Copyright (c) 2022 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Adsorption of Iron(II) and Cadmium(II) Ions Separately using Carbon Materials from Hazelnuts and Walnuts Waste Shells
Corresponding Author(s) : N. Ananiashvili
Asian Journal of Chemistry,
Vol. 34 No. 12 (2022): Vol 34 Issue 12, 2022
Abstract
An inexpensive and efficient carbon materials as adsorbents were obtained from hazelnuts and walnuts waste shells. Their adsorption capacity with respect to iron(II) and cadmium(II) ions was studied. The results show that the carbonaceous material obtained from hazelnut shells has the best adsorption capacity with respect to Fe2+ & Cd2+, which is not inferior to commercial activated carbon. Studies of iron (II) and cadmium(II) of various concentrations showed that within 20-30 min, the best extraction rate and adsorption for both metal ions were achieved with a solution of 0.0025 M. For Fe2+ ions, the adsorption value and extraction rate have achieved good results at pH = 3-5, and for Cd2+ ions at pH = 5-6. Furthermore, the prepared adsorbent exhibited the excellent adsorption abilities even in the presence of various metal ions and successfully used as sorbents for drinking and wastewater treatment without modification and activation.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- M. Osiñska, J. Sol-Gel Sci. Technol., 81, 678 (2017); https://doi.org/10.1007/s10971-016-4256-0
- N.R. Axtell, S.P.K. Sternberg and K. Claussen, Bioresour. Technol., 89, 41 (2003); https://doi.org/10.1016/S0960-8524(03)00034-8
- B.M.W.P.K. Amarasinghe and R.A. Williams, Chem. Eng. J., 132, 299 (2007); https://doi.org/10.1016/j.cej.2007.01.016
- A.I. Adejumoke, O.A. Babatunde, P.O. Abimbola, A. Adelani-Akande Tabitha, O.D. Adewumi and A.O. Toyin, Water Pollution: Effects, Prevention and Climatic Impact, IntechOpen, Chap. 3 (2018).
- M. El Tokhi, B.M. Amin and S.A. Alaabed, J. Pollution Effects Control., 5, 2 (2017).
- I. El-Nahhal, H. Al-Najar and Y. El-Nahhal, Am. J. Anal. Chem., 5, 655 (2014); https://doi.org/10.4236/ajac.2014.510073
- M.A. Barakat, Arab. J. Chem., 4, 361 (2011); https://doi.org/10.1016/j.arabjc.2010.07.019
- I.W. Maina, V. Obuseng and F. Nareetsile, J. Chem., 2016, 9312952 (2016); https://doi.org/10.1155/2016/9312952
- F. Fu and Q. Wang, J. Environ. Manage., 92, 407 (2011); https://doi.org/10.1016/j.jenvman.2010.11.011
- B.H. Hameed, A.T.M. Din and A.L. Ahmad, J. Hazard. Mater., 141, 819 (2007); https://doi.org/10.1016/j.jhazmat.2006.07.049
- Z.Y. Yao, J.H. Qi and L.H. Wang, J. Hazard. Mater., 174, 137 (2010); https://doi.org/10.1016/j.jhazmat.2009.09.027
- S. Hokkanen, A. Bhatnagar and M. Sillanpää, Water Res., 91, 156 (2016); https://doi.org/10.1016/j.watres.2016.01.008
- A. Sihem, M. Bencheikh Lehocine and H.A. Miniai, Energy Procedia, 18, 1145 (2012); https://doi.org/10.1016/j.egypro.2012.05.129
- V.B. Khusidman, V.J. Shoreham, T. Marsagishvili, A. Peikrishvili and G. Tatishvili, System and Method for Tire Conversion into Carbon Black, Liquid and Gaseous Products, US Patent 9,663,662B1 (2016).
- T. Marsagishvili, G. Tatishvili, N. Ananiashvili, M. Gachechiladze, J. Metreveli, Z. Samkharadze, E. Tskhakaia, N. Giorgadze, G. Megreli and M. Matchavariani, Method of Receive Sorbents from Waste containing Plastics and Cellulose, Georgian Patent 7309 B, GE +995 (2021).
