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Vol. 27 No. 10 (2015): Vol 27 Issue 10

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Synthesis and Enzymatic Behaviour of Mono- and Dinuclear Complexes of Bivalent Transition Metal Ions with Schiff Base Derived from 2,6-Dibenzoyl-4-methylphenol and 2,6-Diaminopyridine

https://doi.org/10.14233/ajchem.2015.18996
Jagdish Chander
Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125 004, India
Anil Kumar
Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125 004, India
Sumona Kumari
Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125 004, India
S. Kumar
Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125 004, India
Meera
Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125 004, India
K.S. Dhindsa
Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University, Hisar-125 004, India

Corresponding Author(s) : Jagdish Chander

jakharjc@gmail.com

Asian Journal of Chemistry, Vol. 27 No. 10 (2015): Vol 27 Issue 10

Abstract

The synthesis of Schiff base ligand 13,27-dimethyl-2,10,16,24-tetraphenyl-3,9,17,23,31,32-hexaazapentacyclo[26.3.1.14,8.111,15.118,22]-dotriaconta-1(28),2,4(31),5,7,9,11,13,15(30),16,18,20,22(32),23,25(29),26-hexadecaen-29,30-diol (H2L) and its mono- and dinuclear complexes with VO(IV), Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) has been accomplished by both direct as well as template methods. The compounds have been characterized by elemental analyses, molecular weight determinations, molar conductance, room temperature magnetic moments, infrared, electronic and 1H NMR spectral data. The macrocyclic ligand complexes have been proposed to have distorted octahedral geometries around the metal ions. The mono- and dinuclear complexes have been evaluated for peroxidase-like activity.

Keywords

Schiff base Macrocyclic ligand Peroxidase-like activity
Chander, J., Kumar, A., Kumari, S., Kumar, S., Meera, ., & Dhindsa, K. (2015). Synthesis and Enzymatic Behaviour of Mono- and Dinuclear Complexes of Bivalent Transition Metal Ions with Schiff Base Derived from 2,6-Dibenzoyl-4-methylphenol and 2,6-Diaminopyridine. Asian Journal of Chemistry, 27(10), 3813–3817. https://doi.org/10.14233/ajchem.2015.18996
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