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Vol. 33 No. 2 (2021): Vol 33 Issue 2

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Optical Studies of Binary Mixture of Chloro Substituted Benzene and n-Hexane or Cyclohexane or 1,4-Dioxane

https://doi.org/10.14233/ajchem.2021.22920
Anshu
Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131039, India
Manju Rani
Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131039, India
Sanjeev Maken
Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131039, India

Corresponding Author(s) : Sanjeev Maken

sanjeevmakin@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 2 (2021): Vol 33 Issue 2

Abstract

Thermophysical properties of binary liquid mixtures are highly beneficial for getting information about the intermolecular interactions and geometrical effects in the system. The chloro-substituted benzene compounds like 2-chlorotoluene, 4-chlorotoluene, 1,3-dichlorobenzene also have wide range of application in industrial and biomedical areas. In present work, the refractive indices (n) of haloarenes, hydrocarbons, ether, and respective possible binary mixtures were experimentally determined over the entire compositions at T= (298.15-318.15) K. The mixtures selected were 2-chlorotoluene or 4-chlorotoluene or 1,3-dichlorobenzene (1) + n-hexane or cyclohexane or 1,4-dioxane (2) with its possible combinations. The Δn is positive for all binary mixtures at all investigated compositions. Different rules of mixing like Lorentz-Lorentz, Erying-John, Arago-Biot, etc. were also used to predict n values. The Δn values were also analyzed in terms of ongoing intermolecular interactions among the components of the selected systems.

Keywords

Refractive index Chlorotoluene Hydrocarbons 1,3-Dichlorobenzene 1,4-Dioxane Mixing rules
Anshu, ., Rani, M., & Maken, S. (2021). Optical Studies of Binary Mixture of Chloro Substituted Benzene and n-Hexane or Cyclohexane or 1,4-Dioxane. Asian Journal of Chemistry, 33(2), 291–298. https://doi.org/10.14233/ajchem.2021.22920
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