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Vol. 33 No. 9 (2021): Vol 33 Issue 9, 2021

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Synthesis and Spectral Characterization of Mn(II) and Co(II) Complexes with Tetradentate Macrocyclic Ligand

https://doi.org/10.14233/ajchem.2021.23275
Usha Bansal
Department of Chemistry, Zakir Husain Delhi College, J.L.N. Marg, New Delhi-110002, India
Samta Goyal
Department of Chemistry, Zakir Husain Delhi College, J.L.N. Marg, New Delhi-110002, India
Swati Agrawal
Department of Chemistry, Motilal Nehru College, Benito Juarez Marg, New Delhi-110021, India

Corresponding Author(s) : Samta Goyal

samtagoyal@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 9 (2021): Vol 33 Issue 9, 2021

Abstract

Manganese(II) and cobalt(II) complexes were synthesized with [N4] tetradentate macrocyclic ligand using different metal salts i.e. MnCl2, Mn(NO3)2, CoCl2 and Co(NCS)2. The ligand was prepared by condensation of glyoxal and carbahydrazide. All these were characterized by elemental analysis, molar conductance measurements, magnetic moment, IR, mass, electronic and EPR spectral studies. Elemental analysis indicates that the complexes have composition MLX2 where (X = Cl–, NO3–, NCS–). All the complexes were found to be non-electrolytic in nature so can be formulated as [MLX2]. Infrared spectra of metal complexes suggest that the ligand behaves as tetradentate. On the basis of magnetic moment, electronic and EPR spectral data, all the metal complexes were found to be high spin with octahedral geometry.

