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Vol. 27 No. 2 (2015): Vol 27 Issue 2

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Synthesis and Structural Characterization of Trinuclear Cu2+, Zn2+ and Zn2+-Eu3+ Complexes Based on 2,3-Dihydroxybenzene-1,4-dicarbaldehyde, 1,3-bis(Aminooxy)propane with 3-Ethoxysalicylaldehyde

https://doi.org/10.14233/ajchem.2015.17547
Jing Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Yang Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Shou-Ting Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Xiu-Yan Dong
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Wen-Kui Dong
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : Wen-Kui Dong

dongwk@126.com

Asian Journal of Chemistry, Vol. 27 No. 2 (2015): Vol 27 Issue 2

Abstract

A novel bis(salamo)-type multipledentate chelating ligand H4L and its three Cu2+, Zn2+ and Zn2+-Eu3+ complexes have been designed and synthesized and characterized by elemental analyses, IR, UV-visible spectra and 1H NMR spectroscopy. The bis(salamo)-type compound H4L shows that the complexation between H4L and metal ions can affords 1:3 complex [M3(L)]2+ or [M12M2(L)]3+. The most likely structures of the Cu2+, Zn2+ and Zn2+-Eu3+ complexes have been suggested.

Keywords

bis(salamo)-type compound Synthesis Characterization
Zhang, J., Zhang, Y., Zhang, S.-T., Dong, X.-Y., & Dong, W.-K. (2015). Synthesis and Structural Characterization of Trinuclear Cu2+, Zn2+ and Zn2+-Eu3+ Complexes Based on 2,3-Dihydroxybenzene-1,4-dicarbaldehyde, 1,3-bis(Aminooxy)propane with 3-Ethoxysalicylaldehyde. Asian Journal of Chemistry, 27(2), 654–656. https://doi.org/10.14233/ajchem.2015.17547
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