention of mild steel corrosion. Experiments were performed in 1 N HCl acidic medium by weight loss method and electrochemical analysis. On comparing the results, it reveals that the novel organic compound shows better inhibition efficiency on mild steel corrosion, which is more effective in 1 N HCl at three different temperatures. Electrochemical studies such as AC impedance and potentiodynamic polarization studies were proven the results by showing the inhibitor is a mixed type inhibitor in acidic medium. From the semi-micrograph obtained from SEM analysis shows a better efficiency of the inhibitor over the surface of the mild steel.
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- M.A. Quraishi, F.A. Ansari and D. Jamal, Mater. Chem. Phys., 77, 687 (2003); https://doi.org/10.1016/S0254-0584(02)00130-X
- C. Küstü, C.K. Emregül and O. Atakol, Corros. Sci., 49, 2800 (2007); https://doi.org/10.1016/j.corsci.2007.02.002
- M. Hosseini, S.F.L. Mertens, M. Ghorbani and M.R. Arshadi, Mater. Chem. Phys., 78, 800 (2003); https://doi.org/10.1016/S0254-0584(02)00390-5
- R. Solmaz, G. Kardas, B. Yazici and M. Erbil, Prot. Met., 41, 581 (2005); https://doi.org/10.1007/s11124-005-0083-3
- F. Bentiss, M. Lebrini, H. Vezin and M. Lagrenee, Mater. Chem. Phys., 87, 18 (2004); https://doi.org/10.1016/j.matchemphys.2004.05.040
- W. Li, Q. He, C. Pei and B. Hou, Electchim. Acta, 52, 6386 (2007); https://doi.org/10.1016/j.electacta.2007.04.077
- T.Y. Soror, H.A. El-Dahan and N.G. El-Sayed Ammer, J. Mater. Sci. Technol., 15, 559 (1999).
- H.-B. Fan, C.-Y. Fu, H.-L. Wang, X.-P. Guo and J.-S. Zheng, Br. Corros. J., 37, 122 (2002); https://doi.org/10.1179/000705902225004383
- A. Yurt, S. Ulutas and H. Dal, Appl. Surf. Sci., 253, 919 (2006); https://doi.org/10.1016/j.apsusc.2006.01.026
- A. Popova, M. Christov and A. Zwetanova, Corros. Sci., 49, 2131 (2007); https://doi.org/10.1016/j.corsci.2006.10.021
- G. Quartarone, L. Bonaldo and C. Tortato, Appl. Surf. Sci., 252, 8251 (2006); https://doi.org/10.1016/j.apsusc.2005.10.051
- G. Avci, Colloids Surf. A Physicochem. Eng. Asp., 317, 730 (2007); https://doi.org/10.1016/j.colsurfa.2007.12.009
- P. Venkatesan, B. Anand and P. Matheswaran, E-J. Chem., 6(s1), S438 (2009). https://doi.org/10.1155/2009/507383
- F. Bentiss, M. Traisnel and M. Lagrenee, Corros. Sci., 42, 127 (2000); https://doi.org/10.1016/S0010-938X(99)00049-9
- K.R. Ansari, M.A. Quraishi and A. Singh, Corros. Sci., 79, 5 (2014); https://doi.org/10.1016/j.corsci.2013.10.009
- G. Moretti, G. Quartarone, A. Tassan and A. Zingales, Electrochim. Acta, 41, 1971 (1996); https://doi.org/10.1016/0013-4686(95)00485-8
- R.H. Chaturvedi and R.S. Chaudhary, Corros. Prev. Control, 37, 53 (1990).
- S. Muralidharan, M.A. Quraishi and S.V.K. Iyer, Corros. Sci., 37, 1739 (1995); https://doi.org/10.1016/0010-938X(95)00068-U
- Y. Abboud, A. Abourriche, T. Saffaj, M. Berrada, M. Charrouf, A. Bennamara and H. Hannache, Desalination, 237, 175 (2009); https://doi.org/10.1016/j.desal.2007.12.031
- C.N. Igwe and U.C. Okoro, Org. Chem. Int., 2014, 419518 (2014); https://doi.org/10.1155/2014/419518
- M. Ozcan, J. Dehri and M. Erbil, Appl. Surf. Sci., 236, 155 (2004); https://doi.org/10.1016/j.apsusc.2004.04.017
- L.J. Berchmans, V. Sivan and S.V.K. Iyer, Mater. Chem. Phys., 98, 395 (2006); https://doi.org/10.1016/j.matchemphys.2005.09.053
- ASTM-G1-03, Standard Practice for Preparing, Cleaning and Evaluating Corrosion Test Specimens, Annual Book ASTM Standards, vol. 3, pp. 17-25 (2003).
