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Vol. 33 No. 11 (2021): Vol 33 Issue 11, 2021

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Thermoacoustic Properties of Binary Liquid Mixtures of Sulfolane with Aniline, N,N-Dimethylaniline and N,N-Diethylaniline at Different Temperatures and Atmospheric Pressure

https://doi.org/10.14233/ajchem.2021.23383
Mohammad Aftabuzzaman
Global GET-Future Lab, Department of Advanced Materials Chemistry, Korea University, 2511 Sejong-ro, Sejong 339-700, Republic of Korea ; Department of Chemistry, University of Rajshahi, Rajshahi-6205, Bangladesh
Mohammad Monirul Islam
Department of Chemistry, University of Rajshahi, Rajshahi-6205, Bangladesh
Nasiruddin
Department of Chemistry, University of Rajshahi, Rajshahi-6205, Bangladesh ; Department of Chemistry, Bangabandhu Sheikh Mujibur Rahman Science and Technology University, Gopalganj 8100, Bangladesh
Farhana Rahman Rima
Department of Chemistry, University of Rajshahi, Rajshahi-6205, Bangladesh
Mohammad Nazrul Islam
Department of Chemistry, University of Rajshahi, Rajshahi-6205, Bangladesh
Mohammad Azhar Ali
Department of Chemistry, University of Rajshahi, Rajshahi-6205, Bangladesh

Corresponding Author(s) : Mohammad Aftabuzzaman

aftab.ru08@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 11 (2021): Vol 33 Issue 11, 2021

Abstract

Densities and sound velocities of the binary liquid mixtures of sulfolane + aniline, sulfolane + N,N-dimethylaniline, sulfolane + N,N-diethylaniline over the whole range of composition and their pure component were measured at temperatures (T = 303.15, 308.15, 313.15 K) and atmospheric pressure. A high precision vibrating-tube densitometer was used for the measurements. From the measured values, excess adiabatic compressibility (βsE), excess sound velocity (uE), excess internal pressure (PiE) and deviation of surface tension (Δγ) were calculated for each of the systems. The excess properties and surface tension deviation were fitted to the Redlich-Kister equation. All these properties have been discussed in terms of molecular interactions.

Keywords

Sulfolane Aniline Binary mixture N,N-Dimethylaniline N,N-Diethylaniline
Aftabuzzaman, M., Monirul Islam, M., Nasiruddin, ., Rahman Rima, F., Nazrul Islam, M., & Azhar Ali, M. (2021). Thermoacoustic Properties of Binary Liquid Mixtures of Sulfolane with Aniline, N,N-Dimethylaniline and N,N-Diethylaniline at Different Temperatures and Atmospheric Pressure. Asian Journal of Chemistry, 33(11), 2796–2802. https://doi.org/10.14233/ajchem.2021.23383
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