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Vol. 33 No. 9 (2021): Vol 33 Issue 9, 2021

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Role of Cationic and Anionic Dopants on the Structural, Morphological, Optical and Magnetic Properties of Lead Oxide Nanocrystals Prepared by Solvothermal Method

https://doi.org/10.14233/ajchem.2021.23289
N. Saraswathi
Department of Physics, Sree Devi Kumari Women′s College, Kuzhithurai-629163, India
K.J. Abhirama
Department of Physics, Sree Devi Kumari Women′s College, Kuzhithurai-629163, India

Corresponding Author(s) : K.J. Abhirama

abhiramathampi87@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 9 (2021): Vol 33 Issue 9, 2021

Abstract

A facile and simple microwave assisted solvothermal technique was adopted for the synthesis of undoped and doped (Mn2+, S2–) lead oxide nanoparticles. Thermogravimetric analysis and differential thermal analysis were carried out to realize the thermal behaviour of PbO nanoparticles. The synthesized nanoparticles were annealed at about 400 ºC. The calcined samples were characterized by powder X-ray diffraction, SEM, EDX, UV spectroscopic analysis and VSM measurement. The diffraction patterns of the prepared nanoparticles showed the formation of an orthorhombic phase of lead oxide. All the samples were in nano- regime with an average grain size of 22-26 nm. Spherical morphology of the samples was revealed in the SEM micrographs. EDX pattern confirmed the presence of cationic and anionic dopants. The band gap energy values range from 4.2 to 5.6 eV. The VSM measurement revealed that the sample has weak ferromagnetic nature.

