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Synthesis and Performance Evaluation of Green Anionic Polymeric Surfactant for Detergent Application
Corresponding Author(s) : Neeta Singh
Asian Journal of Chemistry,
Vol. 33 No. 2 (2021): Vol 33 Issue 2
Abstract
The main role of this study is to prepare the green polymer based anionic surfactant as an alternative to non-biodegradable surfactant for detergent applications. The detergent properties i.e., surface tension measurements, foaming property, emulsifying ability, dispersing property, FTIR analysis and wetting behaviour were studied using several rheological techniques. The critical micelle concentration (CMC) value was obtained at 6 mg/L of surfactant concentration showing no further remarkable changes in surface tension with increases in concentration. Low surface tension value was correlated with decrease in cohesive force exist between the molecules and allowed the surfactant easily adsorbed on the pore surface. The low surface tension value, reliable wetting characteristic, excellent emulsifying power, benchmark dispersing behaviour and suitable foaming property assuring the successful utilization of polymer based anionic surfactant for detergent applications.
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- S. Kumar, N. Saxena and A. Mandal, J. Ind. Eng. Chem., 43, 106 (2016);https://doi.org/10.1016/j.jiec.2016.07.055
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- Z. Zhang, J. Li and J. Zhou, Transp. Porous Media, 86, 199 (2011);https://doi.org/10.1007/s11242-010-9616-6
- H.L. Chang, J. Petrol. Technol., 30, 1113 (1978);https://doi.org/10.2118/7043-PA
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- A. de Lucas, L. Rodríguez, J. Lobato and P. Sánchez, Chem. Eng. Sci., 57, 479 (2002);https://doi.org/10.1016/S0009-2509(01)00372-4
- B. Kapur, J. Solomon and B. Bluestein, J. Am. Oil Chem. Soc., 55, 549 (1978);https://doi.org/10.1007/BF02668068
- Y. Lim, R.D. Stanimirova, H. Xu and J. Petkov, Household and Personal Care Today, 11, 47 (2016).
- W. El-Dougdoug and E. El-Mossalamy, Appl. Surf. Sci., 253, 2487 (2006);https://doi.org/10.1016/j.apsusc.2006.05.006
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- Y. Yu, J. Zhao and A.E. Bayly, Chin. J. Chem. Eng., 16, 517 (2008);https://doi.org/10.1016/S1004-9541(08)60115-9
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- Y. Kakizawa and M. Miyake, J. Oleo Sci., 68, 19081 (2019);https://doi.org/10.5650/jos.ess19081
- A. Eissa, M. El-Hefnawy, S. Bader and M. Radwan, J. Surfactants Deterg., 15, 411 (2012);https://doi.org/10.1007/s11743-011-1324-x
- Y.-F. Chen, C.-H. Yang, M.-S. Chang, Y.-P. Ciou and Y.-C. Huang, Int. J. Mol. Sci., 11, 4417 (2010);https://doi.org/10.3390/ijms11114417
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References
S. Kumar, N. Saxena and A. Mandal, J. Ind. Eng. Chem., 43, 106 (2016);https://doi.org/10.1016/j.jiec.2016.07.055
D. Jenkins, W.J. Kaufman, P. McGauhey, A.J. Horne and J. Gasser, Water Res., 7, 265 (1973);https://doi.org/10.1016/0043-1354(73)90168-1
Z. Chu and Y. Feng, ACS Sustain. Chem. Eng., 1, 75 (2013);https://doi.org/10.1021/sc300037e
P. Raffa, D.A.Z. Wever, F. Picchioni and A.A. Broekhuis, Chem. Rev., 115, 8504 (2015);https://doi.org/10.1021/cr500129h
Z. Zhang, J. Li and J. Zhou, Transp. Porous Media, 86, 199 (2011);https://doi.org/10.1007/s11242-010-9616-6
H.L. Chang, J. Petrol. Technol., 30, 1113 (1978);https://doi.org/10.2118/7043-PA
B. Sandiford, J. Petrol. Technol., 16, 917 (1964);https://doi.org/10.2118/844-PA
K.D. Danov, R.D. Stanimirova, P.A. Kralchevsky, E.S. Basheva, V.I. Ivanova and J.T. Petkov, J. Colloid Interface Sci., 457, 307 (2015);https://doi.org/10.1016/j.jcis.2015.07.020
G. Martins and M.F.R.G. Dias, ed.: M. Miteva, Hair Cosmeceuticals. In Alopecia, Elsevier, Chap. 27, pp 285-293 (2019).
A. de Lucas, L. Rodríguez, J. Lobato and P. Sánchez, Chem. Eng. Sci., 57, 479 (2002);https://doi.org/10.1016/S0009-2509(01)00372-4
B. Kapur, J. Solomon and B. Bluestein, J. Am. Oil Chem. Soc., 55, 549 (1978);https://doi.org/10.1007/BF02668068
Y. Lim, R.D. Stanimirova, H. Xu and J. Petkov, Household and Personal Care Today, 11, 47 (2016).
W. El-Dougdoug and E. El-Mossalamy, Appl. Surf. Sci., 253, 2487 (2006);https://doi.org/10.1016/j.apsusc.2006.05.006
D. Hall and G. Tiddy, Surfactant Science Series, 11, 60 (1981).
A.M. Fernandez, U. Held, A. Willing and W.H. Breuer, Prog. Org. Coat., 53, 246 (2005);https://doi.org/10.1016/j.porgcoat.2004.12.011
L. Cohen, A. Moreno and J. Berna, J. Am. Oil Chem. Soc., 70, 79 (1993);https://doi.org/10.1007/BF02545372
P.E. Throckmorton, R.R. Egan, D. Aelony, G.K. Mulberry and F.H. Otey, J. Am. Oil Chem. Soc., 51, 486 (1974);https://doi.org/10.1007/BF02635857
X. Li and W. Eli, J. Mol. Catal. Chem., 279, 159 (2008);https://doi.org/10.1016/j.molcata.2007.08.032
S. Kumar and A. Mandal, Polymer, 120, 30 (2017);https://doi.org/10.1016/j.polymer.2017.05.051
Y. Yu, J. Zhao and A.E. Bayly, Chin. J. Chem. Eng., 16, 517 (2008);https://doi.org/10.1016/S1004-9541(08)60115-9
Y.S. Lim, N.B. Baharudin and Y.W. Ung, J. Surfactants Deterg., 22, 549 (2019);https://doi.org/10.1002/jsde.12230
Y. Kakizawa and M. Miyake, J. Oleo Sci., 68, 19081 (2019);https://doi.org/10.5650/jos.ess19081
A. Eissa, M. El-Hefnawy, S. Bader and M. Radwan, J. Surfactants Deterg., 15, 411 (2012);https://doi.org/10.1007/s11743-011-1324-x
Y.-F. Chen, C.-H. Yang, M.-S. Chang, Y.-P. Ciou and Y.-C. Huang, Int. J. Mol. Sci., 11, 4417 (2010);https://doi.org/10.3390/ijms11114417
A. El Menam Eissa, M. El Hefnawy, S. Bader, M. Radwan and M. Deef Allah, J. Surfactants Deterg., 15, 411 (2012);https://doi.org/10.1007/s11743-011-1324-x
E. Kamba, A. Itodo and E. Ogah, Int. J. Mater. Chem., 3, 69 (2013);https://doi.org/10.5923/j.ijmc.20130304.01