Keywords

Macrocyclic ligand Tetradentate Glyoxal Carbahydrazide Manganese complex Cobalt complex
Bansal, U., Goyal, S., & Agrawal, S. (2021). Synthesis and Spectral Characterization of Mn(II) and Co(II) Complexes with Tetradentate Macrocyclic Ligand. Asian Journal of Chemistry, 33(9), 2207–2211. https://doi.org/10.14233/ajchem.2021.23275
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References
  1. R. Golbedaghi, A.M. Tabanez, S. Esmaeili and R. Fausto Appl. Organomet. Chem., 34, e5884 (2020); https://doi.org/10.1002/aoc.5884
  2. A. Chaudhary and E. Rawat, Int. J. Inorg. Chem., 2014, 509151 (2014); https://doi.org/10.1155/2014/509151
  3. M. Savastano, P. Arranz-Mascarós, C. Bazzicalupi, M.P. Clares, M.L. Godino-Salido, L. Guijarro, M.D. Gutiérrez-Valero, A. Bianchi, E. GarcíaEspaña and R. López-Garzón, ACS Omega, 2, 3868 (2017); https://doi.org/10.1021/acsomega.7b00736
  4. P.A. Vigato and S. Tamburini, Coord. Chem. Rev., 248, 1717 (2004); https://doi.org/10.1016/j.cct.2003.09.003
  5. D.E. Fenton, U. Casellato, P.A. Vigato and M. Vidali, Inorg. Chim. Acta, 95, 187 (1984); https://doi.org/10.1016/S0020-1693(00)87465-4
  6. A. McAuley and S. Subramanian, Coord. Chem. Rev., 200-202, 75 (2000); https://doi.org/10.1016/S0010-8545(00)00341-6
  7. P.A. Vigato, S. Tamburini and D.E. Fenton, Coord. Chem. Rev., 106, 25 (1990); https://doi.org/10.1016/0010-8545(60)80002-1
  8. L.F. Lindoy, The Chemistry of Macrocyclic Ligand Complexes, Cambridge University Press (1989).
  9. J. Costamagna, G. Ferraudi, B. Matsuhiro, M. Campos-Vallette, J. Canales, M. Villagran, J. Vargas and M. Aguirre, J. Coord. Chem. Rev., 196, 125 (2000); https://doi.org/10.1016/S0010-8545(99)00165-4
  10. T.A. Kaden, Top. Curr. Chem., 121, 157 (1984); https://doi.org/10.1007/3-540-12821-2_5
  11. N.W. Alcock, K.P. Balakrishnan, P. Moore and G.A. Pike, J. Chem. Soc., Dalton Trans., 889 (1987); https://doi.org/10.1039/DT9870000889
  12. H. Adams, M.R.J. Elsegood, D.E. Fenton, S.L. Heath and S.J. Ryan, J. Chem. Soc., Dalton Trans., 2031 (1999); https://doi.org/10.1039/a901992h
  13. A.C. Benniston, D. Ellis, L.J. Farrugia, R. Kennedy, R.D. Peacock and S. Walker, Polyhedron, 21, 333 (2002); https://doi.org/10.1016/S0277-5387(01)00994-9
  14. H. Keypour, S. Salehzadeh, R.G. Pritchard and R.V. Parish, Inorg. Chem., 39, 5787 (2000); https://doi.org/10.1021/ic000511m
  15. K.P. Wainwright, Adv. Inorg. Chem., 52, 293 (2001).
  16. C.B. Smith, A.K.W. Stephens, K.S. Wallwork, S.F. Lincoln, M.R. Taylor and K.P. Wainwright, Inorg. Chem., 41, 1093 (2002); https://doi.org/10.1021/ic010694s
  17. P.G. More, R.B. Bhalvankar and S.C. Pattar, J. Indian Chem. Soc., 78, 474 (2001).
  18. G.B. Bagihalli, P.G. Avaji, S.A. Patil and P.S. Badami, Eur. J. Med. Chem., 43, 2639 (2008); https://doi.org/10.1016/j.ejmech.2008.02.013
  19. J. Vanco, J. Marek, Z. Travnicek, E. Racanska, J. Muselik and O. Svajlenova, J. Inorg. Biochem., 102, 595 (2008); https://doi.org/10.1016/j.jinorgbio.2007.10.003
  20. N.A. Illan-Cabeza, F. Hueso-Urena, M.N. Moreno-Carretero, J.M. Martínez-Martos and M.J. Ramírez-Expósito, J. Inorg. Biochem., 102, 647 (2008); https://doi.org/10.1016/j.jinorgbio.2007.10.008
  21. N.F. Curtis, Coord. Chem. Rev., 3, 3 (1968); https://doi.org/10.1016/S0010-8545(00)80104-6
  22. H. Okawa, H. Furutachi and D.E. Fenton, Coord. Chem. Rev., 174, 51 (1998); https://doi.org/10.1016/S0010-8545(97)00082-9
  23. A.E. Martell, J. Perutka and D. Kong, Coord. Chem. Rev., 216-217, 55 (2001); https://doi.org/10.1016/S0010-8545(00)00407-0
  24. H.A. O’Riley, A. Levina, J.B. Aitken and P.A. Lay, Inorg. Chim. Acta, 454, 128 (2017); https://doi.org/10.1016/j.ica.2016.07.050
  25. H. Keypour, N. Ansari, M. Mahmoudabadi, R. Karamian, S.H.M. Farida, M.E. Moghadam and R.W. Gable, Inorg. Chim. Acta, 509, 119705 (2020); https://doi.org/10.1016/j.ica.2020.119705
  26. C.H.G. Jakob, A.W. Muñoz, J.F. Schlagintweit, V. Weiß, R.M. Reich, S.A. Sieber, J.D.G. Correia and F.E. Kühn, J. Organomet. Chem., 932, 121643 (2021); https://doi.org/10.1016/j.jorganchem.2020.121643
  27. M. Aidi, H. Keypour, A. Shooshtari, M. Bayat, L. Hosseinzadeh, H.A. Rudbari and R.W. Gable, Inorg. Chim. Acta, 490, 294 (2019); https://doi.org/10.1016/j.ica.2018.12.046
  28. S. Ali, V. Singh, P. Jain and V. Tripathi, J. Saudi Chem. Soc., 23, 52 (2019); https://doi.org/10.1016/j.jscs.2018.04.005
  29. C. Preti and G. Tosi, Aust. J. Chem., 29, 543 (1976); https://doi.org/10.1071/CH9760543
  30. L.E. Orgel, J. Chem. Phys., 23, 1004 (1955); https://doi.org/10.1063/1.1742182
  31. J.E. Huheey, Principles of Structure and Reactivity, Ed. Harper Row, Int. Edition: New York, p. 363 (1972)
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