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Vol. 33 No. 6 (2021): Vol 33 Issue 6, 2021

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Some Organotellurium(IV) Complexes of 1-Methyl-3-(p-tolylimino)indolin-2-one Schiff Base

https://doi.org/10.14233/ajchem.2021.23159
Manish Kumar
Department of Chemistry, Maharishi Dayanand University, Rohtak-124001, India
K.K. Verma
Department of Chemistry, Maharishi Dayanand University, Rohtak-124001, India
Sapana Garg
Department of Chemistry, Maharishi Dayanand University, Rohtak-124001, India

Corresponding Author(s) : Sapana Garg

sapanagarg1511@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 6 (2021): Vol 33 Issue 6, 2021

Abstract

Six new hexa-coordinated organotellurium(IV) complexes of type RTeCl3·NMeIPT and R2TeCl2·NMeIPT (R = 4-hydroxyphenyl, 4-methoxyphenyl or 3-methy-4-hydroxyphenyl; NMeIPT(L) = Schiff base (1-methyl-3-(p-tolylimino)indolin-2-one) derived from condensation of 4-methylisatin and p-toluidine) have been synthesized and characterized by different spectral studies like elemental analyses, molar conductance, infrared, mass spectrometry, 1H NMR, 13C NMR and UV-visible spectroscopy. On the basis of spectroscopic data, it is evident that Schiff base behaves as NO donor bidentate ligand via azomethine nitrogen atom and oxygen atom from carbonyl group for all the tellurium(IV) complexes. The results showed that all the organotellurium(IV) complexes possess distorted octahedral geometry. Geometry of the all organotellurium(IV) complexes was optimized and their theoretical quantum mechanical parameters were calculated. This computational study also suggests octahedral geometry for complexes. The antimicrobial activity of NMeIPT and all the organotellurium(IV) complexes were screened against bacteria i.e. Xanthomonas campestris and Bacillus cereus and fungi i.e. Fusarium oxysporum, Candida albicans and Sclerotinia sclerotium.

Keywords

N-Methylisatin p-Toluidine Organotellurium complexes Antibacterial activity Antifungal activity
Kumar, M., Verma, K., & Garg, S. (2021). Some Organotellurium(IV) Complexes of 1-Methyl-3-(p-tolylimino)indolin-2-one Schiff Base. Asian Journal of Chemistry, 33(6), 1236–1244. https://doi.org/10.14233/ajchem.2021.23159
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