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Vol. 34 No. 3 (2022): Vol 34 Issue 3, 2022

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Silica Supported Acids (HClO4-SiO2, KHSO4-SiO2) as Eco-friendly Reusable Catalysts for Bromodecarboxylation of α,β-Unsaturated Carboxylic Acids using KBr under Solvothermal and Solvent-Free Conditions

https://doi.org/10.14233/ajchem.2022.23457
Vijay Shekar Pulusu
Department of Chemistry, Osmania University, Hyderabad-500007, India
Chinna Rajanna Kamatala
Department of Chemistry, Osmania University, Hyderabad-500007, India
Umesh Kumar Utkoor
Department of Chemistry, Osmania University, Hyderabad-500007, India
Maasi Reddy Nagannagari
Department of Chemistry, Osmania University, Hyderabad-500007, India
Hemanth Sriram Yelike
Department of Chemistry, Osmania University, Hyderabad-500007, India
Samba Shiva Rao Arisha
Department of Chemistry, Maturi Venkata Subba Rao Engineering College, Nadergul, Hyderabad-501510, India
Yaku Gugulothu
Department of Chemistry, Osmania University, Hyderabad-500007, India

Corresponding Author(s) : Samba Shiva Rao Arisha

kcrajannaou@yahoo.com

Asian Journal of Chemistry, Vol. 34 No. 3 (2022): Vol 34 Issue 3, 2022

Abstract

A mild procedure has been developed for the bromodecarboxylation of α,β-carboxylic acids using nano silica supported SiO2-HClO4, SiO2-KHSO4 as catalysts and KBr as a bromine source in conventional solvothermal, ultrasonic assisted and solvent-free microwave assisted conditions. The α,β-unsaturated cinnamic acids were converted to corresponding β-bromo styrenes with high regioselectivity, while aliphatic α,β-unsaturated carboxylic acids afforded related β-bromo alkenes.

Keywords

HClO4-SiO2 HClO4-SiO2 KHSO4-SiO2 KHSO4-SiO2 Bromo decarboxylation Bromo decarboxylation α α β-Unsaturated carboxylic acids β-Unsaturated carboxylic acids
Shekar Pulusu, V., Rajanna Kamatala, C., Kumar Utkoor, U., Reddy Nagannagari, M., Sriram Yelike, H., Shiva Rao Arisha, S., & Gugulothu, Y. (2022). Silica Supported Acids (HClO4-SiO2, KHSO4-SiO2) as Eco-friendly Reusable Catalysts for Bromodecarboxylation of α,β-Unsaturated Carboxylic Acids using KBr under Solvothermal and Solvent-Free Conditions. Asian Journal of Chemistry, 34(3), 535–542. https://doi.org/10.14233/ajchem.2022.23457
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