Issue

Vol. 27 No. 10 (2015): Vol 27 Issue 10

Copyright (c) 2015 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Selective Oxidation of Alkylbenzenes to Aryl Ketones with Polymer-Supported Molybdenum Catalyst

https://doi.org/10.14233/ajchem.2015.18827
Q. Xu
Department of Chemistry, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P.R. China
B.D. Li
Department of Chemistry, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P.R. China
L. Chen
Department of Chemistry, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P.R. China

Corresponding Author(s) : B.D. Li

libindong@mail.njust.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 10 (2015): Vol 27 Issue 10

Abstract

A new polymer-supported molybdenum-3,5-dimethyl pyrazole catalyst was synthesized and the structure was characterized by FT-IR and SEM. The resulting catalyst presented high activity for selective oxidation of alkyl aromatics to benzylic ketones with tert-butyl hydroperoxide and could be reused at least five times without loss of activity.

Keywords

Polymer-supported tert-Butyl hydroperoxide Alkyl aromatics Oxidation
Xu, Q., Li, B., & Chen, L. (2015). Selective Oxidation of Alkylbenzenes to Aryl Ketones with Polymer-Supported Molybdenum Catalyst. Asian Journal of Chemistry, 27(10), 3555–3558. https://doi.org/10.14233/ajchem.2015.18827
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. M. Hudlicky, Oxidations in Organic Chemistry, American Chemical Society, Washington (1990).
  2. F. Rajabi, R. Luque, J.H. Clark, B. Karimi and D.J. Macquarrie, Catal. Commun., 12, 510 (2011); doi:10.1016/j.catcom.2010.11.024.
  3. X.M. Yang, Y. Wang, C.F. Zhang, T. Fang, L.P. Zhou, W. Zhang and J. Xu, J. Phys. Org. Chem., 24, 693 (2011); doi:10.1002/poc.1810.
  4. D. Habibi, A.R. Faraji, M. Arshadi, H. Veisi and A. Gil, J. Mol. Catal. A, 382, 41 (2014); doi:10.1016/j.molcata.2013.10.023.
  5. Q.H. Zhang, C. Chen, H. Ma, H. Miao, W. Zhang, Z.Q. Sun and J. Xu, J. Chem. Technol. Biotechnol., 83, 1364 (2008); doi:10.1002/jctb.1977.
  6. G.X. Li, Y.Z. Li, R.N. Mu, Y.D. Xu and P. Dong, React. Kinet. Mech. Catal., 109, 199 (2013); doi:10.1007/s11144-013-0555-4.
  7. C.L. Lu, Z.H. Fu, Y.C. Liu, F.L. Liu, Y.Y. Wu, J.W. Qin, X.L. He and D.L. Yin, J. Mol. Catal. A, 331, 106 (2010); doi:10.1016/j.molcata.2010.08.008.
  8. S. Velusamy and T. Punniyamurthy, Tetrahedron Lett., 44, 8955 (2003); doi:10.1016/j.tetlet.2003.10.016.
  9. M. Arshadi, M. Ghiaci, A.A. Ensafi, H. Karimi-Maleh and S.L. Suib, J. Mol. Catal. A, 338, 71 (2011); doi:10.1016/j.molcata.2011.01.027.
  10. S. Gago, S.M. Bruno, D.C. Queirós, A.A. Valente, I.S. Gonçalves and M. Pillinger, Catal. Lett., 141, 1009 (2011); doi:10.1007/s10562-011-0599-x.
  11. A. Shaabani, A. Bazgir, F. Teimouri and D.G. Lee, Tetrahedron Lett., 43, 5165 (2002); doi:10.1016/S0040-4039(02)00976-0.
  12. R.X. Wang, H.L. Zhu and B.J. Gao, React. Kinet. Mech. Catal., 103, 431 (2011); doi:10.1007/s11144-011-0316-1.
  13. A. Shaabani, E. Farhangi and A. Rahmati, Appl. Catal. A, 338, 14 (2008); doi:10.1016/j.apcata.2007.12.014.
  14. D. Habibi and A.R. Faraji, Appl. Surf. Sci., 276, 487 (2013); doi:10.1016/j.apsusc.2013.03.121.
  15. J. Luo, H. Yu, H.J. Wang and F. Peng, Catal. Commun., 51, 77 (2014); doi:10.1016/j.catcom.2014.03.031.
  16. L. Chen, B.D. Li, Q.X. Xu and D.B. Liu, Chin. Chem. Lett., 24, 849 (2013); doi:10.1016/j.cclet.2013.05.017.
  17. M.X. Zhu, X. Wei, B.D. Li and Y.Z. Yuan, Tetrahedron Lett., 48, 9108 (2007); doi:10.1016/j.tetlet.2007.10.135.
  18. M.R. Maurya, M. Kumar and A. Arya, Catal. Commun., 10, 187 (2008); doi:10.1016/j.catcom.2008.08.017.
  19. S. Das, T. Bhowmick, T. Punniyamurthy, D. Dey, M.K. Chaudhuri and J. Nath, Tetrahedron Lett., 44, 4915 (2003); doi:10.1016/S0040-4039(03)01126-2.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0