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Vol. 33 No. 11 (2021): Vol 33 Issue 11, 2021

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Synthesis, Characterization and Antimicrobial Activity Studies of Chlorocobaloximes with Neutral Bases Containing Amine Functionality

https://doi.org/10.14233/ajchem.2021.23417
V. Vijaikanth
Department of Applied Chemistry, Karunya Institute of Technology and Sciences, Coimbatore-641114, India
S. Vasuki
Department of Applied Chemistry, Karunya Institute of Technology and Sciences, Coimbatore-641114, India
C. Immanuel David
Department of Applied Chemistry, Karunya Institute of Technology and Sciences, Coimbatore-641114, India
L. Chandana
Department of Applied Chemistry, Karunya Institute of Technology and Sciences, Coimbatore-641114, India
S. Sowmya
Department of Applied Chemistry, Karunya Institute of Technology and Sciences, Coimbatore-641114, India
S. Murugan
Department of Biotechnology, Karunya Institute of Technology and Sciences, Coimbatore-641114, India

Corresponding Author(s) : V. Vijaikanth

vvijaikanth@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 11 (2021): Vol 33 Issue 11, 2021

Abstract

The inorganic cobaloximes of type [Co(Cl)(dmgH)2B]; where dmgH = dimethyl glyoxime and B = neutral bases: glycine, ethyl amine, 2-aminopyridine, 4-aminopyridine, 2,6-diaminopyridine, aniline and 1-napthylamine have been synthesized. The synthesized cobaloximes were characterized by IR, UV-visible, 1H NMR and 13C NMR spectroscopic techniques. The cobaloxime complexes were screened for their antibacterial activity against methicillin resistant Staphylococcus aureus (MRSA) and Acinetobacter baumannii by the zone of inhibition test, biofilm eradication on biomaterial using catheter and modified Congo red agar method. It has been found that the cobaloxime complexes exhibit inhibition against both gram positive and gram negative bacteria and the cobaloximes showed better inhibition towards Gram-negative bacteria compared to Gram-positive bacteria.

Keywords

Chlorocobaloximes Dimethyl glyoxime Amine Aminopyridine Antibacterial studies Biofilm
Vijaikanth, V., Vasuki, S., Immanuel David, C., Chandana, L., Sowmya, S., & Murugan, S. (2021). Synthesis, Characterization and Antimicrobial Activity Studies of Chlorocobaloximes with Neutral Bases Containing Amine Functionality. Asian Journal of Chemistry, 33(11), 2781–2788. https://doi.org/10.14233/ajchem.2021.23417
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