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Vol. 27 No. 2 (2015): Vol 27 Issue 2

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Synthesis and Characterization of meso-Tetra(4-carboxyphenyl)porphyrin Complex of Palladium

https://doi.org/10.14233/ajchem.2015.17025
Wen-Tong Chen
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, China; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian Province, P.R. China
Rong-Hua Hu
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, China
Zhi-Gang Luo
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, China
Hua-Long Chen
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, China

Corresponding Author(s) : Wen-Tong Chen

wtchen_2000@aliyun.com

Asian Journal of Chemistry, Vol. 27 No. 2 (2015): Vol 27 Issue 2

Abstract

A porphyrinic compound Pd[TCPP-(CH3)4]·H2O (1) [TCPP = meso-tetra(4-carboxyphenyl)porphyrin] has been prepared via solvothermal reactions and characterized by X-ray diffraction method. It features an isolated structure with a coplanar porphyrin macrocycle. The Pd[TCPP-(CH3)4] moieties and lattice water molecules link together by hydrogen bonding interactions to give a three-dimensional (3-D) supramolecular framework.

Keywords

Crystal Porphyrin Supermolecule meso-Tetra(4-carboxyphenyl)porphyrin
Chen, W.-T., Hu, R.-H., Luo, Z.-G., & Chen, H.-L. (2015). Synthesis and Characterization of meso-Tetra(4-carboxyphenyl)porphyrin Complex of Palladium. Asian Journal of Chemistry, 27(2), 775–776. https://doi.org/10.14233/ajchem.2015.17025
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