- T. Marsagishvili, G. Tatishvili, N. Ananiashvili, N. Giorgadze, E. Tskhakaia, M. Gachechiladze, J. Metreveli and M. Machavariani, IFMBE Proc., 77, 97 (2020); https://doi.org/10.1007/978-3-030-31866-6_21
- N. Giorgadze, N. Ananiashvili, T. Marsagishvili, E. Tskhakaia, G. Tatishvili and M. Matchavariani, Adsorption of Cu++ Ions on Carbonaceous Sorbents, obtained from Secondary Raw Material, Publishing House “MERIDIANI” Tbilisi, pp. 257-264 (2020).
- N.V. Giorgadze, T.A. Marsagishvili, G.D. Tatishvili, N.Sh. Ananiashvili, E.T. Tskhakaia, M.P. Gachechiladze, J.A. Metreveli and M.N. Matchavariani, Int. J. Green Herbal Chem. Sec. A, 10, 101 (2021); https://doi.org/10.24214/IJGHC/GC/10/2/10108
- T. Marsagishvili, G. Tatishvili, N. Ananiashvili, N. Giorgadze, Z. Samkharadze, E. Tskhakaia, M. Gachechiladze, J. Metreveli and M. Machavariani, J. Electrical Eng., 6, 23 (2021).
- E.R. Ushakumary, PhD Thesis, Wastewater Treatment Using Low Cost Natural Adsorbents, Cochin University of Science and Technology, India (2013).
- M.W. Kaakani, Master’s Thesis, Heavy Metal Removal from Waste Water using Novel Adsorbent, American University of Sharjah (2012).
- E.I. Ugwu, O. Tursunov, D. Kodirov, L.M. Shaker, A.A. Al-Amiery, I. Yangibaeva and F. Shavkarov, IOP Conf. Ser. Earth Environ. Sci., 614, 012166 (2020); https://doi.org/10.1088/1755-1315/614/1/012166
- J.P. Holmberg, Master's Thesis Competitive Adsorption and Displacement Behaviour of Heavy Metals on Peat, Chalmers University of Technology, Göteborg, Sweden (2006).
- Handbook of a Chemist, Ionic Radii According to Belov and Bokiy. Inorganic Chemistry, Appendix 5, Tomsk (1997).
- J.M. Lezcano, F. Gonzalez, A. Ballester, M.L. Blazquez, J.A. Munoz and C. Garcia-Balboa, Chem. Ecol., 26, 1 (2010); https://doi.org/10.1080/02757540903468102
References
M. Osiñska, J. Sol-Gel Sci. Technol., 81, 678 (2017); https://doi.org/10.1007/s10971-016-4256-0
N.R. Axtell, S.P.K. Sternberg and K. Claussen, Bioresour. Technol., 89, 41 (2003); https://doi.org/10.1016/S0960-8524(03)00034-8
B.M.W.P.K. Amarasinghe and R.A. Williams, Chem. Eng. J., 132, 299 (2007); https://doi.org/10.1016/j.cej.2007.01.016
A.I. Adejumoke, O.A. Babatunde, P.O. Abimbola, A. Adelani-Akande Tabitha, O.D. Adewumi and A.O. Toyin, Water Pollution: Effects, Prevention and Climatic Impact, IntechOpen, Chap. 3 (2018).
