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Vol. 33 No. 4 (2021): Vol 33 Issue 4

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Synthesis of Silver Nanoparticles from Mimusops elengi Extract of Raw Fruits and Characterization of PVA-Silver Polymer Nanocomposite Films

https://doi.org/10.14233/ajchem.2021.23074
Bhabani Shankar Panda
Coastal Laboratory, State Pollution Control Board, Integrated Coastal Zone Management Project (ICZMP), Bhubaneswar-751024, India
Mohammed Ansar Ahemad
Department of Chemistry, Gandhi Institute for Education and Technology, Bhubaneswar-752060, India

Corresponding Author(s) : Bhabani Shankar Panda

bpanda607@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 4 (2021): Vol 33 Issue 4

Abstract

The present work concerns on the synthesis of silver nanoparticles at 25 ºC using raw fruits extract of Bakul (Mimusops elengi) tree via chemical reduction route development of poly(vinyl alcohol) PVA-silver polymer nanocomposite films. The nanocomposite films were subjected to characterization by UV-visible, FTIR, X-ray diffraction, field emission scanning electron microscope (FESEM) and thermal studies. The UV-visible spectrum shows a characteristic broad absorption band observed near 465 nm suggesting presence of silver nanoparticles in polymer nanocomposites (PNCs) film. The vibrational band shift of –OH group of poly(vinyl alcohol) in the presence of nanoparticle designated the chemical interaction between –OH group of poly(vinyl alcohol) and silver nanoparticles. The FESEM study confirmed that PVA is not only acted as a capping agent, but also a cross-linking agent. X-ray diffraction study shows that the existence of AgNPs in the poly nanocomposite film and nanoaparticles are crystalline in nature. Thermal studies suggest that the enhanced thermal stability is because of the good packing of the polar crystallites in β-PVA composites as compared to the non-polar α-phase of neat poly(vinyl alcohol) (PVA).

