Synthesis, Crystal Structure of Two-Dimensional Porous Network [Zn(dmbdc)(py)]&middot;NMP}2n (py = Pyridine, NMP = N-Methyl-pyrrolidone, H2dmbdc = 2,5-Dimethylbenzenedicarboxylic Acid)

F.K. Wang; S.Y. Yang

doi:10.14233/ajchem.2015.17116

Issue

Vol. 27 No. 2 (2015): Vol 27 Issue 2

Issue Published : January 10, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Crystal Structure of Two-Dimensional Porous Network [Zn(dmbdc)(py)]·NMP}2n (py = Pyridine, NMP = N-Methyl-pyrrolidone, H2dmbdc = 2,5-Dimethylbenzenedicarboxylic Acid)

https://doi.org/10.14233/ajchem.2015.17116

F.K. Wang

College of Material and Chemical Engineering, Research Center for Solar Photovoltaic Material Development and Application, West An-hui University, Lu'an 237012, P.R. China

S.Y. Yang

Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P.R. China

Corresponding Author(s) : F.K. Wang

wangfangkuo2491@126.com

Asian Journal of Chemistry, Vol. 27 No. 2 (2015): Vol 27 Issue 2
Article Published : January 10, 2015

Abstract

A 2D porous coordination polymer with (4,4) network {[Zn(dmbdc)(py)]·NMP}_2n 1, (H₂dmbdc = 2,5-dimethylbenzenedicarboxylic acid, py = pyridine, NMP = N-methyl-pyrrolidone) crystallized in the triclinic, space group P-1, a = 9.9876(15), b = 10.975(7), c = 20.032(5) Å, a =77.23(3), b = 86.565(15), g = 67.90(3)°, Z = 2 and consists of paddle-wheel dinucleus Zinc SBUs coordinated with ancillary ligands pyridine in the two sides of (4,4) net. In the structure of 1, the paddle-wheel SBUs was connected with adjacent four SBUs through four dmbdc in the plane to form 2D sheet along a axis and two guest molecules NMP accommodated in the holes of 2D networks.

Keywords

Porous Network Paddle-whell SBUs Crystal structure

Wang, F., & Yang, S. (2015). Synthesis, Crystal Structure of Two-Dimensional Porous Network [Zn(dmbdc)(py)]·NMP}2n (py = Pyridine, NMP = N-Methyl-pyrrolidone, H2dmbdc = 2,5-Dimethylbenzenedicarboxylic Acid). Asian Journal of Chemistry, 27(2), 643–645. https://doi.org/10.14233/ajchem.2015.17116

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References

W.Q. Kan, B. Liu, J. Yang, Y.Y. Liu and J.F. Ma, Cryst. Growth Des., 12, 2288 (2012); doi:10.1021/cg2015644.

A. Morozan and F. Jaouen, Energy Environ. Sci., 5, 9269 (2012); doi:10.1039/c2ee22989g.

X.X. Lv, S.F. Tang, L.J. Li, J.J. Cai, C. Wang, X.X. Xu and X.B. Zhao, Eur. J. Inorg. Chem., 2013, 5081 (2013); doi:10.1002/ejic.201300714.

J.W. Zhang, C.H. Gong, L.L. Hou, A.X. Tian and X.L. Wang, J. Solid State Chem., 205, 104 (2013); doi:10.1016/j.jssc.2013.07.013.

R. Singh and P.K. Bharadwaj, Cryst. Growth Des., 13, 3722 (2013); doi:10.1021/cg400756z.

J. Zhao, D. Zhao, K. Peng, Y. Guo, S. Chen and J. Hu, Transition Met. Chem., 38, 771 (2013); doi:10.1007/s11243-013-9748-y.

D.C. Zhong and T.B. Lu, Sci. China Chem., 54, 1395 (2011); doi:10.1007/s11426-011-4358-z.

M.F. Wang, X.J. Hong, Q.G. Zhan, H.G. Jin, Y.T. Liu, Z.P. Zheng, S.H. Xu and Y.P. Cai, Dalton Trans., 41, 11898 (2012); doi:10.1039/c2dt31243c.

H.X. Sun, W.L. Xie, S.H. Lv, Y. Xu, Y. Wu, Y.M. Zhou, Z.M. Ma, M. Fang and H.K. Liu, Dalton Trans., 41, 7590 (2012); doi:10.1039/c2dt30611e.

L.N. Li, S.Y. Wang, T.L. Chen, Z.H. Sun, J.H. Luo and M.C. Hong, Cryst. Growth Des., 12, 4109 (2012); doi:10.1021/cg300617h.

P.O. Adelani and T.E. Albrecht-Schmitt, Inorg. Chem., 50, 12184 (2011); doi:10.1021/ic201945p.

H. Kwak, S.H. Lee, S.H. Kim, Y.M. Lee, B.K. Park, E.Y. Lee, Y.J. Lee, C. Kim, S.J. Kim and Y. Kim, Polyhedron, 27, 3484 (2008); doi:10.1016/j.poly.2008.08.010.

G.X. Liu, Y.Q. Huang, Q. Chu, T. Okamura, W.Y. Sun, H. Liang and N. Ueyama, Cryst. Growth Des., 8, 3233 (2008); doi:10.1021/cg701137d.

C.J. Milios, T.C. Stamatatos and S.P. Perlepes, Polyhedron, 25, 134 (2006); doi:10.1016/j.poly.2005.07.022.

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G.M. Sheldrick, SHELXS-97, Program for X-ray Crystal Structure Determination, University of Gottingen, Germany (1997).