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Vol. 34 No. 3 (2022): Vol 34 Issue 3, 2022

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A Novel Terpolymer Membrane-Based Electrode Sensor for Selective Determination of Cd(II) Ions

https://doi.org/10.14233/ajchem.2022.23701
Geetu Gambhir
Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College (University of Delhi), Govindpuri, Kalkaji, New Delhi-110019, India
Drashya Gautam
Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College (University of Delhi), Govindpuri, Kalkaji, New Delhi-110019, India
Laishram Saya
Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College (University of Delhi), Govindpuri, Kalkaji, New Delhi-110019, India ; Department of Chemistry, Sri Venkateswara College (University of Delhi), Dhaula Kuan, New Delhi-110021, India ; Department of Chemistry, Manipur University, Canchipur, Imphal-795003, India
Amit Kumar
Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College (University of Delhi), Govindpuri, Kalkaji, New Delhi-110019, India
Subodh Kumar
Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College (University of Delhi), Govindpuri, Kalkaji, New Delhi-110019, India
Aarushi Singh
Drug Discovery and Development Laboratory, Department of Chemistry, University of Delhi, Delhi-110007, India
Snigdha Singh
Drug Discovery and Development Laboratory, Department of Chemistry, University of Delhi, Delhi-110007, India
Ramesh Chandra
Drug Discovery and Development Laboratory, Department of Chemistry, University of Delhi, Delhi-110007, India
Sunita Hooda
Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College (University of Delhi), Govindpuri, Kalkaji, New Delhi-110019, India

Corresponding Author(s) : Ramesh Chandra

acbrdu@hotmail.com

Asian Journal of Chemistry, Vol. 34 No. 3 (2022): Vol 34 Issue 3, 2022

Abstract

A new polymeric membrane sensor for Cd(II) ion based on methyl acrylate-acrylonitrile-methyl methacrylate terpolymer as membrane carrier has been synthesized via atom transfer radical polymerization (ATRP) method at 60 ºC. Preliminary investigation with the membrane exhibited promising selectivity for Cd(II) ion with a slope of 32.02 mV/decade and the same could be estimated in the concentration range of 1 × 10-6 − 1 × 10-1 M in the working pH range of 4-6 for up to 90 days. The potentials generated across the membrane were reproducible and the response time was less than one minute. The electrode works well even in a partially non-aqueous media. The effect of surfactant and detergent on the working of Cd(II) selective electrode was also studied. A decrease in potential was observed in the presence of appreciable amount of surfactant and detergent. Addition of plasticisers was found to greatly improve the performance of membrane, best results being obtained with the membrane ratio (NaTPB:TP:TBP::1:100:06), exhibiting a working concentration range of 1 × 10-6 − 1 × 10-1 mol L-1 with a short response time of 10 s. The proposed sensor shows significantly good selectivity toward Cd(II) ion in comparison with some alkali, alkaline earth, transition and heavy metal ions. It was successfully employed as an indicator electrode in potentiometric titration of cadmium(II) ions against EDTA solution.

Keywords

Methyl methacrylate Terpolymer Sensor Cadmium(II) Ion selective electrode Membrane
Gambhir, G., Gautam, D., Saya, L., Kumar, A., Kumar, S., Singh, A., … Hooda, S. (2022). A Novel Terpolymer Membrane-Based Electrode Sensor for Selective Determination of Cd(II) Ions. Asian Journal of Chemistry, 34(3), 749–756. https://doi.org/10.14233/ajchem.2022.23701
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