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Vol. 33 No. 2 (2021): Vol 33 Issue 2

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Synthetic, Spectroscopic and Biological Studies on Some μ-Oxy-bis[triphenylantimony(V)]carboxylates and Cyclic Organoantimonates

https://doi.org/10.14233/ajchem.2021.23045
Surjeet Singh
Department of Chemistry, University of Lucknow, Lucknow-226007, India
Neha Bahuguna
Department of Chemistry, M.K.P. (P.G.) College, Dehradun-248001, India
Kiran Singhal
Department of Chemistry, University of Lucknow, Lucknow-226007, India
Prem Raj
Department of Chemistry, University of Lucknow, Lucknow-226007, India

Corresponding Author(s) : Prem Raj

premraj123@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 2 (2021): Vol 33 Issue 2

Abstract

A series of hitherto unreported μ-oxy-bis[triphenylantimony(V)]dicarboxylates and μ-oxy-bis[triphenylantimony(V)] chlorocarboxylates of general formula Ph3Sb(L)-O-Sb(L)Ph3 and Ph3Sb(Cl)-O-Sb(L)Ph3, respectively have been synthesized by the metathetical reaction of μ-oxybis-[triphenylantimony(V)]dichloride and silver salts of corresponding carboxylic acids in 1:2 and 1:1 molar ratio [where L = thiosalicyclic acid, p-nitrobenzoic acid, p-aminobenzoic acid, p-fluorobenzoic acid, o-chlorobenzoic acid]. The newly isolated antimony carboxylates have been identified on the basis of melting points, elemental analysis, FT-IR, 1H NMR, 13C NMR, 19F NMR. The molecular weight and conductivity data indicate the monomeric and non-electrolytic behaviour in solution. Compounds have been evaluated for their antifungal and antibacterial activity.

Keywords

Thiosalicyclic acid Antimicrobial activity µ-Oxy-bis[triphenylantimony(V)]dicarboxylates and mixed carboxylates
Singh, S., Bahuguna, N., Singhal, K., & Raj, P. (2021). Synthetic, Spectroscopic and Biological Studies on Some μ-Oxy-bis[triphenylantimony(V)]carboxylates and Cyclic Organoantimonates. Asian Journal of Chemistry, 33(2), 387–392. https://doi.org/10.14233/ajchem.2021.23045
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