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Preparation and Mechanical Properties of Graphene Reinforced Poly(vinyl alcohol) Nanocomposites
Corresponding Author(s) : Yong Qian
Asian Journal of Chemistry,
Vol. 27 No. 2 (2015): Vol 27 Issue 2
Abstract
The incorporation of carbon nanomaterials significantly affected the macroscopic properties of the polymer-based composites. In this paper, graphene oxide nanosheets which exhibited excellent dispersibility and compatibility in poly(vinyl alcohol) matrix were successfully incorporated into poly(vinyl alcohol) through solution mixing; the mechanical properties and reinforced mechanism were investigated in detail. A 52.3 % increase in the tensile strength and a 94.2 % improvement in the Young's modulus were achieved for 2 wt. % graphene oxide loading. The success of this method provides a good rational for developing high-performance poly(vinyl alcohol)-based composite materials.
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References
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C. Lee, X. Wei, J.W. Kysar and J. Hone, Science, 321, 385 (2008); doi:10.1126/science.1157996.
X. Du, I. Skachko, A. Barker and E.Y. Andrei, Nat. Nanotechnol., 3, 491 (2008); doi:10.1038/nnano.2008.199.
H. Kim, A.A. Abdala and C.W. Macosko, Macromolecules, 43, 6515 (2010); doi:10.1021/ma100572e.
V. Mittal, Macromol. Mater. Eng., 299, 906 (2014); doi:10.1002/mame.201300394.
H.C. Schniepp, K.N. Kudin, J. Li, R.K. Prud’homme, R. Car, D.A. Saville and I.A. Aksay, ACS Nano, 2, 2577 (2008); doi:10.1021/nn800457s.
H. Schniepp, J. Li, M. McAllister, H. Sai, M. Herrera-Alonso, D.H. Adamson, R.K. Prud’homme, R. Car, D.A. Saville and I.A. Aksay, J. Phys. Chem. C, 110, 8535 (2006); doi:10.1021/jp060936f.
H. Kim, Y. Miura and C.W. Macosko, Chem. Mater., 22, 3441 (2010); doi:10.1021/cm100477v.
W.H. Lee, J. Park, Y. Kim, K.S. Kim, B.H. Hong and K. Cho, Adv. Mater., 23, 3460 (2011); doi:10.1002/adma.201101340.
H. Wang, L.-F. Cui, Y. Yang, H. Sanchez Casalongue, J.T. Robinson, Y. Liang, Y. Cui and H. Dai, J. Am. Chem. Soc., 132, 13978 (2010); doi:10.1021/ja105296a.
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Z. Liu, J.T. Robinson, X.M. Sun and H.J. Dai, J. Am. Chem. Soc., 130, 10876 (2008); doi:10.1021/ja803688x.
C.H. Lu, H.H. Yang, C.L. Zhu, X. Chen and G.N. Chen, Angew. Chem. Int. Ed., 48, 4785 (2009); doi:10.1002/anie.200901479.
X.-C. Dong, H. Xu, X.-W. Wang, Y.-X. Huang, M.B. Chan-Park, H. Zhang, L.-H. Wang, W. Huang and P. Chen, ACS Nano, 6, 3206 (2012); doi:10.1021/nn300097q.
S. Chen, J. Zhu, X. Wu, Q. Han and X. Wang, ACS Nano, 4, 2822 (2010); doi:10.1021/nn901311t.
V. Chandra, J. Park, Y. Chun, J.W. Lee, I.C. Hwang and K.S. Kim, ACS Nano, 4, 3979 (2010); doi:10.1021/nn1008897.
N.L. Yang, J. Zhai, D. Wang, Y.S. Chen and L. Jiang, ACS Nano, 4, 887 (2010); doi:10.1021/nn901660v.
S. Wang, D. Yu, L. Dai, D.W. Chang and J.-B. Baek, ACS Nano, 5, 6202 (2011); doi:10.1021/nn200879h.
G.M. Scheuermann, L. Rumi, P. Steurer, W. Bannwarth and R. Mulhaupt, J. Am. Chem. Soc., 131, 8262 (2009); doi:10.1021/ja901105a.
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H.X. Tang, G.J. Ehlert, Y.R. Lin and H.A. Sodano, Nano Lett., 12, 84 (2012); doi:10.1021/nl203023k.
N. Wu, X.L. She, D.J. Yang, X.F. Wu, F.B. Su and Y.F. Chen, J. Mater. Chem., 22, 17254 (2012); doi:10.1039/c2jm33114d.
C.L. Bao, Y.Q. Guo, L. Song and Y. Hu, J. Mater. Chem., 21, 13942 (2011); doi:10.1039/c1jm11662b.
T. Ramanathan, A.A. Abdala, S. Stankovich, D.A. Dikin, M. Herrera-Alonso, R.D. Piner, D.H. Adamson, H.C. Schniepp, X. Chen, R.S. Ruoff, S.T. Nguyen, I.A. Aksay, R.K. Prud'homme and L.C. Brinson, Nat. Nanotechnol., 3, 327 (2008); doi:10.1038/nnano.2008.96.
H. Bai, C. Li, X.L. Wang and G.Q. Shi, Chem. Commun., 46, 2376 (2010); doi:10.1039/c000051e.
C.C. Yang, S.J. Chiu, W.C. Chien and S.S. Chiu, J. Power Sources, 195, 2212 (2010); doi:10.1016/j.jpowsour.2009.10.091.
L.Z. Zhang, Y.Y. Wang, C.L. Wang and H. Xiang, J. Membr. Sci., 308, 198 (2008); doi:10.1016/j.memsci.2007.09.056.
J.H. Yeun, G.S. Bang, B.J. Park, S.K. Ham and J.H. Chang, J. Appl. Polym. Sci., 101, 591 (2006); doi:10.1002/app.23372.
R. Mukherjee, G.K. Patil and A. Sharma, Ind. Eng. Chem. Res., 48, 8812 (2009); doi:10.1021/ie801740y.
W.S. Hummers Jr. and R.E. Offeman, J. Am. Chem. Soc., 80, 1339 (1958); doi:10.1021/ja01539a017.
Y. Qian, C.Y. Wang and Z.-G. Le, Appl. Surf. Sci., 257, 10758 (2011); doi:10.1016/j.apsusc.2011.07.093.
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