Complexation Equilibria of Vitamin B9, Glycine Oligopeptides with Di- and Trivalent Metal Ions

Ahmed E. Fazary; Aisha Q. Rajhi

doi:10.14233/ajchem.2015.19060

Issue

Vol. 27 No. 10 (2015): Vol 27 Issue 10

Issue Published : June 22, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Complexation Equilibria of Vitamin B9, Glycine Oligopeptides with Di- and Trivalent Metal Ions

https://doi.org/10.14233/ajchem.2015.19060

Ahmed E. Fazary

Chemistry Department, Faculty of Science, King Khalid University, Abha 9004, Kingdom of Saudi Arabia; Applied Research Sector, Egyptian Organization for Biological Products and Vaccines (VACSERA Holding Company), 51 Wezaret El-Zeraa St., Agouza, Giza, Egypt

Aisha Q. Rajhi

Chemistry Department, Faculty of Science, King Khalid University, Abha 9004, Kingdom of Saudi Arabia

Corresponding Author(s) : Ahmed E. Fazary

aefazary@gmail.com; afazary@kku.edu.sa

Asian Journal of Chemistry, Vol. 27 No. 10 (2015): Vol 27 Issue 10
Article Published : June 23, 2015

Abstract

UV-visible spectrophotometric technique was used to study the complexation equilibria involved during the formation of binary and ternary biocomplexes of some divalent metal ions [Cu(II), Co(II) and Ni(II)] and trivalent [Fe(III), Al(III) and Cr(III)], with folic acid and biologically relevant glycine oligopeptides [glycine (G), glycylglycine (GG), glycyl-L-phenylalanine (GP) and glyclglycylglycine (GGG)], to investigate the complexation behavior of these systems as these systems could mimic many biological interactions of the vitamins.

Keywords

Folic acid Glycine oligopeptides Complexes UV-visible spectrophotometry

E. Fazary, A., & Q. Rajhi, A. (2015). Complexation Equilibria of Vitamin B9, Glycine Oligopeptides with Di- and Trivalent Metal Ions. Asian Journal of Chemistry, 27(10), 3872–3876. https://doi.org/10.14233/ajchem.2015.19060

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References

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A.Y. Rajhi, Y.H. Ju, A. Angkawijaya and A.E. Fazary, J. Solution Chem., 42, 2409 (2013); doi:10.1007/s10953-013-0116-5.
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E. Hernowo, A. Angkawijaya, A.E. Fazary, S. Ismadji and Y.H. Ju, J. Chem. Eng. Data, 56, 4549 (2011); doi:10.1021/je200819r.
A.E. Fazary, E. Hernowo, A. Angkawijaya, T.C. Chou, C.H. Lin, M. Taha and Y.H. Ju, J. Solution Chem., 40, 1965 (2011); doi:10.1007/s10953-011-9768-1.
A. Angkawijaya, A.E. Fazary, E. Hernowo, M. Taha and Y.H. Ju, J. Chem. Eng. Data, 56, 532 (2011); doi:10.1021/je101075q.
A.E. Fazary, M. Taha and Y.H. Ju, J. Chem. Eng. Data, 54, 35 (2009); doi:10.1021/je800441u.
M.M. Khalil and A.E. Fazary, Monatsh. Chem., 135, 1455 (2004); doi:10.1007/s00706-004-0243-1.
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H.D. William and J. Fleming. Spectroscopic Methods in Organic Chemistry, McGraw-Hill Book Company Ltd., London, edn 4 (1980).

References

J. Yang, R. Han, B. Su, C. Lin, N. Wang and J. Hu, J. Anal. Sci., 14, 965 (1998); doi:10.2116/analsci.14.965.

J.G. Donnelly, Crit. Rev. Clin. Lab. Sci., 38, 183 (2001); doi:10.1080/20014091084209.