Keywords

Microwave Solvothermal Lead oxide Orthorhombic Annealed
Saraswathi, N., & Abhirama, K. (2021). Role of Cationic and Anionic Dopants on the Structural, Morphological, Optical and Magnetic Properties of Lead Oxide Nanocrystals Prepared by Solvothermal Method. Asian Journal of Chemistry, 33(9), 2043–2048. https://doi.org/10.14233/ajchem.2021.23289
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References
  1. A. Rastogi, M. Zivcak, O. Sytar, H.M. Kalaji, X. He, S. Mbarki and M. Brestic, Front. Chem., 5, 78 (2017); https://doi.org/10.3389/fchem.2017.00078
  2. M.S. Chavali and M.P. Nikolova, SN Appl. Sci., 1, 607 (2019); https://doi.org/10.1007/s42452-019-0592-3
  3. J.K. Hedlund Orbeck and R.J. Hamers, J. Vacuum Sci. Technol. A, 38, 031001 (2020); https://doi.org/10.1116/1.5141853
  4. A.M. Abu-Dief, J. Nanotechnol. Nanomater., 1, 5 (2020).
  5. J.A. Rodriguez and M. Fernandez-Garcia, Synthesis, Properties and Applications of Oxide Nanoparticles, Wiley: New Jersey (2007).
  6. M. Fernandez-Garcia, A. Martinez-Arias, J.C. Hanson and J.A. Rodriguez, Chem. Rev., 104, 4063 (2004); https://doi.org/10.1021/cr030032f
  7. R. Medhi, M.D. Marquez, and T.R. Lee, ACS Appl. Nano Mater., 3, 6156 (2020); https://doi.org/10.1021/acsanm.0c01035
  8. N. Millot, D. Aymes, F. Bernard, J.C. Niepce, A. Traverse, F. Bouree, B.L. Cheng and P. Perriat, J. Phys. Chem. B, 107, 5740 (2003); https://doi.org/10.1021/jp022312p
  9. J. Schoiswohl, G. Kresse, S. Surnev, M. Sock, M.G. Ramsey and F.P. Netzer, Phys. Rev. Lett., 92, 206103 (2004); https://doi.org/10.1103/PhysRevLett.92.206103
  10. J.M. McHale, A. Auroux, A.J. Perrota and A. Navrotsky, Science, 277, 788 (1997); https://doi.org/10.1126/science.277.5327.788
  11. H. Zhang and J.F. Banfield, J. Mater. Chem., 8, 2073 (1998); https://doi.org/10.1039/a802619j
  12. O.A. Oyewo, E.E. Elemike, D.C. Onwudiwe and M.S. Onyango, Int. J. Biol. Macromol., 164, 2477 (2020); https://doi.org/10.1016/j.ijbiomac.2020.08.074
  13. S. Varzdar, L. Hashemi, A. Morsali and M. Dusek, J. Iran. Chem. Soc., 14, 2255 (2017); https://doi.org/10.1007/s13738-017-1162-5
  14. P. Veluchamy, M. Sharon, M. Shimizu and H. Minoura, J. Electroanal.Chem., 365, 179 (1994); https://doi.org/10.1016/0022-0728(93)02973-L
  15. S. Ghasemi, M.F. Mousavi, M. Shamsipur and H. Karami, Ultrason. Sonochem., 15, 448 (2008); https://doi.org/10.1016/j.ultsonch.2007.05.006
  16. A. Miri, M. Sarani, A. Hashemzadeh, Z. Mardani and M. Darroud, Green Chem. Lett. Rev., 11, 567 (2018); https://doi.org/10.1080/17518253.2018.1547926
  17. B. Jia and L. Gao, Mater. Chem. Phys., 100, 351 (2006); https://doi.org/10.1016/j.matchemphys.2006.01.012
  18. S. Li, W. Yang, M. Chen, J. Gao, J. Kang and Y. Qi, Mater. Chem. Phys., 90, 262 (2005); https://doi.org/10.1016/j.matchemphys.2004.02.022
  19. L.J. Chen, S.M. Zhang, Z.S. Wu, Z.J. Zhang and H.X. Dang, Mater. Lett., 59, 3119 (2005); https://doi.org/10.1016/j.matlet.2005.05.031
  20. F.G. Ma, Z.Q. Shao, L.Y. Song and H.M. Tan, Chin. J. Synth. Chem. (Hecheng Huaxue), 9, 449 (2001).
  21. Z.W. Pan, Z.R. Dai and Z.L. Wang, Appl. Phys. Lett., 80, 309 (2002); https://doi.org/10.1063/1.1432749
  22. M. Ghaedi, A.M. Ghaedi, B. Mirtamizdoust, S. Agarwal and V.K. Gupta, J. Mol. Liq., 213, 48 (2016); https://doi.org/10.1016/j.molliq.2015.09.051
  23. K.H.H. Al-Attiyah, A. Hashim and S.F. Obaid, Int. J. Plast. Technol., 23, 39 (2019); https://doi.org/10.1007/s12588-019-09228-5
  24. L. Zhan, X. Xiang, B. Xie and B. Gao, Powder Technol., 308, 30 (2017); https://doi.org/10.1016/j.powtec.2016.12.005
  25. S.G. Rejith and G. Sudha, Int. Adv. Res. J. Sci. Eng. Technol., 4, 130 (2017); https://doi.org/10.17148/IARJSET.2017.4230
  26. P.B. Taunk, R. Das, D.P. Bisen and R. Tamrakar, Optik, 127, 6028 (2016); https://doi.org/10.1016/j.ijleo.2016.04.073
  27. M. Salavati-Niasari, F. Mohandes and F. Davar, Polyhedron, 28, 2263 (2009); https://doi.org/10.1016/j.poly.2009.04.009
  28. A. Ramazani, S. Hamidi and A. Morsali, J. Mol. Liq., 157, 73 (2010); https://doi.org/10.1016/j.molliq.2010.08.012
  29. V.S. Kundu, R.L. Dhiman, D. Singh, A.S. Maan and S. Arora, Int. J. Adv. Res. Sci. Eng., 2, 5 (2013).
  30. R.S. Dongre, eds.: P. Chooto, Lead: Toxicological Profile, Pollution Aspects and Remedial Solutions, In: Lead Chemistry, IntechOpen (2020).
  31. R. Thielsch, T. Bohme, R. Reiche, D. Schlafer, H.D. Bauer and H. Bottcher, Nano Struct. Mater., 10, 131 (1998); https://doi.org/10.1016/S0965-9773(98)00056-7
  32. T.J. Wilkinson, D.L. Perry, E. Spiller, P. Berdahl, S.E. Derenzo and M.J. Weber, Proc. MRS, 704, 117 (2002).
  33. P. Tyagi and A.G. Vedeshwar, Bull. Mater. Sci., 24, 297 (2001); https://doi.org/10.1007/BF02704925
  34. D. Chu, Y. Zeng and D. Jiang, Solid State Commun., 143, 308 (2007); https://doi.org/10.1016/j.ssc.2007.05.036
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