Issue

Vol. 33 No. 2 (2021): Vol 33 Issue 2

Copyright (c) 2021 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Syntheses, Structures, Magnetic Properties and Antibacterial Activities of Two Copper(II) Azido Complexes with Varied Nuclearities Containing Symmetrical 1,3-Diammine as Chelator

https://doi.org/10.14233/ajchem.2021.23007
Habibar Chowdhury
Department of Chemistry, Kabi Nazrul College, Murarai, Birbhum-731 219, India
Chandan Adhikary
Department of Education, The University of Burdwan, Golapbag, Burdwan-713104, India

Corresponding Author(s) : Chandan Adhikary

cadhikary123@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 2 (2021): Vol 33 Issue 2

Abstract

Two copper(II) azido complexes of the types mononuclear [Cu(TMEDA)2(N3)2] (1) and dinuclear [Cu(TMEDA)(μ1,1-N3)(N3)]2 (2) [TMEDA = trimethylenediamine; N3– = azide ion] have been synthesized and characterized. X-ray structural analysis revealed that each copper(II) center in complex 1 adopts a distorted octahedron geometry with a CuN6 chromophore ligated through four N atoms of two different symmetrical TMEDA ligands as bidentate chelator and two N atoms of two terminal azides. In complex 2, each copper(II) center adopts a distorted square pyramidal geometry with a CuN5 chromophore ligated through two N atoms of TMEDA as bidentate chelator and two N atoms of two different azides as μ1,1-N3 bridging mode and one N atom of terminal azide ion. The two copper centers are connected through double μ1,1-N3 bridges affording a dinuclear structure with Cu···Cu separation 3.327(2) Å. In crystalline state, mononuclear units in complex 1 are associated through intermolecular N-H···N and C-H···N hydrogen bonds to form a 2D sheet structure viewed along crystallographic b-axis, whereas dinuclear entities in complex 2 are propagated through intermolecular N-H···N and C-H···N hydrogen bonds to form a 3D network structure viewed along crystallographic a-axis. The Variable-temperature magnetic susceptibility measurement evidenced a dominant antiferromagnetic interaction between the metal centers through μ1,1-azide bridges in complex 2 with J = − 0.40 cm-1. The antibacterial activities of the complexes have also been studied.

