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Vol. 37 No. 7 (2025): Vol 37 Issue 7, 2025

Copyright (c) 2025 Meena Lande

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Iron Oxide Nanoparticles as an Efficient Catalyst for Azide-Alkyne Cycloaddition Reaction

https://doi.org/10.14233/ajchem.2025.33868
Meena B. Lande
Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Chhatrapati Sambhajinagar-431004, India; Department of Chemistry, Mula Education Society’s Arts, Commerce and Science College, Sonai-414105, India
https://orcid.org/0009-0000-2287-0195
Mahesh S. Jangale
Department of Chemistry, Mula Education Society’s Arts, Commerce and Science College, Sonai-414105, India
https://orcid.org/0000-0001-6645-4425
Suresh T. Gaikwad
Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Chhatrapati Sambhajinagar-431004, India
https://orcid.org/0000-0002-3212-4185
Anjali S. Rajbhoj
Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Chhatrapati Sambhajinagar-431004, India
https://orcid.org/0000-0003-0434-1999

Corresponding Author(s) : Anjali S. Rajbhoj

anjali.rajbhoj@gmail.com

Asian Journal of Chemistry, Vol. 37 No. 7 (2025): Vol 37 Issue 7, 2025

Abstract

The current work focused on the synthesis of iron oxide nanoparticles by electrochemical method and its application in sustainable and eco-friendly copper-free method for the azide–alkyne cycloaddition reactions using a mild-conditions. The electrochemical reduction method was used to synthesize the iron oxide nanoparticles (IONPs) by optimizing the current density of 10 mA/cm2 and tetrapropylammonium bromide as a structure-directing agent in an organic medium. A conventional electrolysis cell was used to generate nanoparticles, with a readily available iron metal sheet acts as an anode and a platinum sheet served as a cathode. The synthesized iron oxide nanoparticles were characterized using FTIR, XRD, SEM and energy dispersive X-ray analysis techniques. The reaction is regioselective as Huisgen 1,3-dipolar cycloaddition reaction where 1,4-disubstituted 1,2,3-triazole formed as product. IONPs could be magnetically collected and also reused without any significant loss of its catalytic activity. The synthesized 1,2,3-triazole products were characterized by FTIR, 1H NMR and 13C NMR.

Keywords

Cycloaddition reaction Electrochemical reduction method Iron oxide nanoparticles Tetrapropylammonium bromide
(1)
Lande, M. B.; Jangale, M. S.; Gaikwad, S. T.; Rajbhoj, A. S. Iron Oxide Nanoparticles As an Efficient Catalyst for Azide-Alkyne Cycloaddition Reaction. ajc 2025, 37, 1636-1640.
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