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Vol. 33 No. 10 (2021): Vol 33 Issue 10, 2021

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Synthesis, Spectroscopic Investigation and Catalytic Behaviour of Histidine Substituted Nickel(II) Phthalocyanine

https://doi.org/10.14233/ajchem.2021.23202
K.R. Venugopala Reddy
Department of Studies and Research in Chemistry Vijayanagara Sri Krishnadevaraya University, Bellary-583105, India
T.M. Sharanakumar
Department of Studies and Research in Chemistry Vijayanagara Sri Krishnadevaraya University, Bellary-583105, India ; Department of Chemistry, Ballari Institute of Technology and Management, Jnana Gangotri Campus, Bellary-583104, India
N.Y. Praveenkumar
Department of Studies and Research in Chemistry Vijayanagara Sri Krishnadevaraya University, Bellary-583105, India
N.H.M Nandinibaby
Department of Physics, Ballari Institute of Technology and Management, Jnana Gangotri Campus, Bellary-583104, India
Mounesh
Department of Studies and Research in Chemistry Vijayanagara Sri Krishnadevaraya University, Bellary-583105, India
Suresh
Department of Chemistry, Ballari Institute of Technology and Management, Jnana Gangotri Campus, Bellary-583104, India

Corresponding Author(s) : K.R. Venugopala Reddy

venurashmi30@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 10 (2021): Vol 33 Issue 10, 2021

Abstract

In this work, the oxidation behaviour of phenol and chlorophenol contaminants present in the water catalyzed by histidine substituted nickel(II) phthalocyanine (NiPc) is reported. This work comprises synthesis, characterization and study the catalytic behaviour of histidine substituted NiPc on the oxidation of phenol and their substrates like 2- and 4-chlorophenols with 4-aminoantipyrine utilizing molecular oxygen. The products from the oxidation can be analyzed by UV-Vis spectroscopy and the results confirmed the formation of superoxide anion radical were crucial for the formation of product and a feasible mechanism including a successive transfer of single electron from phenolic compounds to O2 through the axis of histidine Ni(II)Pc was reported.

Keywords

Histidine Nickel(II) phthalocyanine 4-Aminoantipyrine Phenol Chlorophenol Catalytic oxidation 2,4-dichlorophenol
Venugopala Reddy, K., Sharanakumar, T., Praveenkumar, N., Nandinibaby, N., Mounesh, ., & Suresh, . (2021). Synthesis, Spectroscopic Investigation and Catalytic Behaviour of Histidine Substituted Nickel(II) Phthalocyanine. Asian Journal of Chemistry, 33(10), 2455–2464. https://doi.org/10.14233/ajchem.2021.23202
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