M. El Tokhi, B.M. Amin and S.A. Alaabed, J. Pollution Effects Control., 5, 2 (2017).
I. El-Nahhal, H. Al-Najar and Y. El-Nahhal, Am. J. Anal. Chem., 5, 655 (2014); https://doi.org/10.4236/ajac.2014.510073
M.A. Barakat, Arab. J. Chem., 4, 361 (2011); https://doi.org/10.1016/j.arabjc.2010.07.019
I.W. Maina, V. Obuseng and F. Nareetsile, J. Chem., 2016, 9312952 (2016); https://doi.org/10.1155/2016/9312952
F. Fu and Q. Wang, J. Environ. Manage., 92, 407 (2011); https://doi.org/10.1016/j.jenvman.2010.11.011
B.H. Hameed, A.T.M. Din and A.L. Ahmad, J. Hazard. Mater., 141, 819 (2007); https://doi.org/10.1016/j.jhazmat.2006.07.049
Z.Y. Yao, J.H. Qi and L.H. Wang, J. Hazard. Mater., 174, 137 (2010); https://doi.org/10.1016/j.jhazmat.2009.09.027
S. Hokkanen, A. Bhatnagar and M. Sillanpää, Water Res., 91, 156 (2016); https://doi.org/10.1016/j.watres.2016.01.008
A. Sihem, M. Bencheikh Lehocine and H.A. Miniai, Energy Procedia, 18, 1145 (2012); https://doi.org/10.1016/j.egypro.2012.05.129
V.B. Khusidman, V.J. Shoreham, T. Marsagishvili, A. Peikrishvili and G. Tatishvili, System and Method for Tire Conversion into Carbon Black, Liquid and Gaseous Products, US Patent 9,663,662B1 (2016).
T. Marsagishvili, G. Tatishvili, N. Ananiashvili, M. Gachechiladze, J. Metreveli, Z. Samkharadze, E. Tskhakaia, N. Giorgadze, G. Megreli and M. Matchavariani, Method of Receive Sorbents from Waste containing Plastics and Cellulose, Georgian Patent 7309 B, GE +995 (2021).
T. Marsagishvili, G. Tatishvili, N. Ananiashvili, N. Giorgadze, E. Tskhakaia, M. Gachechiladze, J. Metreveli and M. Machavariani, IFMBE Proc., 77, 97 (2020); https://doi.org/10.1007/978-3-030-31866-6_21
N. Giorgadze, N. Ananiashvili, T. Marsagishvili, E. Tskhakaia, G. Tatishvili and M. Matchavariani, Adsorption of Cu++ Ions on Carbonaceous Sorbents, obtained from Secondary Raw Material, Publishing House “MERIDIANI” Tbilisi, pp. 257-264 (2020).
N.V. Giorgadze, T.A. Marsagishvili, G.D. Tatishvili, N.Sh. Ananiashvili, E.T. Tskhakaia, M.P. Gachechiladze, J.A. Metreveli and M.N. Matchavariani, Int. J. Green Herbal Chem. Sec. A, 10, 101 (2021); https://doi.org/10.24214/IJGHC/GC/10/2/10108
T. Marsagishvili, G. Tatishvili, N. Ananiashvili, N. Giorgadze, Z. Samkharadze, E. Tskhakaia, M. Gachechiladze, J. Metreveli and M. Machavariani, J. Electrical Eng., 6, 23 (2021).
E.R. Ushakumary, PhD Thesis, Wastewater Treatment Using Low Cost Natural Adsorbents, Cochin University of Science and Technology, India (2013).
M.W. Kaakani, Master’s Thesis, Heavy Metal Removal from Waste Water using Novel Adsorbent, American University of Sharjah (2012).
E.I. Ugwu, O. Tursunov, D. Kodirov, L.M. Shaker, A.A. Al-Amiery, I. Yangibaeva and F. Shavkarov, IOP Conf. Ser. Earth Environ. Sci., 614, 012166 (2020); https://doi.org/10.1088/1755-1315/614/1/012166
J.P. Holmberg, Master's Thesis Competitive Adsorption and Displacement Behaviour of Heavy Metals on Peat, Chalmers University of Technology, Göteborg, Sweden (2006).
Handbook of a Chemist, Ionic Radii According to Belov and Bokiy. Inorganic Chemistry, Appendix 5, Tomsk (1997).
J.M. Lezcano, F. Gonzalez, A. Ballester, M.L. Blazquez, J.A. Munoz and C. Garcia-Balboa, Chem. Ecol., 26, 1 (2010); https://doi.org/10.1080/02757540903468102