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Vol. 33 No. 2 (2021): Vol 33 Issue 2

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A Validated SPE-UPLC-DAD Method for Quantification of Parabens in Industrial Waste Effluent Water Samples by Using Activated Carbon Nanofiber Modified Filter Paper

https://doi.org/10.14233/ajchem.2021.23012
Eegala Bheema Shankar
Division of Chemistry, Vignan’s Foundation for Science, Technology & Research (Deemed to be University) Vadlamudi-522213, India
Challa Gangu Naidu
Division of Chemistry, Vignan’s Foundation for Science, Technology & Research (Deemed to be University) Vadlamudi-522213, India
CH. N.S. Sai Pavan Kumar
Division of Chemistry, Vignan’s Foundation for Science, Technology & Research (Deemed to be University) Vadlamudi-522213, India
Kasturi Rajashekhar
Division of Chemistry, Vignan’s Foundation for Science, Technology & Research (Deemed to be University) Vadlamudi-522213, India

Corresponding Author(s) : Challa Gangu Naidu

naiduiict@gmail.com; naidu064@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 2 (2021): Vol 33 Issue 2

Abstract

The present work describes a sensitive, simple, cost-effective and fast analytical procedure to detect the parabens in industrial waste effluent water samples using novel activated carbon nanofiber (CNF) modified filter paper based solid phase extraction technique coupled with liquid chromatography with photodiode array detector (UPLC-PDA). The carbon nanofiber coated filter paper was used as an adsorbent and also characterized by field emission scanning electron microscope (FESEM) showed superior porous structure. Various factors effecting the adsorption and desorption process were studied. The optimum parameters which improve the efficiency are paper length 1 cm × 2 cm, adsorption time 15 min, eluent methanol, eluent volume 5 mL, sample pH 7, desorption time 2 min, 2% salt addition and 300 rpm stirring rate respectively. The parabens exhibited superior linearity ranging from 0.1-50 ng mL-1. The regression coefficient (R2) value ranging from 0.9981-0.9989. This method exhibited good sensitivity with the quantification limit (LOQ) between 0.5-0.75 ng mL-1 and detection limit (LOD) over the range of 0.1-0.25 ng mL-1. The precision was expressed from the RSDs values from 0.74-0.97 %. The spiked analytes revealed excellent recoveries in the range of 95.30-116.72 % with RSD less than 5.72 % for all the water samples also applied for real samples.