M. Lucock, Mol. Genet. Metab., 71, 121 (2000); doi:10.1006/mgme.2000.3027.

A. Brzezińska, P. Wińska and M. Balińska, Acta Biochim. Pol., 47, 735 (2000).

T. Tamura and M.F. Picciano, Am. J. Clin. Nutr., 83, 993 (2006).

O. Stanger, Curr. Drug Metab., 3, 211 (2002); doi:10.2174/1389200024605163.

M. McCarthy, Lancet, 347, 677 (1996); doi:10.1016/S0140-6736(96)91216-7.

M. Eichholzer, O. Tonz and R. Zimmermann, Lancet, 367, 1352 (2006); doi:10.1016/S0140-6736(06)68582-6.

Z. Wu, X. Li, C. Hou and Y. Qian, J. Chem. Eng. Data, 55, 3958 (2010); doi:10.1021/je1000268.

Meroz and D. Horn, Proteins, 72, 606 (2008); doi:10.1002/prot.21951.

C.D. Fjell, J.A. Hiss, R.E. Hancock and G. Schneider, Nat. Rev. Drug Discov., 11, 37 (2012); doi:10.1038/nrd3653.

J.C. Reubi, Endocr. Rev., 24, 389 (2013); doi:10.1210/er.2002-0007.

B. Murray and R. FitzGerald, Curr. Pharm. Des., 13, 773 (2007); doi:10.2174/138161207780363068.

J.C. Hutton and K. Siddle, Peptide Hormone Secretion: A Practical Approach, IRL Press at Oxford University Press (1990).

J.C. Bulinski, Int. Rev. Cytol., 103, 281 (1986); doi:10.1016/S0074-7696(08)60838-4.

A.Y. Rajhi, Y.H. Ju, A. Angkawijaya and A.E. Fazary, J. Solution Chem., 42, 2409 (2013); doi:10.1007/s10953-013-0116-5.

A.E. Fazary, J. Chem. Eng. Data, 58, 2219 (2013); doi:10.1021/je4002569.

A. Angkawijaya, A.E. Fazary, S. Ismadji and Y. H. Ju, J. Chem. Eng. Data, 57, 3443 (2012); doi:10.1021/je300589r.

A. Angkawijaya, A.E. Fazary, E. Hernowo, S. Ismadji and Y.H. Ju, J. Solution Chem., 41, 1156 (2012); doi:10.1007/s10953-012-9861-0.

E. Hernowo, A. Angkawijaya, A.E. Fazary, S. Ismadji and Y.H. Ju, J. Chem. Eng. Data, 56, 4549 (2011); doi:10.1021/je200819r.

A.E. Fazary, E. Hernowo, A. Angkawijaya, T.C. Chou, C.H. Lin, M. Taha and Y.H. Ju, J. Solution Chem., 40, 1965 (2011); doi:10.1007/s10953-011-9768-1.

A. Angkawijaya, A.E. Fazary, E. Hernowo, M. Taha and Y.H. Ju, J. Chem. Eng. Data, 56, 532 (2011); doi:10.1021/je101075q.

A.E. Fazary, M. Taha and Y.H. Ju, J. Chem. Eng. Data, 54, 35 (2009); doi:10.1021/je800441u.

M.M. Khalil and A.E. Fazary, Monatsh. Chem., 135, 1455 (2004); doi:10.1007/s00706-004-0243-1.

A.E. Fazary, Bull. Chem. Soc. Ethiopia, 28, 393 (2014); doi:10.4314/bcse.v28i3.8.

A.E. Fazary and A.M. Ramadan, TCME Complex Metals, 1, 139 (2014); doi:10.1080/2164232X.2014.941115.

H.D. William and J. Fleming. Spectroscopic Methods in Organic Chemistry, McGraw-Hill Book Company Ltd., London, edn 4 (1980).

Issue

Vol. 27 No. 10 (2015): Vol 27 Issue 10

Complexation Equilibria of Vitamin B9, Glycine Oligopeptides with Di- and Trivalent Metal Ions

Corresponding Author(s) : Ahmed E. Fazary

Abstract

Keywords

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