Keywords

Raw fruits extract Mimusops elengi Polymer nanocomposites Nanofluids Silver nanoparticles
Shankar Panda, B., & Ansar Ahemad, M. (2021). Synthesis of Silver Nanoparticles from Mimusops elengi Extract of Raw Fruits and Characterization of PVA-Silver Polymer Nanocomposite Films. Asian Journal of Chemistry, 33(4), 762–766. https://doi.org/10.14233/ajchem.2021.23074
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References
  1. I. Khan, K. Saeed and I. Khan, Arab. J. Chem., 12, 908 (2019); https://doi.org/10.1016/j.arabjc.2017.05.011
  2. J. Jeevanandam, A. Barhoum, Y.S. Chan, A. Dufresne and M.K Danquah, Beilstein J. Nanotechnol., 9, 1050 (2018); https://doi.org/10.3762/bjnano.9.98
  3. Q. Wu, W.-S. Miao, Y.-D. Zhang, H.-J. Gao and D. Hui, Nanotechnol.Rev., 9, 259 (2020); https://doi.org/10.1515/ntrev-2020-0021
  4. P.H.C. Camargo, K.G. Satyanarayana and F. Wypych, Mater. Res., 12, 1 (2009); https://doi.org/10.1590/S1516-14392009000100002
  5. W. Choi, I. Lahiri, R. Seelaboyina and Y.S. Kang, Crit. Rev. Solid State Mater. Sci., 35, 52 (2010); https://doi.org/10.1080/10408430903505036
  6. A.T. Odularu, Bioinorg. Chem. Appl., 2018, 9354708 (2018); https://doi.org/10.1155/2018/9354708
  7. O. Zaytseva and G. Neumann, Chem. Biol. Technol. Agric., 3, 17 (2016); https://doi.org/10.1186/s40538-016-0070-8
  8. G. Vinci and M. Rapa, Bioengineering, 6, 10 (2019); https://doi.org/10.3390/bioengineering6010010
  9. F. Hussain, M. Hojjati, M. Okamoto and R.E. Gorga, J. Compos. Mater., 40, 1511 (2006); https://doi.org/10.1177/0021998306067321
  10. R. Das, M.E. Ali, S.B.A. Hamid, S. Ramakrishna and Z.Z.Chowdhury, Desalination, 336, 97 (2014); https://doi.org/10.1016/j.desal.2013.12.026
  11. A.A. Yetisgin, S. Cetinel, M. Zuvin, A. Kosar and O. Kutlu, Molecules, 25, 2193 (2020); https://doi.org/10.3390/molecules25092193
  12. D.R. Paul and L.M. Robeson, Polymer, 49, 3187 (2008); https://doi.org/10.1016/j.polymer.2008.04.017
  13. J.H. Koo, Polymer Nanocomposites, McGrawHill Professional Publ., (2006).
  14. J. Wang, X. Wang, C. Xu, M. Zhang and X. Shang, Polym. Int., 60, 816 (2011); https://doi.org/10.1002/pi.3025
  15. M.A. Omer and E.A. Bashir, J. Radiation Res. Appl. Sci., 11, 237 (2018); https://doi.org/10.1016/j.jrras.2018.03.001
  16. I. Saini, A. Sharma, R. Dhiman, S. Aggarwal, S. Ram and P.K. Sharma, J. Alloys Compd., 714, 172 (2017); https://doi.org/10.1016/j.jallcom.2017.04.183
  17. X.F. Qian, J. Yin, Y.F. Yang, Q.H. Lu, Z.K. Zhu and J. Lu, J. Appl. Polym. Sci., 82, 2744 (2001); https://doi.org/10.1002/app.2127
  18. A.N. Krklješ, M.T. Marinovic-Cincovic, Z.M. Kacarevic-Popovic and J.M. Nedeljkovic, Eur. Polym. J., 43, 2171 (2007); https://doi.org/10.1016/j.eurpolymj.2007.03.023
  19. S.K. Chatterjee, X-Ray Diffraction: Its Theory and Applications, PHI Learning Pvt. Ltd. (2010).
  20. O.C. Wells, Scanning Electron Microscopy, McGraw Hill: New York (1974).
  21. A.A. Salisu, H. Abba and M.S. Inuwa, Int. J. Eng. Appl. Sci., 2, 109, (2015).
  22. B.S. Panda, M.A. Ahemad and L.N. Mishra, Int. J. ChemTech Res., 14, 16 (2021).
  23. K. Jyoti, M. Baunthiyal and A. Singh, J. Radiat. Res. Appl. Sci., 9, 217 (2016); https://doi.org/10.1016/j.jrras.2015.10.002
  24. Z. Zaheer and Rafiuddin, Colloids Surf. B Biointerfaces, 90, 48 (2012); https://doi.org/10.1016/j.colsurfb.2011.09.037
  25. S. Moharana and R.N. Mahaling, Chem. Phys. Lett., 680, 31 (2017); https://doi.org/10.1016/j.cplett.2017.05.018
  26. J. Audoit, L. Laffont, A. Lonjon, E. Dantras and C. Lacabanne, Polymer, 78, 104 (2015); https://doi.org/10.1016/j.polymer.2015.09.062
  27. A.M. Shehap, Egypt. J. Solids., 31, 75 (2008).
  28. M. Maity, S.K. Pramanik, U. Pal, B. Banerji and N.C. Maiti, J. Nanopart. Res., 16, 2179 (2014); https://doi.org/10.1007/s11051-013-2179-z
  29. M.L. Bhaisare, M.S. Khan, S. Pandey, G. Gedda and H.F. Wu, RSC Adv., 7, 23607 (2017); https://doi.org/10.1039/C6RA28705K
  30. C.S. Liyanage, S.N. De Silva and C.A. Fernando, Int. J. Nanoelectron.Mater., 11, 129 (2018).
  31. P. Li, W. Lv and S. Ai, J. Exp. Nanosci., 11, 18 (2016); https://doi.org/10.1080/17458080.2015.1015462
  32. A. Muthuvinothini and S. Stella, Asian J. Chem., 31, 109 (2019); https://doi.org/10.14233/ajchem.2019.21578
  33. F.S. Al-Hazmi, D.M. de Leeuw, A.A. Al-Ghamdi and F.S. Shokr, Curr. Appl. Phys., 17, 1181 (2017); https://doi.org/10.1016/j.cap.2017.05.011
  34. M. Behera, S.K. Biswal, B.S. Panda and M.A. Ahemad, Asian J. Chem.,32, 106 (2019); https://doi.org/10.14233/ajchem.2020.22344
  35. R. Majumdar, B.G. Bag and P. Ghosh, Appl. Nanosci., 6, 521 (2016); https://doi.org/10.1007/s13204-015-0454-2
  36. S. Abdalla, A. Obaid and F.M. Al-Marzouki, Results Phys., 6, 617 (2016); https://doi.org/10.1016/j.rinp.2016.09.003
  37. M. Behera, S.K. Biswal, M.A. Ahemad and B.S. Panda, Biointerf. Res.Appl. Chem., 11, 12584 (2021); https://doi.org/10.33263/BRIAC115.1258412595
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