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Vol. 37 No. 10 (2025): Vol 37 Issue 10, 2025

Copyright (c) 2025 Kumari Punjima, Sudha Yadava, Anand Ratnam, Nand Kishor Gour, Pankaj Kumar Chaurasia

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Manganese(III) Complexes of Porphyrin-based Ligand: Synthesis, DFT Study and Catalytic Application

https://doi.org/10.14233/ajchem.2025.34540
Kumari Punjima
Department of Chemistry, Deen Dayal Upadhyaya Gorakhpur University, Gorakhpur-273009, India
https://orcid.org/0009-0001-7832-1993
Sudha Yadava
Department of Chemistry, Deen Dayal Upadhyaya Gorakhpur University, Gorakhpur-273009, India
https://orcid.org/0000-0002-2189-482X
Anand Ratnam
Department of Chemistry, Deen Dayal Upadhyaya Gorakhpur University, Gorakhpur-273009, India
https://orcid.org/0000-0002-4152-3815
Nand Kishor Gour
Department of Chemical Sciences, Tezpur University, Tezpur-784028, India
https://orcid.org/0000-0003-3919-1513
Pankaj Kumar Chaurasia
Chemical, Biological and Environmental Laboratory, P.G. Department of Chemistry, L.S. College (Affiliated to B.R. Ambedkar Bihar University), Muzaffarpur-842001, India
https://orcid.org/0000-0002-1729-8427

Corresponding Author(s) : Pankaj Kumar Chaurasia

pankaj.chaurasia31@gmail.com

Asian Journal of Chemistry, Vol. 37 No. 10 (2025): Vol 37 Issue 10, 2025

Abstract

Four new Mn(III) porphyrin complexes with 1,2-diaminoethane were synthesized, with the general formula [MnIII(TEHPP)X(dae)], where TEHPP is 5,10,15,20-tetra(3-ethoxy-4-hydroxyphenyl)porphine, X represents Cl–, Br–, NCS– or N3– and ‘dae’ is 1,2-diaminoethane. These complexes were characterized with ultraviolet-visible (UV-visible) spectroscopy, Fourier transform-infrared (FT-IR), elemental analyses, magnetic susceptibility measurements and conductivity measurements. The synthesized novel Mn(III) porphyrins exhibit catalytic activity in the oxidation of aromatic alcohols to aldehydes. The catalytic performance of these complexes was evaluated for the oxidation of benzyl alcohol derivative to corresponding aldehyde at room temperature (30 ºC) using oxidants such as NaIO4, H2O2 and NaOCl. Density functional theory (DFT) calculations were also conducted to optimize the complex structures and HOMO–LUMO energies were determined using NBO analysis at the same theoretical level.

Keywords

Mn(III) porphyrins 5,10,15,20-Tetra(3-ethoxy-4-hydroxyphenyl)porphine 1,2-Diaminoethane Catalytic activity
(1)
Punjima, K.; Yadava, S.; Ratnam, A.; Gour, N. K.; Chaurasia, P. K. Manganese(III) Complexes of Porphyrin-Based Ligand: Synthesis, DFT Study and Catalytic Application. ajc 2025, 37, 2599-2604.
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