Keywords

Carbon nanofiber Dispersion Effluent water Parabens UPLC-DAD
Bheema Shankar, E., Gangu Naidu, C., N.S. Sai Pavan Kumar, C., & Rajashekhar, K. (2021). A Validated SPE-UPLC-DAD Method for Quantification of Parabens in Industrial Waste Effluent Water Samples by Using Activated Carbon Nanofiber Modified Filter Paper. Asian Journal of Chemistry, 33(2), 350–358. https://doi.org/10.14233/ajchem.2021.23012
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References
  1. S. Oishi, Toxicol. Ind. Health, 17, 31 (2001);https://doi.org/10.1191/0748233701th093oa
  2. C. Piao, L. Chen and Y. Wang, J. Chromatogr. B Analyt. Technol. Biomed. Life Sci., 969, 139 (2014);https://doi.org/10.1016/j.jchromb.2014.08.015
  3. P.D. Darbre, A. Aljarrah, W.R. Miller, N.G. Coldham, M.J. Sauer and G.S. Pope, J. Appl. Toxicol., 24, 5 (2004);https://doi.org/10.1002/jat.958
  4. B.K. Park, J.W. Dear and D.J. Antoine, BMJ Clin. Evid., 317, 1609 (2015).
  5. S. Oishi, Food Chem. Toxicol., 40, 1807 (2002);https://doi.org/10.1016/S0278-6915(02)00204-1
  6. J. Feng, X. He, X. Liu, X. Sun and Y. Li., J. Chromatogr. A, 1465, 20 (2016);https://doi.org/10.1016/j.chroma.2016.08.052
  7. A.J. Ocana-González, M.Villar-Navarro, M. Ramos-Payán, R. Fernández-Torres, M.A. Bello-López, Anal. Chim. Acta, 858, 1 (2015);https://doi.org/10.1016/j.aca.2014.07.002
  8. M. Pastor-Belda, L. Marín-Soler, N. Campillo, P. Viñas and M. Hernández-Córdoba, J. Chromatogr. A, 1564, 102 (2018);https://doi.org/10.1016/j.chroma.2018.06.025
  9. J. Chen, W. Deng, X. Li, X. Wang and Y. Xiao, J. Chromatogr. A, 1591, 33 (2019);https://doi.org/10.1016/j.chroma.2019.01.030
  10. J. Boberg, C. Taxvig, S. Christiansen and U. Hass, Reprod. Toxicol., 30, 301 (2010);https://doi.org/10.1016/j.reprotox.2010.03.011
  11. D. Bledzka, J. Gromadzi’nska and W. Wasowicz, Environ. Int., 67, 27 (2014);https://doi.org/10.1016/j.envint.2014.02.007
  12. M. Fisher, S. MacPherson, J.M. Braun, R. Hauser, M. Walker, M. Feeley, R. Mallick, R. Berube and T.E. Arbuckle, Environ. Sci. Technol., 51, 4009 (2017);https://doi.org/10.1021/acs.est.6b04302
  13. J.D. Meeker, T. Yang, X. Ye, A.M. Calafat and R. Hauser, Health Perspect., 119, 252 (2011);https://doi.org/10.1289/ehp.1002238
  14. P.W. Harvey and D.J. Everett, J. Appl. Toxicol., 24, 1 (2004);https://doi.org/10.1002/jat.957
  15. V. Cristina Jardim, L. de Paula Melo, D. Soares Domingues and M.E. Costa Queiroz, J. Chromatogr. B Analyt. Technol. Biomed. Life Sci., 974, 35 (2015);https://doi.org/10.1016/j.jchromb.2014.10.026
  16. J. He, S. Chen, Y. Jiang, Y. Shen, J. Zhu, H. Wei, H. Zhang and K. Lu, J. Sep. Sci., 35, 308 (2012);https://doi.org/10.1002/jssc.201100721
  17. C. Almeida and J.M.F. Nogueira, J. Chromatogr. A, 1348, 17 (2014);https://doi.org/10.1016/j.chroma.2014.04.057
  18. G. Mafra, A.L. Oenning, A.N. Dias, J. Merib, D. Budziak, C.B. Silveira and E. Carasek, Talanta, 178, 886 (2018);https://doi.org/10.1016/j.talanta.2017.10.022
  19. M. Md Yusoff, M. Raoov, N. Yahaya and N. Md Salleh, RSC Adv., 7, 35832 (2017);https://doi.org/10.1039/C7RA06682A
  20. H. Ghambari, E.M. Reyes-Gallardo, R. Lucena, M. Saraji and S. Cárdenas, Talanta, 170, 451 (2017);https://doi.org/10.1016/j.talanta.2017.04.026
  21. N. Ramírez, F. Borrull and R.M. Marcé, J. Sep. Sci., 35, 580 (2012);https://doi.org/10.1002/jssc.201100887
  22. X. You, C. Piao and L. Chen, J. Sep. Sci., 39, 2831 (2016);https://doi.org/10.1002/jssc.201600335
  23. U. Alshana, N. Ertas and N.G. Goger, Food Chem., 181, 1 (2015);https://doi.org/10.1016/j.foodchem.2015.02.074
  24. R. Jain, M.K.R. Mudiam, A. Chauhan, R. Ch, R.C. Murthy and H.A. Khan, Food Chem., 141, 436 (2013);https://doi.org/10.1016/j.foodchem.2013.03.012
  25. M. Moradi and Y. Yamini, J. Chromatogr. A, 1229, 30 (2012);https://doi.org/10.1016/j.chroma.2012.01.028
  26. Z. Es’haghi, M.A. Golsefidi, A. Saify, A.A. Tanha, Z. Rezaeifar and Z. Alian-Nezhadi, J. Chromatogr. A, 1217, 2768 (2010);https://doi.org/10.1016/j.chroma.2010.02.054
  27. Z. Es’haghi, Z. Rezaeifar, G.-H. Rounaghi, Z.A. Nezhadi and M.A. Golsefidi, Anal. Chim. Acta, 689, 122 (2011);https://doi.org/10.1016/j.aca.2011.01.019
  28. N. Zhang, J. Gao, C. Huang, W. Liu, P. Tong and L. Zhang, Anal. Chim. Acta, 934, 122 (2016);https://doi.org/10.1016/j.aca.2016.06.029
  29. Y. Yang, P. Qin, J. Zhang, W. Li, J. Zhu, M. Lu and Z. Cai, J. Chromatogr. A, 1570, 47 (2018);https://doi.org/10.1016/j.chroma.2018.07.080
  30. Y. Yang, J. Chen and Y.-P. Shi, Talanta, 97, 222 (2012);https://doi.org/10.1016/j.talanta.2012.04.021
  31. M.N. Yazdi, Y. Yamini and H. Asiabi, J. Chromatogr. A, 1554, 8 (2018);https://doi.org/10.1016/j.chroma.2018.04.040
  32. N. Zhang, C. Huang, Z. Feng, H. Chen, P. Tong, X. Wu and L. Zhang, J. Chromatogr. A, 1570, 10 (2018);https://doi.org/10.1016/j.chroma.2018.07.065
  33. X.Y. Song, Y.P. Shi and J. Chen, Talanta, 116, 188 (2013);https://doi.org/10.1016/j.talanta.2013.05.025
  34. E. Kazemi, A.M. Haji Shabani and S. Dadfarnia, Food Chem., 221, 783 (2017);https://doi.org/10.1016/j.foodchem.2016.11.103
  35. F.A. Casado-Carmona, M.C. Alcudia-León, R. Lucena, S. Cárdenas and M. Valcárcel, Microchem. J., 128, 347 (2016);https://doi.org/10.1016/j.microc.2016.05.011
  36. F. Makkliang, P. Kanatharana, P. Thavarungkul and C. Thammakhet-Buranachai, Talanta, 184, 429 (2018);https://doi.org/10.1016/j.talanta.2018.03.024
  37. I. Márquez-Sillero, E. Aguilera-Herrador, S. Cárdenas and M. Valcárcel, J. Chromatogr. A, 1217, 1 (2010);https://doi.org/10.1016/j.chroma.2009.11.005
  38. S. Li, M. Jia, H. Guo and X. Hou, Anal. Bioanal. Chem., 410, 6619 (2018);https://doi.org/10.1007/s00216-018-1269-2
  39. A.N. Dias, A.C. da Silva, V. Simão, J. Merib and E. Carasek, Anal. Chim. Acta, 888, 59 (2015);https://doi.org/10.1016/j.aca.2015.07.011
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