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Kinetics and Mechanism of Slurry Phase Air Oxidation of Benzyl Alcohol over Zirconium Vanadate Catalyst

https://doi.org/10.14233/ajchem.2021.22947
Shweta Kanungo Joshi
School of Chemical Sciences, Devi Ahilya Vishwavidyalaya, Indore-452001, India
Neena Sohani
Patel Group of Institutions, Ralamandal, Indore-452020, India
Savita Khare
School of Chemical Sciences, Devi Ahilya Vishwavidyalaya, Indore-452001, India
Rajendra Prasad
School of Chemical Sciences, Devi Ahilya Vishwavidyalaya, Indore-452001, India

Corresponding Author(s) : Shweta Kanungo Joshi

shwetakanungojoshi@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 1 (2021): Vol 33 Issue 1

Abstract

The kinetics of slurry phase air oxidation of benzyl alcohol to benzaldehyde over zirconium vanadate catalyst is reported in this study. Initial rates for the formation of product were determined by varying the partial pressures of the reactants. The data collected were found to satisfy a rate law: R = [(k1PBk2Po)/(k1PB + k2Po)]. The study suggests that reaction follows a Mars-Van Krevelen type of redox mechanism.

Keywords

Benzyl alcohol Zirconium vanadate Oxidation Kinetic study
Kanungo Joshi, S., Sohani, N., Khare, S., & Prasad, R. (2020). Kinetics and Mechanism of Slurry Phase Air Oxidation of Benzyl Alcohol over Zirconium Vanadate Catalyst. Asian Journal of Chemistry, 33(1), 108–112. https://doi.org/10.14233/ajchem.2021.22947
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