- D.D. Macdonald, Electrochim. Acta, 51, 1376 (2006); https://doi.org/10.1016/j.electacta.2005.02.107
References
M.A. Quraishi, F.A. Ansari and D. Jamal, Mater. Chem. Phys., 77, 687 (2003); https://doi.org/10.1016/S0254-0584(02)00130-X
C. Küstü, C.K. Emregül and O. Atakol, Corros. Sci., 49, 2800 (2007); https://doi.org/10.1016/j.corsci.2007.02.002
M. Hosseini, S.F.L. Mertens, M. Ghorbani and M.R. Arshadi, Mater. Chem. Phys., 78, 800 (2003); https://doi.org/10.1016/S0254-0584(02)00390-5
R. Solmaz, G. Kardas, B. Yazici and M. Erbil, Prot. Met., 41, 581 (2005); https://doi.org/10.1007/s11124-005-0083-3
F. Bentiss, M. Lebrini, H. Vezin and M. Lagrenee, Mater. Chem. Phys., 87, 18 (2004); https://doi.org/10.1016/j.matchemphys.2004.05.040
W. Li, Q. He, C. Pei and B. Hou, Electchim. Acta, 52, 6386 (2007); https://doi.org/10.1016/j.electacta.2007.04.077
T.Y. Soror, H.A. El-Dahan and N.G. El-Sayed Ammer, J. Mater. Sci. Technol., 15, 559 (1999).
H.-B. Fan, C.-Y. Fu, H.-L. Wang, X.-P. Guo and J.-S. Zheng, Br. Corros. J., 37, 122 (2002); https://doi.org/10.1179/000705902225004383
A. Yurt, S. Ulutas and H. Dal, Appl. Surf. Sci., 253, 919 (2006); https://doi.org/10.1016/j.apsusc.2006.01.026
A. Popova, M. Christov and A. Zwetanova, Corros. Sci., 49, 2131 (2007); https://doi.org/10.1016/j.corsci.2006.10.021
G. Quartarone, L. Bonaldo and C. Tortato, Appl. Surf. Sci., 252, 8251 (2006); https://doi.org/10.1016/j.apsusc.2005.10.051
G. Avci, Colloids Surf. A Physicochem. Eng. Asp., 317, 730 (2007); https://doi.org/10.1016/j.colsurfa.2007.12.009
P. Venkatesan, B. Anand and P. Matheswaran, E-J. Chem., 6(s1), S438 (2009). https://doi.org/10.1155/2009/507383
F. Bentiss, M. Traisnel and M. Lagrenee, Corros. Sci., 42, 127 (2000); https://doi.org/10.1016/S0010-938X(99)00049-9
K.R. Ansari, M.A. Quraishi and A. Singh, Corros. Sci., 79, 5 (2014); https://doi.org/10.1016/j.corsci.2013.10.009
G. Moretti, G. Quartarone, A. Tassan and A. Zingales, Electrochim. Acta, 41, 1971 (1996); https://doi.org/10.1016/0013-4686(95)00485-8
R.H. Chaturvedi and R.S. Chaudhary, Corros. Prev. Control, 37, 53 (1990).
S. Muralidharan, M.A. Quraishi and S.V.K. Iyer, Corros. Sci., 37, 1739 (1995); https://doi.org/10.1016/0010-938X(95)00068-U
Y. Abboud, A. Abourriche, T. Saffaj, M. Berrada, M. Charrouf, A. Bennamara and H. Hannache, Desalination, 237, 175 (2009); https://doi.org/10.1016/j.desal.2007.12.031
C.N. Igwe and U.C. Okoro, Org. Chem. Int., 2014, 419518 (2014); https://doi.org/10.1155/2014/419518
M. Ozcan, J. Dehri and M. Erbil, Appl. Surf. Sci., 236, 155 (2004); https://doi.org/10.1016/j.apsusc.2004.04.017
L.J. Berchmans, V. Sivan and S.V.K. Iyer, Mater. Chem. Phys., 98, 395 (2006); https://doi.org/10.1016/j.matchemphys.2005.09.053
ASTM-G1-03, Standard Practice for Preparing, Cleaning and Evaluating Corrosion Test Specimens, Annual Book ASTM Standards, vol. 3, pp. 17-25 (2003).
D.D. Macdonald, Electrochim. Acta, 51, 1376 (2006); https://doi.org/10.1016/j.electacta.2005.02.107