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Vol. 34 No. 11 (2022): Vol 34 Issue 11, 2022

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Preparation and Characteristics of Starch Nanocrystals as Corrosion Inhibitor: Experimental and Theoretical Studies

https://doi.org/10.14233/ajchem.2022.23944
Ahmed Neamah Thamer
The General Directorate of Educational in Najaf Al-Ashraf, Iraq
Lekaa Hussain Kadham
Department of Chemistry, Collage of Education for Girls, University of Kufa, Najaf, Iraq
Ismaeel M. Alwaan
Department of Chemical Engineering, College of Engineering, University of Kufa, Najaf, Iraq

Corresponding Author(s) : Ismaeel M. Alwaan

ismael.alsallami@uokufa.edu.iq

Asian Journal of Chemistry, Vol. 34 No. 11 (2022): Vol 34 Issue 11, 2022

Abstract

Technological advances have led to sophisticated computer software and programs, along with mathematical and experimental techniques, to envisage corrosion inhibition. Using potentiodynamic polarization measurements, weight loss techniques and quantum chemical calculations, the corrosion inhibition of mild steel was explored in 1 M HCl by employing novel inhibitor starch nanocrystals (SNCs). The structures of starch and its nanocrystals were investigated by FESEM, FTIR, AFM and TEM techniques. In presence of 0.5 g/L SNCs at 293 K, the maximum inhibition efficiency (%IE) was 67%. The results showed that the novel SNC inhibitor follows the Temkin adsorption isotherm. The activation energy, Gibbs free energy, enthalpy and entropy of adsorption were calculated. Quantum chemical calculations further helped to understand the SNC inhibition mechanism through density functional theory (DFT) to estimate possible active centres that could be responsible for SNC adsorption on the surface of mild steel. Moreover, quantum chemical descriptors were computed. The findings indicated that SNCs show a high efficiency for corrosion inhibition.

Keywords

Starch nanocrystals Corrosion inhibition Mild steel Hydrochloric acid Density functional theory
Neamah Thamer, A., Hussain Kadham, L., & M. Alwaan, I. (2022). Preparation and Characteristics of Starch Nanocrystals as Corrosion Inhibitor: Experimental and Theoretical Studies. Asian Journal of Chemistry, 34(11), 2854–2864. https://doi.org/10.14233/ajchem.2022.23944
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