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Influence of Reaction Conditions in the Selective Hydrogenation of Isophorone to 3,3,5-Trimethylcyclohexanone over NiC Composite Catalyst
Corresponding Author(s) : Nagendranath Mahata
Asian Journal of Chemistry,
Vol. 33 No. 6 (2021): Vol 33 Issue 6, 2021
Abstract
NiC composite catalyst was synthesized by carbon deposition over skeletal Raney nickel by exploiting methane decomposition reaction and applied in the hydrogenation of isophorone. Nickel content in the composite catalyst was ascertained by atomic emission spectroscopy. Influence of operating variables (agitation, solvent, temperature, H2 pressure and isophorone concentration) on the hydrogenation of isophorone over the NiC composite catalyst was investigated. Ethyl acetate was observed to be an excellent solvent for the reaction in terms of both isophorone conversion as well as 3,3,5-trimethylcyclohexanone selectivity. The catalytic reaction was observed to be 0.06 order with respect to isophorone and 0.82 order with respect to H2.
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- P. Gallezot and D. Richard, Catal. Rev., Sci. Eng., 40, 81 (1998); https://doi.org/10.1080/01614949808007106
- N. Mahata, A.F. Cunha, J.J.M. Orfao and J.L. Figueiredo, Chem. Eng. J., 188, 155 (2012); https://doi.org/10.1016/j.cej.2012.01.127
- A.S. Nagpure, L. Gurrala, P. Gogoi and S.V. Chilukuri, RSC Adv., 6, 44333 (2016); https://doi.org/10.1039/C6RA04154J
- Y. Hou, S. Ren, M. Niu and W. Wu, R. Soc. Open Sci., 5, 171523 (2018); https://doi.org/10.1098/rsos.171523
- N. Mahata, F. Goncalves, M.F.R. Pereira and J.L. Figueiredo, J. Appl. Catal. A, 339, 159 (2008); https://doi.org/10.1016/j.apcata.2008.01.023
- L. Xu, S. Sun, X. Zhang, H. Gao and W. Wang, RSC Adv., 11, 4465 (2021); https://doi.org/10.1039/D0RA08107H
- N. Mahata, A.F. Cunha, J.J.M. Orfao and J.L. Figueiredo, ChemCatChem, 2, 330 (2010); https://doi.org/10.1002/cctc.200900299
- M. Pisarek, M. Lukaszewski, P. Winiarek, P. Kedzierzawski and M. JanikCzachor, Mater. Chem. Phys., 114, 774 (2009); https://doi.org/10.1016/j.matchemphys.2008.10.027
- A. Das, K.M. Hansda and N. Mahata, J. Indian Chem. Soc., 95, 1531 (2018).
- W. Wang, Y. Liu, N. Li, G. Li, W. Wang, A. Wang, X. Wang and T. Zhang, Sci. Rep., 7, 6111 (2017); https://doi.org/10.1038/s41598-017-06556-7
- T. Sato, C.V. Rode, O. Sato and M. Shirai, Appl. Catal. B, 49, 181 (2004); https://doi.org/10.1016/j.apcatb.2003.12.010
- M. Pisarek, M. Lukaszewski, P. Winiarek, P. Kedzierzawski and M. Janik-Czachor, J. Appl. Catal. A, 358, 240 (2009); https://doi.org/10.1016/j.apcata.2009.02.012
- R.L. Augustine, P. Goel, N. Mahata, C. Reyes and S.K. Tanielyan, J. Mol. Catal. Chem., 216, 189 (2004); https://doi.org/10.1016/j.molcata.2004.03.009
- M.G. Prakash, R. Mahalakshmy, K.R. Krishnamurthy and B. Viswanathan, Catal. Sci. Technol., 5, 3313 (2015); https://doi.org/10.1039/C4CY01379D
- S. Han, Y. Liu, J. Li, R. Li, F. Yuan and Y. Zhu, Catalysts, 8, 200 (2018); https://doi.org/10.3390/catal8050200
References
P. Gallezot and D. Richard, Catal. Rev., Sci. Eng., 40, 81 (1998); https://doi.org/10.1080/01614949808007106
N. Mahata, A.F. Cunha, J.J.M. Orfao and J.L. Figueiredo, Chem. Eng. J., 188, 155 (2012); https://doi.org/10.1016/j.cej.2012.01.127
A.S. Nagpure, L. Gurrala, P. Gogoi and S.V. Chilukuri, RSC Adv., 6, 44333 (2016); https://doi.org/10.1039/C6RA04154J
Y. Hou, S. Ren, M. Niu and W. Wu, R. Soc. Open Sci., 5, 171523 (2018); https://doi.org/10.1098/rsos.171523
N. Mahata, F. Goncalves, M.F.R. Pereira and J.L. Figueiredo, J. Appl. Catal. A, 339, 159 (2008); https://doi.org/10.1016/j.apcata.2008.01.023
L. Xu, S. Sun, X. Zhang, H. Gao and W. Wang, RSC Adv., 11, 4465 (2021); https://doi.org/10.1039/D0RA08107H
N. Mahata, A.F. Cunha, J.J.M. Orfao and J.L. Figueiredo, ChemCatChem, 2, 330 (2010); https://doi.org/10.1002/cctc.200900299
M. Pisarek, M. Lukaszewski, P. Winiarek, P. Kedzierzawski and M. JanikCzachor, Mater. Chem. Phys., 114, 774 (2009); https://doi.org/10.1016/j.matchemphys.2008.10.027
A. Das, K.M. Hansda and N. Mahata, J. Indian Chem. Soc., 95, 1531 (2018).
W. Wang, Y. Liu, N. Li, G. Li, W. Wang, A. Wang, X. Wang and T. Zhang, Sci. Rep., 7, 6111 (2017); https://doi.org/10.1038/s41598-017-06556-7
T. Sato, C.V. Rode, O. Sato and M. Shirai, Appl. Catal. B, 49, 181 (2004); https://doi.org/10.1016/j.apcatb.2003.12.010
M. Pisarek, M. Lukaszewski, P. Winiarek, P. Kedzierzawski and M. Janik-Czachor, J. Appl. Catal. A, 358, 240 (2009); https://doi.org/10.1016/j.apcata.2009.02.012
R.L. Augustine, P. Goel, N. Mahata, C. Reyes and S.K. Tanielyan, J. Mol. Catal. Chem., 216, 189 (2004); https://doi.org/10.1016/j.molcata.2004.03.009
M.G. Prakash, R. Mahalakshmy, K.R. Krishnamurthy and B. Viswanathan, Catal. Sci. Technol., 5, 3313 (2015); https://doi.org/10.1039/C4CY01379D
S. Han, Y. Liu, J. Li, R. Li, F. Yuan and Y. Zhu, Catalysts, 8, 200 (2018); https://doi.org/10.3390/catal8050200