Keywords

Dinuclear Copper(II) complex Terminal azide Bridged azide X-ray structure Antibacterial activities
Chowdhury, H., & Adhikary, C. (2021). Syntheses, Structures, Magnetic Properties and Antibacterial Activities of Two Copper(II) Azido Complexes with Varied Nuclearities Containing Symmetrical 1,3-Diammine as Chelator. Asian Journal of Chemistry, 33(2), 359–366. https://doi.org/10.14233/ajchem.2021.23007
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. R. Ricco, C. Pfeiffer, K. Sumida, C.J. Sumby, P. Falcaro, S. Furukawa, N.R. Champness and C.J. Doonan, CrystEngComm, 18, 6532 (2016);https://doi.org/10.1039/C6CE01030J
  2. R.R. Ozer and J.P. Hinestroza, RSC Adv., 5, 15198 (2015);https://doi.org/10.1039/C4RA15161E
  3. T. N. Mandal, A. Karmakar, S. Sharma and S.K. Ghosh, Chem. Record, 18, 154 (2018);https://doi.org/10.1002/tcr.201700033
  4. Z.N. Wang, X. Wang, S. Yue Wei, J. Xiao Wang, F. Ying Bai, Y. Heng Xing and L. Xian Sun, New J. Chem., 39, 4168 (2015);https://doi.org/10.1039/C5NJ00173K
  5. C. Mottillo and T. Friscic, Chem. Commun., 51, 8924 (2015);https://doi.org/10.1039/C5CC01645B
  6. R. Chakrabarty, P.S. Mukherjee and P.J. Stang, Chem. Rev., 111, 6810 (2011);https://doi.org/10.1021/cr200077m
  7. M.L. Neidig, D.L. Clark and R.L. Martin, Coord. Chem. Rev., 257, 394 (2013);https://doi.org/10.1016/j.ccr.2012.04.029
  8. J. Reedijk, Chem. Soc. Rev., 42, 1776 (2013);https://doi.org/10.1039/C2CS35239G
  9. R.D. Willet, D. Gatteschi and O. Kahn, eds., Magneto-Structural Correlations in Exchange Coupled Systems, NATO ASI Series: Reidel, Dordrecht (1985).
  10. M.M. Turnbull, T. Sugimoto and L.K. Thompson, Molecular Based Magnetic Materials: Theory, Techniques and Applications, ACS Symposium Series, no. 644, ACS: Washington (1996).
  11. A. Caneschi, D. Gatteschi, L. Pardi and R. Sessoli, ed.: A.F. Williams Clusters, Chains and Layered Molecules: The Chemists Way to Magnetic Materials, In: Perspectives in Coordination Chemistry, VCH: Weinheim (1992).
  12. J.L. Manson, A.M. Arif and J.S. Miller, Chem. Commun., 1479 (1999);https://doi.org/10.1039/a903406d
  13. O. Kahn, Condens. Mater. Phys, 17, 39 (1994).
  14. J.R. Long, ed.: P. Yang, Molecular Cluster Magnets in Chemistry of Nanostructured Materials: World Scientific: Hong Kong (2003).
  15. L.K. Thompson and S.K. Tandon, Comments Inorg. Chem., 18, 125 (1996);https://doi.org/10.1080/02603599608032718
  16. A. Escuer and G. Aromí, Eur. J. Inorg. Chem., 2006, 4721 (2006);https://doi.org/10.1002/ejic.200600552
  17. Y.-F. Zeng, X. Hu, F.-C. Liu and X.-H. Bu, Chem. Soc. Rev., 38, 469 (2009);https://doi.org/10.1039/B718581M
  18. S. Saha, D. Mal, S. Koner, A. Bhattacherjee, P. Gütlich, S. Mondal, M. Mukherjee and K.-I. Okamoto, Polyhedron, 23, 1811 (2004);https://doi.org/10.1016/j.poly.2004.04.007
  19. J. Ribas, M. Monfort, I. Resino, B. Kumar Ghosh, X. Solans and M. Font-Bardia, Polyhedron, 17, 1735 (1998);https://doi.org/10.1016/S0277-5387(97)00444-0
  20. S. Koner, S. Iijima, M. Watanabe and M. Sato, J. Coord. Chem., 56, 103 (2003);https://doi.org/10.1080/0095897031000066060
  21. N. Kuhn, T. Kratz, D. Bläser and R. Boese, Adv. Inorg. Chem., 43, 179 (1995);https://doi.org/10.1016/0020-1693(95)04701-A
  22. R. Robson, Aust. J. Chem., 23, 2217 (1970);https://doi.org/10.1071/CH9702217c
  23. A. Escuer, M.A.S. Goher, F.A. Mautner and R. Vicente, Inorg. Chem., 39, 2107 (2000);https://doi.org/10.1021/ic991135c
  24. W.-W. Sun, X.-B. Qian, C.-Y. Tian and E.-Q. Gao, Inorg. Chim. Acta, 362, 2744 (2009);https://doi.org/10.1016/j.ica.2008.12.016
  25. B. Graham, M.T.W. Hearn, P.C. Junk, C.M. Kepert, F.E. Mabbs, B. Moubaraki, K.S. Murray and L. Spiccia, Inorg. Chem., 40, 1536 (2001);https://doi.org/10.1021/ic000991h
  26. S. Youngme, T. Chotkhun, S. Leelasubcharoen, N. Chaichit, C. Pakawatchai, G.A. van Albada and J. Reedijk, Polyhedron, 26, 725 (2007);https://doi.org/10.1016/j.poly.2006.09.073
  27. J.D. Woodward, R.V. Backov, K.A. Abboud, D. Dai, H.-J. Koo, M.-H. Whangbo, M.W. Meisel and D.R. Talham, Inorg. Chem., 44, 638 (2005);https://doi.org/10.1021/ic049175q
  28. E.A. Boudreaux and L.N. Mulay, Theory and Applications of Molecular Paramagnetism, Wiley-Interscience: New York (1976).
  29. Bruker APEX2, (Version 2008.1-0), SAINT (Version 7.51A) and SADABS (Version 2007/4) Bruker AXS Inc. Madison, Wisconsin: USA (2008).
  30. A. Altomare, M.C. Burla, M. Camalli, G.L. Cascarano, C. Giacovazzo, A. Guagliardi, A.G.G. Moliterni, G. Polidori and R. Spagna, J. Appl. Cryst., 32, 115 (1999);https://doi.org/10.1107/S0021889898007717
  31. G.M. Sheldrick, Acta Crystallogr. C, 71, 3 (2015);https://doi.org/10.1107/S2053229614024218
  32. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A and B, Wiley: NewYork, edn 5 (1997).
  33. A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier: New York, edn 2 (1984).
  34. P. Dapporto, M. Formica, V. Fusi, L. Giorgi, M. Micheloni, P. Paoli, R. Pontellini and P. Rossi, Inorg. Chem., 40, 6186 (2001);https://doi.org/10.1021/ic0105415
  35. T. Gajda, A. Jancsó, S. Mikkola, H. Lönnberg and H. Sirges, J. Chem. Soc., Dalton Trans., 1757 (2002);https://doi.org/10.1039/b108948j
  36. A.W. Addison, T.N. Rao, J. Reedijk, J. van Rijn and G.C. Verschoor, J. Chem. Soc., Dalton Trans., 1349 (1984);https://doi.org/10.1039/DT9840001349
  37. O. Kahn, Molecular Magnetism, VCH: New York (1993).
  38. B.G. Tweedy, Phytopathology, 55, 910 (1964).
  39. K. Kralova, K. Kissova, O. Svajlenova and J. Vanco, Chem. Pap., 58, 361 (2000).
  40. J. Parekh, P. Inamdhar, R. Nair, S. Baluja and S. Chanda, J. Serb. Chem. Soc., 70, 1155 (2005);https://doi.org/10.2298/JSC0510155P
  41. Y. Vaghasiya, R. Nair, M. Soni, S. Baluja and S. Shanda, J. Serb. Chem. Soc., 69, 991 (2004);https://doi.org/10.2298/JSC0412991V
  42. N. Raman, Res. J. Chem. Environ., 4, 9 (2005).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 1