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Vol. 33 No. 3 (2021): Vol 33 Issue 3

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Synthesis and Structural Characterization of Lanthanum(III) Complexes of 4-Nitrosoantipyrine

https://doi.org/10.14233/ajchem.2021.23047
Meera Gopal
Department of Chemistry, Maharaja’s College, Ernakulam-682011, India
Sreesha Sasi
Department of Chemistry, Maharaja’s College, Ernakulam-682011, India

Corresponding Author(s) : Sreesha Sasi

sreeshasasi@gmail.com; sreeshasasi@maharajas.ac.in

Asian Journal of Chemistry, Vol. 33 No. 3 (2021): Vol 33 Issue 3

Abstract

A new series of La(III) complexes of the ligand with the general formula [La(L)2(a)3] and [La2(L)4(aa)3], (a = nitrate (1), thiocyanate (2), acetate (3) and propionate (4) ions, aa = sulphate (5), thiosulphate (6), oxalate (7) and malonate (8) ions with the ligand 4-nitrosoantipyrine (L) were synthesized and characterized using various physico-chemical studies. The primary ligand L acts as a bidentate ligand utilizing the carbonyl group and the nitroso group for bonding. The nitrate, thiocyanate, acetate and propionate ions are monovalent unidentate ligands, whereas sulphate, thiosulphate, oxalate and malonate ions are divalent bidentate ligands in the complexes 1-8. Based on spectral data and magnetic susceptibility measurements, geometry of the lanthanum(III) complexes were also proposed.

Keywords

4-Nitrosoantipyrine Lanthanum(III) complexes
Gopal, M., & Sasi, S. (2021). Synthesis and Structural Characterization of Lanthanum(III) Complexes of 4-Nitrosoantipyrine. Asian Journal of Chemistry, 33(3), 617–621. https://doi.org/10.14233/ajchem.2021.23047
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